An optimal platinum alloy for precision casting was developed by taking 25 possible alloying elements into consideration. In order to rank these elements an equation was designed. The ranking allowed five promising alloy compositions to be identified. From these five alloys arc melted buttons were produced and tested for homogeneity and hardness to ensure their suitability as jewellery alloys. A pyrometer was used to measure solidus temperatures. In a second iteration, the five alloys were further improved and the most promising alloys were cast and compared to a commonly used jewellery alloy: platinum-copper-gallium (PtCuGa). The comparison was based on the melting interval and on microstructural investigations, carried out by scanning electron and optical microscopy, while mechanical properties were determined by tensile testing. Additionally, optical properties such as reflectivity and colour were investigated. After the second iteration two very promising compositions were identified: PtCuFeMnCr and PtCuFePdVY.
This review briefly describes the vacuum electrostatic levitation furnace developed by JAXA and the associated non-contact techniques used to measure the density, the surface tension and the viscosity of materials. The paper then presents a summary of the data taken with this facility in the equilibrium liquid and non-equilibrium liquid phases for the six platinum group metals (pgms): platinum, palladium, rhodium, iridium, ruthenium and osmium over wide temperature ranges that include undercooled and superheated phases. The presented data (density, surface tension and viscosity of Pt, Rh, Ir, Ru and Os and density of Pd) are compared with literature values.
The 28th annual Santa Fe Symposium® was held from 18th–21st May 2014 in Albuquerque, New Mexico, USA, and attracted another large attendance of delegates from 15 countries worldwide, representing a good cross-section of those involved in jewellery manufacturing from mass manufacture to specialised craft operations. In general, many were finding the market is tougher now than a few years...
Platinum-20% rhodium strengthened by oxides of zirconium and yttrium were prepared by solidification of platinum-rhodium-(zirconium)-yttrium powder which had been internally oxidised. After forging, rolling and annealing, 1 mm plates were obtained. Then the plates were mechanically ground to 50–70 μm from rolling-normal direction, followed by argon ion milling until a hole appeared on the centre of the foil to obtain samples which were characterised by transmission electron microscopy (TEM), combined with thermodynamic analysis. The existence of spherical ZrO2 and Y2O3 particles was verified with platinum and rhodium present as pure metals at the same time. It was found that the deformation behaviour of ZrO2 and Y2O3 particles was quite different during processing, where the former basically maintain their spherical shape and were bonded tightly to matrix, while the latter were compressed along normal direction and form two cracks on both sides of Y2O3 particles along the rolling direction. The differences in hardness and interface bonding properties of these two types of particles are supposed to be the main causes of different deformation behaviour during hot forging and cold rolling.