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1887
Volume 13, Issue 2
  • ISSN: 0032-1400

Abstract

The development of electrochemical routes in the industrial production of organic compounds is beginning to attract considerable interest. Already two large-scale processes are in operation, one producing adiponitrile from acrylonitrile, an intermediate step in the manufacture of Nylon 66, and the other producing lead tetra-ethyl anti-knock compounds. This article reviews the basic electrochemistry involved in this type of synthesis and outlines the great possibilities being opened up by advances in technique, in reactor design and in the development of new types of electrode structures in which platinum and its associated metals will play an important part.

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1969-01-01
2024-10-06
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References

  1. F. Haber, Z. Electrochem., 1898, 90, 3263 [Google Scholar]
  2. M. E. Peover, B. S. White, J. Electroanal. Chem., 1967, 13, 93 [Google Scholar]
  3. M. Fleischmann, I. N. Petrov, W. F. K. Wynne, “Electrochemistry—Proceedings of 1st Australian Conference”, Pergamon Press, London, 1964, p. 500 [Google Scholar]
  4. L. L. Miller, A. K. Hoffmann, J. Am. Chem. Soc., 1967, 89, 593 [Google Scholar]
  5. L. Eberson, K. Nyberg, Acta Chim. Scand., 1964, 18, 1567 [Google Scholar]
  6. M. Fleischmann, D. Pletcher, Tetrahedron Letters, 1968, 6255 [Google Scholar]
  7. K. K. Barnes, C. K. Mann, J. Org. Chem., 1967, 32, 1474 [Google Scholar]
  8. F. Lantelme, M. Chemla, Electrochim. Acta, 1965, 10, 657 [Google Scholar]
  9. M. E. Peover, “Electroanal. Chemistry”, Edward Arnold, London, 1967, vol. II, p. 1 [Google Scholar]
  10. M. E. Peover, J. Chem. Soc., 1962, 4540 [Google Scholar]
  11. A. H. Maki, D. H. Geske, J. Am. Chem. Soc., 1961, 83, 1852 [Google Scholar]
  12. M. M. Baizer, J. Electrochem. Soc., 1964, 111, 215 [Google Scholar]
  13. B. C. L. Weedon, Advances in Organic Chem., 1960, 1, 1 [Google Scholar]
  14. T. Okubo, S. Tsutsumi, Bull. Chem. Soc. Japan, 1964, 37, 1794 [Google Scholar]
  15. H. Lehmkuhl, R. Schaefer, K. Ziegler, Chem.-Ing.-Tech., 1964, 36, 612 [Google Scholar]
  16. P. Zuman, D. Barnes, A. Ryvolov, Disc. Faraday Soc., 1968, 45, 202 [Google Scholar]
  17. R. Berkey, S. Wawzonek, E. W. Blaha, M. E. Runner, J. Electrochem. Soc., 1956, 103, 456 [Google Scholar]
  18. M. Finkelstein, R. C. Peterson, S. D. Ross, Electrochim. Acta, 1965, 10, 465 [Google Scholar]
  19. S. H. Langer, H. P. Landi, J. Am. Chem. Soc., 1963, 85, 3043 [Google Scholar]
  20. E. Gileadi, B. Piersma, Butterworths, London, 1966, vol. IV, p. 47
  21. M. Ya. Fioshin, A. J. Kamneva, Sh. M. Itenburg, L. I. Kazakova, Yr. A. Ershov, Khim. Prom., 1963, 263 [Google Scholar]
  22. M. Ya. Fioshin, L. A. Mirkin, L. A. Salmin, A. Kornienko, Zh. Vses. Obshchestva im D. I. Mendeleeva, 1965, 10, 238 [Google Scholar]
  23. E. M. Martlett, Ann. N.Y. Acad. Sci., 1965, 125, 12 [Google Scholar]
  24. J. D. Anderson, M. M. Baizer, J. P. Petrovich, J. Org. Chem., 1966, 31, 3890 [Google Scholar]
  25. B. Wladislaw, H. Viertler, Chem. Ind. (London), 1965, 39 [Google Scholar]
  26. W. J. Koehl, J. Am. Chem. Soc., 1964, 86, 4687 [Google Scholar]
  27. E. J. Corey, N. L. Bauld, R. T. La, J. Casanova, E. T. Kaiser, J. Am. Chem. Soc., 1960, 82, 2645 [Google Scholar]
  28. A. J. Baggerley, R. Brettle, J. Chem. Soc., C, Org., 1968, 2055 [Google Scholar]
  29. N. L. Weinberg, H. R. Weinberg, Chem. Rev., 1968, 68, 449 [Google Scholar]
  30. M. Fleischmann, et al, unpublished work [Google Scholar]
  31. F. Goodridge, R. E. Plimley, I. D. Robb, J. M. Coulson, Brit. Pat. Appln. 16364/67
  32. J. A. M. LeDuc, Chem. Abs., 1967, 24, 43238 p. [Google Scholar]
  33. T. Inoue, S. Tsutsumi, J. Am. Chem. Soc., 1965, 87, 3525 [Google Scholar]
  34. J. Burdon, J. C. Tatlow, “Advances in Fluorine Chemistry”, Butterworths, London, 1960, 1, 129 [Google Scholar]
  35. S. Nagase, Fluorine Chem. Rev., 1967, 1, 77 [Google Scholar]
  36. H. W. Sternberg, R. E. Markby, I. Wender, J. Electrochem. Soc., 1966, 113, 1060 [Google Scholar]
  37. R. A. Benkeser, E. M. Kaiser, J. Am. Chem. Soc., 1963, 85, 2858 [Google Scholar]
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