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1887
Volume 18, Issue 1
  • ISSN: 0032-1400

Abstract

Very pure metals of the actinide, lanthanide and alkaline earth series can be prepared from their oxides by coupled reduction by hydrogen in the presence of platinum group metals. During the process the platinum group metals form intermetallic phases with the metals from the oxides. These phases are decomposed to yield the pure metals in gaseous form and the platinum group metals in solid form. The pure gaseous metals condense to produce pure solid specimens.

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1974-01-01
2024-11-23
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References

  1. H. G. Diehl, C. Keller, J. Solid State Chem., 1971, 3, 621 [Google Scholar]
  2. B. Erdmann, C. Keller, Inorg. Nucl. Chem. Lett., 1971, 7, 675 [Google Scholar]
  3. B. Erdmann, Kernforschungszentrum Karlsruhe Rept. KFK-1444, 1971 [Google Scholar]
  4. B. Erdmann, C. Keller, J. Solid State Chem., 1973, 7, 40 [Google Scholar]
  5. U. Berndt, B. Erdmann, C. Keller, Angew. Chem., 1972, 84, 537; [Google Scholar]
  6. Angew. Chem. Internat. Ed. En., 1972, 11, 515 [Google Scholar]
  7. U. Berndt, B. Erdmann, C. Keller, U.S. Patent [Google Scholar]
  8. H. Holleck, Kernforschungscentrum Karlsruhe Rept.KF K-1011, 1969 [Google Scholar]
  9. H. Holleck, Oslo, 1969
  10. E. D. Eastman, L. Brewer, L. A. Bromley, P. W. Gilles, N. L. Lofgren, J. Am. Ceram. Soc., 1951, 34, 128 [Google Scholar]
  11. R. A. Mercuri, J. M. Criscione, Abstr. Papers, 158th Mtg., Am. Chem. Soc., 1969, INOR 33 [Google Scholar]
  12. H. Holleck, J. Nucl. Mater., 1968, 28, 339 [Google Scholar]
  13. H. Holleck, H. Kleykamp, J. Nucl. Mater., 1970, 35, 158 [Google Scholar]
  14. G. Grube, M. Flad, Z. Elektrochem., 1942, 48, 377 [Google Scholar]
  15. W. Bronger, W. Klemm, Z. Anorg. Allgem. Chem., 1962, 319, 58 [Google Scholar]
  16. A. S. Darling, G. L. Selman, R. Rushforth, Platinum Metals Rev., 1970, 14, 54 [Google Scholar]
  17. Ibid., 1970, 14, 95
  18. Ibid., 1970, 14, 124
  19. Ibid., 1971, 15, 13
  20. A. S. Darling, Platinum Metals Rev., 1967, 11, 138 [Google Scholar]
  21. W. Bronger, J. Less-common Metals, 1967, 12, 63 [Google Scholar]
  22. R. D. , V, U. S. Rao, J. E. Greedan, W. E. Wallace, R. S. Craig, HutchensJ. Appl. Phys., 1971, 42, 1293 [Google Scholar]
  23. B. Erdmann, GIT, 1972, 16, 1283 [Google Scholar]
  24. M. Hansen, K. Anderko, Constitution of Binary Alloys, McGraw-Hill, New York, 1958, p. 876 [Google Scholar]
  25. B. Erdmann, Messen u. Steuern, 1972, H29, 27 [Google Scholar]
  26. H. Holleck, J. Nucl. Mater., 1972, 42, 278 [Google Scholar]
  27. H. Holleck, Monatsh. Chem., 1971, 102, 1699 [Google Scholar]
  28. N. Schmidt, C. Keller,
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