Skip to content
1887
  1. Home
  2. A-Z Publications
  3. Platinum Metals Review
  4. Volume 44, Issue 1
  5. Article
Volume 44, Issue 1
  • ISSN: 0032-1400
file format pdf download PDF

Abstract

The fabrication of nanostructured materials, such as nanometre-sized particles and wires, which are potential building blocks for tailored metal catalysts and electronic devices, is a major challenge currently being investigated. During the last ten years, “ship-in-bottle” catalyst technology using zeolitic crystals as microsized reactors for the template fabrication of metal clusters, nanoparticles and wires has been developed. This novel technology for cluster manipulation gives an ordered basis for better control of particle size, metal compositions and morphology. A variety of platinum metals carbonyl clusters has been synthesised, extracted and characterised, and transformed into nanoparticles and nanowires encapsulated in micro/mesoporous cavities and channels. The resulting nanostructured platinum metals exhibit higher catalytic performances and stabilities for various catalytic reactions as well as having unique magnetic properties, compared with conventional metals. An overview of this technology and recent developments resulting in excellent catalyst performances are described.

© Johnson Matthey
Loading

Article metrics loading...

/content/journals/10.1595/003214000X441314
2000-01-01
2024-10-12
Loading full text...

Full text loading...

/deliver/fulltext/pmr/44/1/pmr0044-0003.html?itemId=/content/journals/10.1595/003214000X441314&mimeType=html&fmt=ahah

References

  1. B. C. Gates, B. C. Gates, (a) Catalyst Design”, ed. L. L. Hegedus, Wiley, Chichester, 1987, p. 71; (b) Metal Clusters”, ed. M. Moskovits, Wiley, New York, 1986, p. 283 [Google Scholar]
  2. R. Wymann, “Surface Organometallic Chemistry”, eds. J. M. Basset, 231, 1988, pp. 75–90 [Google Scholar]
  3. M. Ichikawa, M. Ichikawa, M. Ichikawa, (a) Adv. Catall., 1992, 38, 283; (b) CHEMTECH, 1982, 12, 674; (c) Dynamic Aspects in Heterogeneous Catalysis’ in “Dynamic Processes on Solid Surfaces”, ed. K. Tamaru, 1994, pp. 149–216 [Google Scholar]
  4. H. Vahrenkamp, Adv. Organometal. Chem., 1983, 22, 674 [Google Scholar]
  5. M. Ichikawa, M. Ichikawa, (a) Chemisorption and Reactivity on Supported Clusters and Thin Films’, in “Towards an Understanding on Microscopic Processes in Catalysis”, eds. R. M. Lambert, G. G. Pacchioni, Kluwer Pub., Dordrecht, 1997, pp. 153–192; (b) Polyhedron, 1988, 7, 2351 [Google Scholar]
  6. S. Kawi, B. C. Gates, Clusters and Colloids - From Theory to Application”, ed. G. Schmid, VCH Publisher, New York, 1994, pp. 300–372 [Google Scholar]
  7. T. M. Maschmeyer, F. Rey, G. Sankar, J. M. Thomas, G. A. Ozin, S. Ozkar, G. Schmidt, (a) Nature, 1995, 378, 159; (b) Chem. Mater., 1992, 4, 511; (c) Struct, bonding (Berlin), 1985, 62, 51; Mater. Chem. Phys., 1991, 29, 133 [Google Scholar]
  8. Y. C. Xie, Y. Q. Tang, Adv. Catal., 1990, 37, 1 [Google Scholar]
  9. M. Ichikawa, L. F. Rao, N. Kosugi, A. Fukuoka, J. Chem. Soc., Faraday Diss., 1989, 87, 232 [Google Scholar]
  10. L. F. Rao, A. Fukuoka, N. Kosugi, H. Kuroda, M. Ichikawa, J. Phys. Chem., 1990, 94, 5317 [Google Scholar]
  11. S. Martinengo, P. Chini, G. Giordano, V. G. Albano, G. Cianti, J. Organomet. Chem., 1975, 88, 375 [Google Scholar]
  12. M. Ichikawa, L. F. Rao, T. Kimura, A. Fukuoka, J. Mol. Catal., 1990, 62, 15 [Google Scholar]
  13. S. Kawi, B. C. Gates, S. Kawi, J. R. Chang, B. C. Gates, (a) J. Chem. Soc, Chem. Commun., 1991, 904; (b) J. Am. Chem. Soc., 1993, 115, 4830 [Google Scholar]
  14. L. L. Sheu, H. Knozinger, W. M. H. Sachder, (a) Catal. Lett., 1989, 2, 35; (b) J. Am. Chem. Soc, 1989, 111, 8125 [Google Scholar]
  15. G. C. Chen, T. Shido, M. Ichikawa, M. Ichikawa, A. M. Liu, G. S. Shen, T. Shido, (a) J. Phys. Chem., 1996, 100, 16947; (b) Top. Catal., 1995, 2, 141 [Google Scholar]
  16. G. C. Shen, A. Liu, M. Ichikawa, A.-M. Liu, T. Shido, M. Ichikawa, (a) J. Chem. Soc., Faraday Trans., 1998, 94, 1353; (b) J. Chem. Soc., Chem. Commun., 1995, 507 [Google Scholar]
  17. G. Shen, T. Shido, M. Ichikawa, J. G. C. Shen, A. Liu, M. Ichikawa, (a) J. Phys. Chem., 1996, 100, 16947; (b) J. Phys. Chem. B, 1998, 102, 7782 [Google Scholar]
  18. A. De Mallmann, D. Barthorneuf, Catal. Lett., 1990, 5, 293 [Google Scholar]
  19. G. J. Li, T. Fujimoto, A. Fukuoka, M. Ichikawa, J. Chem. Soc., Chem. Commun., 1991, 1337 [Google Scholar]
  20. G. J. Li, T. Fujimoto, A. Fukuoka, M. Ichikawa, Catal. Lett., 1992, 12, 171 [Google Scholar]
  21. J. S. Beck, J. C. Sartuli, W. J. Roth, C. T. Leonowicz, S. K. Kreag, J. Am. Chem. Soc., 1992, 114, 10843 [Google Scholar]
  22. T. Yanagisawa, T. Shimizu, K. Kuroda, C. Kato, Y. Inagaki, Y. Fukushima, K. Kuroda, Bull. Chem. Soc. Jpn., 1990, 62, 763; J. Chem. Soc., Chem. Commun., 1993, 680 [Google Scholar]
  23. T. Yamamoto, T. Shido, S. Inagaki, Y. Fukushima, M. Ichikawa, J. Am. Chem. Soc., 1996, 118, 5810 [Google Scholar]
  24. T. Yamamoto, T. Shido, S. Inagaki, Y. Fukushima, M. Ichikawa, J. Phys. Chem. B, 1998, 102, 3866 [Google Scholar]
  25. A. Fukuoka, L. F. Rao, N. Kosugi, H. Kuroda, M. Ichikawa, Appl. Catal., 1988, 50, 295 [Google Scholar]
  26. D. S. Shephard, T. Maschmeyer, B. F. G. Johnson, J. M. Thomas, G. Sankar, D. Ozkaya, W. Zhou, R. D. Oldroyd, R. G. Bell, D. S. Shephard, T. Maschmeyer, G. Sankar, J. M. Thomas, D. Ozkaya, B. F. G. Johnson, R. Raja, R. D. Oldroyd, R. G. Bell, (a) Angew. Chem., Int. Ed. Engl., 1997, 36, 2242; (b) Chem. Eur. J., 1998, 4, 1214 [Google Scholar]
  27. A. Fukuoka, T. Kimura, N. Kosugi, H. Kuroda, Y. Minai, Y. Sasaki, T. Tominaga, M. Ichikawa, J. Catal., 1990, 126, 434 [Google Scholar]
  28. M. Sasaki, M. Osada, N. Higashimoto, S. Inagaki, Y. Fukushima, A. Fukuoka, M. Ichikawa, Micro. Mesoporous Mater., 1998, 21, 597 [Google Scholar]
  29. M. Sasaki, M. Osada, N. Higashimoto, T. Yamamoto, A. Fukuoka, M. Ichikawa, J. Mol. Catal, A, 1999, 141, 223 [Google Scholar]
  30. C. H. Ko, R. Ryoo, Chem. Commun., 1996, 2467 [Google Scholar]
  31. R. Wang, T. Fujimoto, T. Shido, M. Ichikawa, J. Chem. Soc., Chem. Commun., 1992, 962 [Google Scholar]
  32. A. Fukuoka, T. Kimura, M. Ichikawa, J. Chem. Soc., Chem. Commun., 1988, 428 [Google Scholar]
  33. M. Ichikawa, A. Fukuoka, T. Kimura, Proc. Int. Congr. Catal., 9th, 1988, Vol. 1, 569 [Google Scholar]
  34. M. Ichikawa, A. J. Lang, D. F. Shriver, W. M. H. Sachtler, W. M. H. Sachtler, M. Ichikawa, A. Fukuoka, M. Ichikawa, J. A. Hriljac, D. F. Shriver, (a) J. Am. Chem. Soc., 1985, 107, (24), 7216; (b) J. Phys. Chem., 1986, 90, 475; (c) Inorg. Chem., 1987, 26, 3643 [Google Scholar]
  35. L. F. Rao, A. Fukuoka, M. Ichikawa, L. F. Rao, A. Fukuoka, J. Chem. Soc., Chem. Commun., 1988, 458; Catalytic Science and Technology.”, Proc. 1 st Int. Conf. Adv. Catal. Sci. Technol., Tokvo, 1990, Kodansha-VCH, Vol. 1, 1991, 111–116 [Google Scholar]
/content/journals/10.1595/003214000X441314
Loading
“Ship-in-Bottle” Catalyst Technology
Platinum Metals Review 44, 3 (2000); https://doi.org/10.1595/003214000X441314
/content/journals/10.1595/003214000X441314
/content/journals/10.1595/003214000X441314
Loading

Data & Media loading...

  • Article Type: Research Article

Most Cited Most Cited RSS feed

This is a required field
Please enter a valid email address
Approval was a Success
Invalid data
An Error Occurred
Approval was partially successful, following selected items could not be processed due to error
Please enter a valid_number test