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1887
Volume 8, Issue 2
  • ISSN: 0032-1400

Abstract

It has been shown in a previous article in this journal that the hitherto little studied metals ruthenium and osmium possess catalytic activities which are comparable with those of the other noble Group VIII metals for the hydrogenation of the n-butenes, buta-1,3-diene and acetylene. Further studies have now been made using alumina-supported ruthenium and osmium catalysts for the hydrogenation and deuteration of dimethylacetylene and for the deuteration of ethylene and acetylene. Some of the results from these more recent studies are given in this article and the catalytic properties of ruthenium and osmium are discussed in relation to their position in the periodic table.

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1964-01-01
2024-04-26
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References

  1. Bond G. C., and Webb G. and Platinum Metals Rev., 1962, 6, 12 [Google Scholar]
  2. Hamilton W. M., and Burwell R. L. and Proc. 2nd Inter. Congress on Catalysis (Editions Technip, Paris, 1961), 1, 987 [Google Scholar]
  3. Kemball C.J. Chem. Soc., 1956, p. 735 [Google Scholar]
  4. Wells P. B., and Gray D. W. and unpublished work
  5. Wells P. B., and Thesis Ph.D.University of Hull ( 1961) [Google Scholar]
  6. Winterbottom J. M., and Thesis Ph.D.University of Hull ( 1962) [Google Scholar]
  7. Phillipson J. J.unpublished work
  8. Rooney J. J.J. Catalysis, 1963, 2, 53 [Google Scholar]
  9. Chatt J., and Duncanson L. A. and J. Chem. Soc., 1953, p. 2939 [Google Scholar]
  10. Guy R. G., and Shaw B. L. and Advances in Inorg. and Radiochemistry, 1962, 4, 78130 [Google Scholar]
  11. Coates G. E.See e.g. “Organometallic Compounds”, (Methuen, London 1956), p. 286 [Google Scholar]
  12. Bond G. C.“Catalysis by Metals”, (Academic Press, New York, 1962) p. 283 [Google Scholar]
  13. Mignolet J. C. P.Discussions Faraday Soc., 1950, 8, 105 [Google Scholar]
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  • Article Type: Research Article
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