Homogeneous Catalysis by Some Ruthenium and Rhodium Complexes: A Consideration of the Catalytically Active Species

By David E. Webster; Peter B. Wells

doi:10.1595/003214069X133104110

ISSN: 0032-1400

oa Homogeneous Catalysis by Some Ruthenium and Rhodium Complexes

A Consideration of the Catalytically Active Species
Authors: By David E. Webster¹ and Peter B. Wells¹
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Affiliations: ¹ Department of Chemistry, University of Hull
Source: Platinum Metals Review, Volume 13, Issue 3, Jul 1969, p. 104 - 110
DOI: https://doi.org/10.1595/003214069X133104110
- Published online: 01 Jan 1969

Abstract

One of the most important applications for organometallic compounds is likely to be their use as homogeneous catalysts in the industrial production of organic chemicals. The majority of these catalysts will undoubtedly be complexes of the platinum metals. This article focuses attention on the problems associated with the production and characterisation of catalytically active species formed in solutions of a number of rhodium and ruthenium complexes. Factors determining activity are described and a suggested formulation for an active species is presented.

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References

Report of the Organomctallic Chemistry Panel, The Science Research Council, November 1968
B. Hudson, P. C. Taylor, D. E. Webster, P. B. Wells, Discussions of the Faraday Society, 1968, No. 46, 37 [Google Scholar]
P. C. Taylor, Thesis, University of Hull, 1967
B. Hudson, Thesis, University of Hull, 1969
D. F. Ewing, B. Hudson, D. E. Webster, P. B. Wells, 1969
R. Cramer, J. Amer. Chem. Soc., 1966, 88, 2272 [Google Scholar]
A. Sacco, R. Ugo, A. Moles, J. Chem. Soc., A, 1966, 1670 [Google Scholar]
G. W. Parshall, J. Amer. Chem. Soc., 1968, 90, 1669 [Google Scholar]

/content/journals/10.1595/003214069X133104110

Homogeneous Catalysis by Some Ruthenium and Rhodium Complexes

Platinum Metals Review 13, 104 (1969); https://doi.org/10.1595/003214069X133104110

/content/journals/10.1595/003214069X133104110

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Article Type: Research Article

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oa Homogeneous Catalysis by Some Ruthenium and Rhodium Complexes

A Consideration of the Catalytically Active Species

Abstract

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