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1887
Volume 44, Issue 1
  • ISSN: 0032-1400

Abstract

The fabrication of nanostructured materials, such as nanometre-sized particles and wires, which are potential building blocks for tailored metal catalysts and electronic devices, is a major challenge currently being investigated. During the last ten years, “ship-in-bottle” catalyst technology using zeolitic crystals as microsized reactors for the template fabrication of metal clusters, nanoparticles and wires has been developed. This novel technology for cluster manipulation gives an ordered basis for better control of particle size, metal compositions and morphology. A variety of platinum metals carbonyl clusters has been synthesised, extracted and characterised, and transformed into nanoparticles and nanowires encapsulated in micro/mesoporous cavities and channels. The resulting nanostructured platinum metals exhibit higher catalytic performances and stabilities for various catalytic reactions as well as having unique magnetic properties, compared with conventional metals. An overview of this technology and recent developments resulting in excellent catalyst performances are described.

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2000-01-01
2024-03-29
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References

  1. Gates B. C., Gates B. C., (a) Catalyst Design”, ed. Hegedus L. L., Wiley, Chichester, 1987, p. 71; (b) Metal Clusters”, ed. and Moskovits M. Wiley, New York, 1986, p. 283 [Google Scholar]
  2. and Wymann R.Surface Organometallic Chemistry”, eds. Basset J. M., 231, 1988, pp. 7590 [Google Scholar]
  3. Ichikawa M., Ichikawa M., Ichikawa M., (a) Adv. Catall., 1992, 38, 283; (b) CHEMTECH, 1982, 12, 674; (c) Dynamic Aspects in Heterogeneous Catalysis’ in “Dynamic Processes on Solid Surfaces”, ed. and Tamaru K. 1994, pp. 149216 [Google Scholar]
  4. Vahrenkamp H. Adv. Organometal. Chem., 1983, 22, 674 [Google Scholar]
  5. Ichikawa M., and Ichikawa M. (a) Chemisorption and Reactivity on Supported Clusters and Thin Films’, in “Towards an Understanding on Microscopic Processes in Catalysis”, eds. Lambert R. M., Pacchioni G. G., Kluwer Pub., Dordrecht, 1997, pp. 153192; (b) Polyhedron, 1988, 7, 2351 [Google Scholar]
  6. Kawi S., Gates B. C., Clusters and Colloids - From Theory to Application”, ed. and Schmid G. VCH Publisher, New York, 1994, pp. 300372 [Google Scholar]
  7. Maschmeyer T. M., Rey F., Sankar G., Thomas J. M., Ozin G. A., Ozkar S., and Schmidt G. (a) Nature, 1995, 378, 159; (b) Chem. Mater., 1992, 4, 511; (c) Struct, bonding (Berlin), 1985, 62, 51; Mater. Chem. Phys., 1991, 29, 133 [Google Scholar]
  8. Xie Y. C., and Tang Y. Q. Adv. Catal., 1990, 37, 1 [Google Scholar]
  9. Ichikawa M., Rao L. F., Kosugi N., and Fukuoka A. J. Chem. Soc., Faraday Diss., 1989, 87, 232 [Google Scholar]
  10. Rao L. F., Fukuoka A., Kosugi N., Kuroda H., and Ichikawa M. J. Phys. Chem., 1990, 94, 5317 [Google Scholar]
  11. Martinengo S., Chini P., Giordano G., Albano V. G., and Cianti G. J. Organomet. Chem., 1975, 88, 375 [Google Scholar]
  12. Ichikawa M., Rao L. F., Kimura T., and Fukuoka A. J. Mol. Catal., 1990, 62, 15 [Google Scholar]
  13. Kawi S., Gates B. C., Kawi S., Chang J. R., and Gates B. C. (a) J. Chem. Soc, Chem. Commun., 1991, 904; (b) J. Am. Chem. Soc., 1993, 115, 4830 [Google Scholar]
  14. Sheu L. L., Knozinger H., and Sachder W. M. H. (a) Catal. Lett., 1989, 2, 35; (b) J. Am. Chem. Soc, 1989, 111, 8125 [Google Scholar]
  15. Chen G. C., Shido T., Ichikawa M., Ichikawa M., Liu A. M., Shen G. S., and Shido T. (a) J. Phys. Chem., 1996, 100, 16947; (b) Top. Catal., 1995, 2, 141 [Google Scholar]
  16. Shen G. C., Liu A., Ichikawa M., Liu A.-M., Shido T., and Ichikawa M. (a) J. Chem. Soc., Faraday Trans., 1998, 94, 1353; (b) J. Chem. Soc., Chem. Commun., 1995, 507 [Google Scholar]
  17. Shen G., Shido T., Ichikawa M., Shen J. G. C., Liu A., and Ichikawa M. (a) J. Phys. Chem., 1996, 100, 16947; (b) J. Phys. Chem. B, 1998, 102, 7782 [Google Scholar]
  18. De Mallmann A., and Barthorneuf D. Catal. Lett., 1990, 5, 293 [Google Scholar]
  19. Li G. J., Fujimoto T., Fukuoka A., and Ichikawa M. J. Chem. Soc., Chem. Commun., 1991, 1337 [Google Scholar]
  20. Li G. J., Fujimoto T., Fukuoka A., and Ichikawa M. Catal. Lett., 1992, 12, 171 [Google Scholar]
  21. Beck J. S., Sartuli J. C., Roth W. J., Leonowicz C. T., and Kreag S. K. J. Am. Chem. Soc., 1992, 114, 10843 [Google Scholar]
  22. Yanagisawa T., Shimizu T., Kuroda K., Kato C., Inagaki Y., Fukushima Y., and Kuroda K. Bull. Chem. Soc. Jpn., 1990, 62, 763; J. Chem. Soc., Chem. Commun., 1993, 680 [Google Scholar]
  23. Yamamoto T., Shido T., Inagaki S., Fukushima Y., and Ichikawa M. J. Am. Chem. Soc., 1996, 118, 5810 [Google Scholar]
  24. Yamamoto T., Shido T., Inagaki S., Fukushima Y., and Ichikawa M. J. Phys. Chem. B, 1998, 102, 3866 [Google Scholar]
  25. Fukuoka A., Rao L. F., Kosugi N., Kuroda H., and Ichikawa M. Appl. Catal., 1988, 50, 295 [Google Scholar]
  26. Shephard D. S., Maschmeyer T., Johnson B. F. G., Thomas J. M., Sankar G., Ozkaya D., Zhou W., Oldroyd R. D., Bell R. G., Shephard D. S., Maschmeyer T., Sankar G., Thomas J. M., Ozkaya D., Johnson B. F. G., Raja R., Oldroyd R. D., and Bell R. G. (a) Angew. Chem., Int. Ed. Engl., 1997, 36, 2242; (b) Chem. Eur. J., 1998, 4, 1214 [Google Scholar]
  27. Fukuoka A., Kimura T., Kosugi N., Kuroda H., Minai Y., Sasaki Y., Tominaga T., and Ichikawa M. J. Catal., 1990, 126, 434 [Google Scholar]
  28. Sasaki M., Osada M., Higashimoto N., Inagaki S., Fukushima Y., Fukuoka A., and Ichikawa M. Micro. Mesoporous Mater., 1998, 21, 597 [Google Scholar]
  29. Sasaki M., Osada M., Higashimoto N., Yamamoto T., Fukuoka A., and Ichikawa M. J. Mol. Catal, A, 1999, 141, 223 [Google Scholar]
  30. Ko C. H., and Ryoo R. Chem. Commun., 1996, 2467 [Google Scholar]
  31. Wang R., Fujimoto T., Shido T., and Ichikawa M. J. Chem. Soc., Chem. Commun., 1992, 962 [Google Scholar]
  32. Fukuoka A., Kimura T., and Ichikawa M. J. Chem. Soc., Chem. Commun., 1988, 428 [Google Scholar]
  33. Ichikawa M., Fukuoka A., and Kimura T. Proc. Int. Congr. Catal., 9th, 1988, Vol. 1, 569 [Google Scholar]
  34. Ichikawa M., Lang A. J., Shriver D. F., Sachtler W. M. H., Sachtler W. M. H., Ichikawa M., Fukuoka A., Ichikawa M., Hriljac J. A., and Shriver D. F. (a) J. Am. Chem. Soc., 1985, 107, (24), 7216; (b) J. Phys. Chem., 1986, 90, 475; (c) Inorg. Chem., 1987, 26, 3643 [Google Scholar]
  35. Rao L. F., Fukuoka A., Ichikawa M., Rao L. F., and Fukuoka A. J. Chem. Soc., Chem. Commun., 1988, 458; Catalytic Science and Technology.”, Proc. 1 st Int. Conf. Adv. Catal. Sci. Technol., Tokvo, 1990, Kodansha-VCH, Vol. 1, 1991, 111116 [Google Scholar]
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