Introduction The Royal Society of Chemistry Faraday Discussions are a series of meetings focusing on rapidly developing areas of physical chemistry. Contrary to typical conferences, Faraday Discussions rely on the active participation of speakers and audience alike. Topics for each session are based on new research papers submitted specifically for the meeting. Audience participation is...
Introduction The third UK Energy Storage Conference (UKES2016) was held at the Edgbaston campus of the University of Birmingham, UK, from midday on Wednesday 30th November to midday on Friday 2nd December 2016. The aim of the conference, organised by the Energy Storage Research Network on behalf of the UK Research Council funded Energy SuperStore Hub and chaired by Professor Nigel Brandon...
Lithium Sulfur: Mechanism, Modelling and Materials (Li-SM3) was organised by Oxis Energy Ltd, UK, Imperial College London, UK, and the Joint Center for Energy Storage Research (JCESR), USA. It was held at the Institution of Engineering and Technology (IET), Savoy Place, London from 26th–27th April 2017. More than 150 researchers from around the world attended this event, 44 of them...
Rechargeable metal-oxygen cells could exceed the stored energy of today’s most advanced lithium-ion cells. However challenges exist that must be overcome to bring this technology into practical application. These challenges include, among others, the recharge and cyclability efficiency, materials development and improvements in fundamental understanding of the electrochemistry and chemistry inside the cell. The common challenges for the anode, including corrosion, passivation and dendrite formation and those for the air cathode and the electrolyte are summarised in this review for cells based on magnesium, calcium, aluminium, silicon, zinc and iron.
Historically, Johnson Matthey has had a long association with electrochemistry, and perhaps this was inevitable because of the importance of the platinum group metals (pgm) to Johnson Matthey’s early development. Platinum, in particular, has been incredibly useful in the field, because of its exceptional electrocatalytic activity and impressive inertness in most environments. Famously,...
Introduction “Electrochemistry: Volume 14” is a collated book of five papers edited by Craig Banks (Manchester Metropolitan University, UK) and Steven McIntosh (Lehigh University, Bethlehem PA, USA), both of whom are well established in the field with research interests covering the topics in the book. The book is one of a series which aims to collate and summarise the key topics receiving...
Chemically regenerative redox cathode (CRRC) polymer electrolyte fuel cells (PEFCs) are attracting more interest as a platinum-free PEFC technology. These fuel cells utilise a liquid catalyst or catholyte, to perform the indirect reduction of oxygen, eliminating the major degradation mechanisms that plague PEFC durability. A key component of a CRRC PEFC system is the catholyte. This article reports a thorough study of the effect of catholyte concentration and temperature on CRRC PEFC system performance for H7PV4Mo8O40 and Na4H3PV4Mo8O40, two promising polyoxometalate (POM)-based catholytes. The results suggest 80°C and a catholyte concentration of 0.3 M provide the optimum performance for both H7PV4Mo8O40 and Na4H3PV4Mo8O40 (for ambient pressure operation).
To date, the world has been making a massive shift away from fossil fuels towards cleaner energy sources. For the past decade, polymer electrolyte membrane fuel cells (PEMFCs) powered by hydrogen have attracted much attention as a promising candidate for eco-friendly vehicles, i.e. fuel cell electric vehicles (FCEVs), owing to their high power density, high efficiency and zero emission features. Since the world’s first mass production of Tucson ix35 FCEV by Hyundai in 2013, global automotive original equipment manufacturers (OEMs) have focused on commercialising FCEVs. In 2018, Hyundai also unveiled the second generation of the mass-produced FCEV (i.e. Nexo) with improved performances and durability compared with its predecessor. Since then, the global market for PEMFCs for a variety of FCEV applications has been growing very rapidly in terms of both passenger vehicles and medium- and heavy-duty vehicles such as buses and trucks, which require much higher durability than passenger vehicles, i.e. 5000 h for passenger vehicles vs. 25,000 h for heavy-duty vehicles. In addition, PEMFCs are also in demand for other applications including fuel cell electric trains, trams, forklifts, power generators and vessels. We herein present recent advances in how hydrogen and PEMFCs will power the future in a wide range of applications and address key challenges to be resolved in the future.
