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1887
Volume 44, Issue 4
  • ISSN: 0032-1400

Abstract

It may at first sight seem strange that concepts developed by Albert Einstein in the first decade of the 20th century to explain the structure and dynamics of the cosmos should have any relevance to chemistry. However, it is now quite clear that the chemical behaviour of the heavier elements in particular is dominated by what are termed “relativistic effects”. This article explores the implications of this for the coordination and chemisorption of carbon monoxide and unsaturated hydrocarbons, and their reactions in homogeneous and heterogeneous catalysis involving the platinum group metals.

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2000-01-01
2024-12-23
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References

  1. N. N. Greenwood, A. Earnshaw, Chemistry of the Elements”, 2nd Edn., Butterworth-Heinemann, Oxford, 1997 [Google Scholar]
  2. F. A. Cotton, G. Wilkinson, Advanced Inorganic Chemistry”, 5th Edn., Wiley-Interscience, New York, 1988 [Google Scholar]
  3. G. C. Bond, D. Thompson, Catal. Rev.: Sci. Eng., 1999, 41, 319 [Google Scholar]
  4. D. C. Hoffmann, D. M. Lee, J. Ciem. Educ., 1999, 76, 332 [Google Scholar]
  5. K. S. Pitzer, Acc. Chem. Res., 1979, 12, 271 [Google Scholar]
  6. P. Pyykkö, J.-P. Desclaux, Acc. Chem. Res., 1979, 12, 276 [Google Scholar]
  7. P. Pyykkö, Chem. Rev., 1988, 88, 563 [Google Scholar]
  8. P. Chini, G. Longoni, V. G. Albans, R. West, Adv. Organomet. Chem., (eds. F. G. A. Stone, 1976, 14, 285 [Google Scholar]
  9. E. P. Kündig, M. Moskovits, G. A. Ozin, Can. J. Chem., 1972, 50, 3587 [Google Scholar]
  10. J. Li, G. Schreckenbach, T. Ziegler, J. Am. Chem. Soc., 1995, 117, 486 [Google Scholar]
  11. K. Dückers, P. Bonzel, Surf. Sci., 1989, 213, 25 [Google Scholar]
  12. A. Sandell, P. Bennich, A. Nilsson, B. Hernnäs, O. Björneholm, N. Mårtenson, Surf. Sci., 1994, 310, 16 [Google Scholar]
  13. P. Dumas, R. G. Tobin, P. L. Richards, Surf. Sci., 1986, 171, 555, 579 [Google Scholar]
  14. G. Paccioni, S.-C. Chung, S. Krüger, N. Rosch, Surf. Sci., 1997, 392, 173 [Google Scholar]
  15. J. Li, R. M. Dickson, T. Ziegler, J. Am. Chem. Soc., 1995, 117, 11482 [Google Scholar]
  16. B.-J. Deelman, J. H. Jones, Platinum Metals Rev., 1999, 43, (3), 105; ibid., 2000, 44, (3), 94 [Google Scholar]
  17. N. Sheppard, C. De la Cruz, Adv. Catal, 1996, 41, 1; ibid., 1998, 42, 181 [Google Scholar]
  18. F. Zaera, Chem. Rev., 1995, 95, 2651 [Google Scholar]
  19. E. Yagaski, R. Masel, Specialist Periodical Reports: Catalysis”, Roy. Soc. Chem., London, 1994, Vol. 11, p. 164 [Google Scholar]
  20. C. A. Tolman, W. C. Seidel, G. H. Gerlach, J. Am. Chem. Soc., 1972, 94, 2669 [Google Scholar]
  21. J. Li, G. Schreckenbach, T. Ziegler, Inorg. Chem., 1995, 34, 3245 [Google Scholar]
  22. G. C. Bond, Discuss. Faraday Soc., 1966, 41, 200; Platinum Metals Rev., 1966, 10, (3), 87 [Google Scholar]
  23. A. M. Bradshaw, Surf. Sci., 1995, 331–333, 978 [Google Scholar]
  24. E. M. Stuve, R. J. Madix, J. Phys. Chem., 1985, 89, 105, 3183 [Google Scholar]
  25. V. Gibson, D. Wass, Chem. Br., 1999, 35, (7), 20 [Google Scholar]
  26. G. C. Bond, P. B. Wells, Adv. Catal., 1964, 15, 92 [Google Scholar]
  27. G. C. Bond, Heterogeneous Catalysis – Principles and Applications”, 2nd Edn., OUP, Oxford, 1987 [Google Scholar]
  28. V. I. Savchenko, I. A. Makaryan, Platinum Metals Rev., 1999, 43, (2), 74 [Google Scholar]
  29. T. M. Gentle, E. L. Muetterties, J. Phys. Chem., 1983, 87, 2469 [Google Scholar]
  30. G. C. Bond, J. Mol. Catal. A: Chem., 2000, 156, 1 [Google Scholar]
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