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1887
Volume 44, Issue 3
  • ISSN: 0032-1400

Abstract

Acetic acid is an important industrial commodity chemical, with a world demand of about 6 million tonnes per year and many industrial uses. The preferred industrial method for its manufacture is by the carbonylation of methanol and this accounts for approximately 60 per cent of the total world acetic acid manufacturing capacity. The carbonylation of methanol, catalysed by rhodium, was invented by Monsanto in the 1960s and for 25 years was the leading technology. In 1996 a new, more efficient, process for the carbonylation of methanol was announced by BP Chemicals, this time using an iridium catalyst. This article describes the new process and looks at the ways in which it improves upon the prior technology.

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2000-01-01
2024-06-21
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References

  1. Eby R. T., and Singleton T. C “Applied Industrial Catalysis”, Academic Press, London, 1983, 1, p. 275 [Google Scholar]
  2. Dekleva T. W., and Forster D. Adv. Catal., 1986, 34, 81 [Google Scholar]
  3. Paulik F. E., and Roth J. R. J. Am. Cbem. Soc., 1968, 1578 [Google Scholar]
  4. Shultz R. G. U.S. Votent, 3, 717, 670; 1973 [Google Scholar]
  5. Vercauteren C. J. E., Clode K. E., and Watson D. J. European Patent, 616, 997; 1994 [Google Scholar]
  6. Maitlis P. M., Haynes A., Sunley G. J., and Howard M. J. J. Cbem. Soc., Dalton Trans., 1996, 2187 [Google Scholar]
  7. Baker M. J., Giles M. F., Garland C. S., and Rafeletos G. European Patent, 749, 948; 1995 [Google Scholar]
  8. Sunley J. G., Giles M. F., and Garland C. S. European Patent, 643, 034; 1994 [Google Scholar]
  9. Garland C. S., Giles M. F., Poole A. D., and Sunley J. G. European Patent, 728, 726; 1994 [Google Scholar]
  10. Singleton T. C., Urry W. H., and Paulik F. E. European Patent, 55, 618; 1982 [Google Scholar]
  11. Paulik F. E., Hershman A, Knox W. R., Shultz R. G., and Roth J. F. European Patent, 5,003, 104; 1988 [Google Scholar]
  12. Smith B. L., Torrence G. P., Aguilo A., and Adler J. S. U.S. Patent, 5,144,068; 1992 [Google Scholar]
  13. Koyama H., and Kojima H. British Patent, 2,146, 637, 1987 [Google Scholar]
  14. Watson D. J. Proc. 17th Conf. Catal. Org. React., ORCS, New Odeans, 29th March-2 April, 1998, Marcel Dekker, New York 1998 [Google Scholar]
  15. Sunley J. G., Ditzel E. J., and Watt R. J. European Patent, 849, 248; 1998 [Google Scholar]
  16. Baker M. J., Giles M. F., Garland C. S., and Muskett M. J. European Patent, 752, 406; 1997 [Google Scholar]
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  • Article Type: Research Article
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