Skip to content
1887
  1. Home
  2. A-Z Publications
  3. Platinum Metals Review
  4. Volume 47, Issue 2
  5. Article
Volume 47, Issue 2
  • ISSN: 0032-1400
file format pdf download PDF

Abstract

Radioactive high-level liquid wastes originating from reprocessing spent nuclear fuel can be a valuable source of platinum metals. The recovery of fission palladium and rhodium is of particular interest and is being investigated worldwide. The radioactivity of fission platinoids is reduced to a non-hazardous level after decontamination from other fission products by a factor of 1010. The intrinsic radioactivity of fission palladium is weak and can be tolerated in many applications, while that of fission rhodium decays to an acceptable level only after storing for about 30 years. With emphasis on recent achievements, this paper, which covers periodical, report and patent literature, reviews the behaviour of fission platinoids in basic separation operations. Aqueous methods, such as solvent extraction, ion exchange, electrolysis, precipitation and redox reactions, are dealt with as well as pyrochemical methods, such as molten salts/metal extraction and solid phase reactions. A second part, to be published in a later issue, considers separation processes.

© Johnson Matthey
Loading

Article metrics loading...

/content/journals/10.1595/003214003X4727487
2003-01-01
2024-12-22
Loading full text...

Full text loading...

/deliver/fulltext/pmr/47/2/pmr0047-0074.html?itemId=/content/journals/10.1595/003214003X4727487&mimeType=html&fmt=ahah

References

  1. “Feasibility of Separation and Utilization of Ruthenium, Rhodium and Palladium from High- Level Wastes”, IAEA Technical Report Series, No. 308, IAEA, Vienna, 1989 [Google Scholar]
  2. B. N. Zaitsev, V. A. Korolev, V. P. Popik, Yu. Z. Prokopchuk, M. N. Chubarov, Radiokbimiya, 1988, 30, (3), 411; Sov. Radiocbem., 1988, 30, (3), 387 [Google Scholar]
  3. F. J. Smith, H. F. McDuffie, Sep. Sci. Technol., 1981, 16, (9), 1071 [Google Scholar]
  4. R. J. Newman, F. J. Smith, Platinum Metals Rev., 1970, 14, (3), 88 [Google Scholar]
  5. H. Koch, A. Schober, Isotopenpraxis, 1976, 12, (2), 49 [Google Scholar]
  6. R. Thompson, 1986
  7. R. P. Bush, Platinum Metals Rev., 1991, 35, (4), 202 [Google Scholar]
  8. V. S. Schmidt, N. A. Shorokhov, At. Energiya, 1988, 64, (2), 103; Sov. At Energy, 1988, 64, (2), 119 [Google Scholar]
  9. W. A. Hoffman Jr., Report ARH-732, Atlantic Richfield Hanford Co., Richland, WA, U.S.A., 1968 [Google Scholar]
  10. E. Blasius, J.-P. Glatz, W. Neumann, Radiochim. Acta, 1981, 29, 159 [Google Scholar]
  11. E. Blasius, H. J. Luxenburger, W. Neumann, Radiochim. Acta, 1984, 36, 149 [Google Scholar]
  12. J. V. Panesko, Report ARH-733, Atlantic Richfield Hanford Co., Richland, WA, U.S.A., 1968 [Google Scholar]
  13. K. P. Lunichkina, E. V. Renard, V. B. Shevchenko, Zh. Neorg. Khim., 1974, 19, (1), 205; Russ. J. Inorg. Chem., 1974, 19, (1), 110 [Google Scholar]
  14. V. S. Shmidt, N. A. Shorokhov, S. S. Novikova, E. G. Teterin, A. N. Panteleeva, Radiokhimiya, 1983, 25, (2), 202; Sov. Radiochem., 1983, 25, (2), 189 [Google Scholar]
  15. E. P. Horwitz, D. G. Kalina, H. Diamond, G. F. Vandegrift, W. W. Schulz, Solvent Extr. Ion Exch., 1985, 3, (1–2), 75 [Google Scholar]
  16. G. H. Rizvi, J. N. Mathur, M. S. Murali, R. H. Iyer, Sep. Sci. Technol, 1996, 31, (13), 1805 [Google Scholar]
  17. J. P. Shukla, R. K. Singh, S. R. Sawant, N. Varadarajan, Anal. Chim. Acta, 1993, 276, 181 [Google Scholar]
  18. O. Courson, M. Lebrun, R. Malmbeck, G. Pagliosa, K. Römer, B. Sätmark, J.-P. Glatz, Radiochim. Acta, 2000, 88, 857 [Google Scholar]
  19. A. N. Turanov, V. K. Karandashev, V. E. Baulin, Zh. Neorg. Khim., 2000, 45, (7), 1259; Russ. J. Inorg. Chem., 2000, 45, (7), 1145 [Google Scholar]
  20. V. S. Shmidt, N. A. Shorokhov, S. D. Nikitin, Zh. Neorg. Khim., 1986, 31, (4), 998; Russ. J. Inorg. Chem., 1986, 31, (4), 568 [Google Scholar]
  21. V. Guyon, J. Foos, A. Guy, T. Moutarde, R. Chomel, M. Draye, M. Lemaire, Sep. Sci. Technol., 1995, 30, (7–9), 1961 [Google Scholar]
  22. K. Kirishima, H. Shibayama, H. Nakahira, H. Shimauchi, M. Myochin, Y. Wada, K. Kawase, Y. Kishimoto, Proc. Int. Conf. Nucl. Waste Management Environ. Remed., 5–11 Sept., 1993, Prague, Czech Rep., ASME, New York, NY, U.S.A., 1993, Vol. 1, p. 667 [Google Scholar]
  23. M. Wisniewski, J. Szymanowski, G. Cote, E. Meissner, J. Chem. Tech. Biotechnol., 1994, 60, 31 [Google Scholar]
  24. G. Cote, D. Bauer, S. Daamach, C. R. Acad. Sci. Paris, Ser. II, 1988, 306, 571 [Google Scholar]
  25. V. G. Torgov, V. V. Tatarchuk, I. A. Druzhinina, T. M. Korda, A. N. Tatarchuk, E. V. Renard, At. Energiya, 1994, 76, (6), 478; Sov. At. Energy, 1994, 76, (6), 442 [Google Scholar]
  26. L. V. Arseenkov, B. S. Zakharkin, K. P. Lunichkina, E. V. Renard, V. Yu. Rogozhkin, N. A. Shorokhov, At. Energiya, 1992, 72, (5), 462; Sov. At. Energy, 1992, 72, (5), 411 [Google Scholar]
  27. D. A. Chowdhury, C. S. Mendoza, S. Kamata, Solvent Extr. Ion Exch., 1994, 12, (5), 1051 [Google Scholar]
  28. T. Ishimori, Y. Kobayashi, Y. Usuba, Bull. Chem. Soc. Jpn., 1968, 41, (6), 1458 [Google Scholar]
  29. K. P. Lunichkina, E. V. Renard, Radiokhimiya, 1974, 16, (2), 268; Sov. Radiochem., 1974, 16, (2), 269 [Google Scholar]
  30. A. M. Rozen, N. A. Kartasheva, Z. N. Nikolotova, Radiokhimiya, 1995, 37, (3), 232; Sov. Radiochem., 1995, 37, (3), 213 [Google Scholar]
  31. A. M. Rozen, Z. N. Nikolotova, N. A. Kartasheva, Radiokhimiya, 1995, 37, (3), 239; Sov. Radiochem., 1995, 37, (3), 220 [Google Scholar]
  32. K. Kimura, Bull Chem. Soc. Jpn., 1960, 33, (8), 1038 [Google Scholar]
  33. S. P. Tandel, S. B. Jadhav, S. P. Malve, Indian J. Chem., Sect. A, Inorg., Bioinotg., Phys. Theor. Anal. Chem., 2001, 40, (10), 1128 [Google Scholar]
  34. Jian-Ming Ouyang, Solvent Extr. Ion Exch., 1999, 17, (5), 1255 [Google Scholar]
  35. Jing Chen, Rongzhou Jiao, Yongjun Zhu, Radiochim. Acta, 1999, 86, 151 [Google Scholar]
  36. S. G. Sarkar, P. M. Dhadke, Indian J. Chem. Technol., 2000, 3, (7), 109 [Google Scholar]
  37. H. Mimura, H. Ohta, H. Hoshi, K. Akiba, Y. Onodera, Sep. Sci. Technol., 2001, 36, (1), 31 [Google Scholar]
  38. Qingxin Rong, H. Freiser, Solvent Extr. Ion Exch., 1987, 5, (5), 923 [Google Scholar]
  39. N. M. Patel, J. R. Thomback, J. H. Miles, Proc. Symp. Extraction ’87: Recovery High Value Metals (EFCE Event No. 347), 23-26 June, 1987, Dounreay, U.K Symp. Series No. 103, Inst. Chem. Eng., Rugby, U.K., 1987, p. 163 [Google Scholar]
  40. V. S. Shmidt, N. A. Shorokhov, S. S. Novikova, Zh. Neorg. Khim., 1984, 29, (3), 773; Russ. J. Inorg. Chem., 1984, 29, (3), 445 [Google Scholar]
  41. V. S. Shmidt, E. A. Mezhov, V. N. Rubisov, L. V. Troyanovskii, N. A. Shorokhov, Radiokhimiya, 1986, 28, (3), 345; Sov. Radiochem., 1986, 28, (3), 311 [Google Scholar]
  42. V. S. Shmidt, N. A. Shorokhov, S. S. Novikova, Radiokhimiya, 1984, 26, (4), 445; Sov. Radiochem., 1984, 26, (4), 426 [Google Scholar]
  43. B. Gorski, M. Beer, L. Russ, Isotopenpraxis, 1988, 24, (5), 200 [Google Scholar]
  44. M. H. Campbell, Anal. Chem., 1968, 40, (1), 6 [Google Scholar]
  45. S. H. Lee, H. Chung, J. Nucl. Sci. Technol, 2000, 37, (3), 281 [Google Scholar]
  46. V. V. Milyutin, S. B. Peshkishev, V. M. Gelis, Radiokhimiya, 1994, 36, (1), 25; Sov. Radiochem., 1994, 36, (1), 26 [Google Scholar]
  47. M. Kubota, Radiochim. Acta, 1993, 63, 91 [Google Scholar]
  48. Y. Yamagishi, M. Kubota, J. Nucl. Sci. Technol., 1993, 30, (7), 717 [Google Scholar]
  49. J. V. Panesko, Report ARH 1552, Atlantic Richfield Hanford Co., Richland, WA, U.S.A., 1970 [Google Scholar]
  50. D. O. Campbell, S. R. Buxton, U.S. Patent 4, 290, 967; 1981 [Google Scholar]
  51. D. O. Campbell, U.S. Patent 3, 979, 498; 1976 [Google Scholar]
  52. Y. Asano, T. Yamamura, H. Tomiyasu, K. Mizumachi, Y. Ikeda, Y. Wada, Proc. Int Topical Meeting Nucl and Hazardous Waste Management (Spectrum ’94), 14–18 Aug., 1994, Atlanta, GA, U.S.A., Am. Nucl Soc., La Grange Park, II, U.S.A., 1994, p. 836 [Google Scholar]
  53. M. Yoneya, Y. Hanamoto, K. Kawamura, H. Igarashi, Y. Miyamoto, Proc. Int. Conf. Future Nucl. Systems: Challenge Towards 2nd Nucl. Era Advanced Fuel Cycles (Global ‘97), 5–10 Oct., 1997, Yokohama, Japan, p. 1501 [Google Scholar]
  54. K. Koizumi, M. Ozawa, T. Kawata, J. Nucl. Sci. Technol., 1993, 30, (11), 1195 [Google Scholar]
  55. M. Ozawa, Y. Tanaka, C. Oohara, H. Tanuma, Proc. Int Conf. Future Nucl. Systems: Challenge Towards 2nd Nucl. Era Advanced Fuel Cycles (Global ’97), 5–10 Oct., 1997, Yokohama, Japan, p. 1232 [Google Scholar]
  56. S. H. Lee, C. H. Jung, J. S. Shon, H. Chung, Sep. Sci. Technol., 2000, 35, (3), 411 [Google Scholar]
  57. E.-H. Kim, J.-H. Yoo, C.-S. Choi, Radiochim. Acta, 1998, 80, 53 [Google Scholar]
  58. E.-H. Kim, D.-Y. Chung, W.-H. Kim, Y.-J. Shin, E. H. Lee, J.-H. Yoo, J. Nucl Sci Technol, 1997, 34, (3), 283 [Google Scholar]
  59. Wu Chuanchu, Liu Yuanfang, Jiang Lingen, J. Nucl. Radiochem. (Chin.), 1986, 8, (3), 147 [Google Scholar]
  60. T. Nishi, N. Uetake, F. Kawamura, H. Yusa, Trans. Am. Nucl Soc., 1987, 55, 242 [Google Scholar]
  61. M. Myochin, K. Kawase, Y. Wada, Y. Kishimoto, M. Ayabe, M. Hatta, K. Arita, Proc. Int Conf. Nucl. Waste Management Environ. Remed., 5–11 Sept, 1993, Prague, Czech Rep., ASME, New York, U.S.A., 1993, Vol. 1, p. 663 [Google Scholar]
  62. H. Moriyama, K. Kinoshita, T. Seshimo, Y. Asaoka, K. Moritani, Y. Ito, Proc. 3rd Int Conf. Nucl. Fucl Reprocessing Waste Management (RECOD ’91), 14–18 Apr., 1991, Sendai, Japan, Vol. 2, p. 639 [Google Scholar]
  63. G. A. Jensen, A. M. Platt, G. B. Mellinger, W. J. Bjorklund, Nucl. Technol, 1984, 65, 305 [Google Scholar]
  64. K. Naito, T. Matsui, H. Nakahira, M. Kitagawa, H. Okada, J. Nucl Mater., 1991, 184, 30 [Google Scholar]
  65. M. Horie, Trans.ENS/ANS-Foratom Conf. (ENC ’90), 23–28 Sept, 1990, Lyon, France. Verlag TÜV Rheinland, Köln, Germany, 1990, Vol. 4, p. 2281 [Google Scholar]
  66. M. Uno, Y. Kadotani, H. Kinoshita, C. Miyake, J. Nucl Sci. Technol, 1996, 33, (12), 973 [Google Scholar]
/content/journals/10.1595/003214003X4727487
Loading
  • Article Type: Research Article

Most Cited Most Cited RSS feed

This is a required field
Please enter a valid email address
Approval was a Success
Invalid data
An Error Occurred
Approval was partially successful, following selected items could not be processed due to error
Please enter a valid_number test