Skip to content
1887
Volume 9, Issue 2
  • ISSN: 0032-1400

Abstract

Complexes made by reacting the platinum group metals with alkyl or aryl phosphines are of considerable potential interest. Many of them are soluble in aromatic or polar aliphatic solvents and are already finding applications as homogenous catalysts. In this paper the methods available for producing the phosphine complexes are reviewed, and details are given of a range of phosphine stabilised hydrido and phosphine stabilised carbonyl hydrido complexes of the metals, all of which have been produced under controlled conditions and are now available in research quantities.

Loading

Article metrics loading...

/content/journals/10.1595/003214065X924750
1965-04-01
2024-03-01
Loading full text...

Full text loading...

/deliver/fulltext/pmr/9/2/pmr0009-0047.html?itemId=/content/journals/10.1595/003214065X924750&mimeType=html&fmt=ahah

References

  1. Hofmann A. W. Ann. Chem. Liebigs, 1857, 103, 357 [Google Scholar]
  2. Cahours A., and Gal H. ibid. 1870, 155, 223, 355 [Google Scholar]
  3. Mann F. G., and Chatt J. J. Chem. Soc. 1938, p. 1949, 2086; [Google Scholar]
  4. 1939, p. 1622
  5. Hieber W., and Heusinger H. J. Inorg. Nucl. Chem., 1957, 4, 179 [Google Scholar]
  6. Malatesta L. J. Chem. Soc, 1955, p. 3924; [Google Scholar]
  7. 1958, 2323; 1963, 2080;
  8. J. Inorg. Nucl. Chem., 1958, 8, 561 [Google Scholar]
  9. Vaska L. J. Amer. Chem. Soc, 1960, 82, 1263; [Google Scholar]
  10. 1961, 83, 756, 1262, 2784;
  11. 1962, 84, 679;
  12. 1964, 86, 1944
  13. Chatt J., and Hayter R. G. (a)J. Chem. Soc, 1961, 896; [Google Scholar]
  14. Chatt J., and Shaw B. L. (b)Chem. Ind., 1960, 931 [Google Scholar]
  15. Chatt J., Shaw B. L., and Field A. E. (c)J. Chem. Soc, 1964, 3466 [Google Scholar]
  16. Heck R.F. J. Amer. Chem. Soc, 1964, 86, 2796 [Google Scholar]
  17. Harrod J. F., and Chalk A. J. J. Amer. Chem. Soc, 1964, 86, 1776 [Google Scholar]
  18. Osborn J. A., Wilkinson G., and Young J. F. Chem. Communications, 1965, 17 [Google Scholar]
  19. Gillard R. D., Osborn J. A., Stockwell R. B., and Wilkinson G. Proc. Chem. Soc, 1964, 284 [Google Scholar]
http://instance.metastore.ingenta.com/content/journals/10.1595/003214065X924750
Loading
/content/journals/10.1595/003214065X924750
Loading

Data & Media loading...

  • Article Type: Research Article
This is a required field
Please enter a valid email address
Approval was a Success
Invalid data
An Error Occurred
Approval was partially successful, following selected items could not be processed due to error