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1887
Volume 18, Issue 2
  • ISSN: 0032-1400

Abstract

Almost all industrial catalysts are heterogeneous, the reaction taking place on a solid surface. During the past decade homogeneous catalysts, soluble in the liquid phase reactant, have received a great deal of attention, although they have so far found only limited industrial use, chiefly because of the difficulty of their separation from the reaction products. More recently an intermediate type, made by attaching the active metal complex to an insoluble polymer support, has been found to offer a promising new range of catalysts for the future. It is likely that a large proportion of these will be based on the platinum group metals.

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1974-01-01
2024-02-28
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References

  1. Manassen J. Platinum Metals Rev., 1971, 15, (4), 142 [Google Scholar]
  2. Kohler N., and Dawans F. Rev. Inst. Fr. Petrole, 1972, 27, 105 [Google Scholar]
  3. Allum K. G., Hancock R. D., McKenzie S., and Pitkethly R. C. Proc. 5th Internat. Cong. Catalysis, Palm Beach, 1972 [Google Scholar]
  4. Haag W. O., and Whitehurst D. D. Ibid.
  5. Heinemann H. Chem. Tech., 1971, 286 [Google Scholar]
  6. Parshall G. W. J. Am. Chem. Soc. 1972, 94, 8716 [Google Scholar]
  7. Acres G. J. K., Bond G. C., Cooper B. J., and Dawson J. A. J. Catalysis, 1966, 6, 139 [Google Scholar]
  8. Rony P. R. J. Catalysis, 1969, 14, 142 [Google Scholar]
  9. Robinson K. K., Paulik F. E., Hershman A., and Roth J. F. J. Catalysis, 1969, 15, 245 [Google Scholar]
  10. Haag W. O., and Whitehurst D. D. Belgian Patent 721,686, 1969 [Google Scholar]
  11. Lazcano R. L., and Germain J. E. Bull. Soc. Chim. Fr., 1971, 1869 [Google Scholar]
  12. B.P. Co. Ltd., U.S. Patent 3,726,809, 1973 [Google Scholar]
  13. Michalska Z. M., and Webster D. E.
  14. Grubbs R. H., and Kroll L. C. J. Am. Chem. Soc., 1971, 93, 3062 [Google Scholar]
  15. Capka M., Svoboda P., Cerný M., and Hetflejs J. Tetrahedron Lett., 1971, 4787 [Google Scholar]
  16. B.P. Co. Ltd., British Patent 1,277,737, 1972 [Google Scholar]
  17. For example see reference 16
  18. Niebergall H. Makromol. Chem., 1962, 52, 218 [Google Scholar]
  19. B.P. Co. Ltd., British Patent 1,291,237, 1972 [Google Scholar]
  20. B.P. Co. Ltd., British Patent 1,295,673, 1972 [Google Scholar]
  21. B.P. Co. Ltd., Canadian Patent 903,950, 1972 [Google Scholar]
  22. B.P. Co. Ltd., British Patent 1,287,566, 1972 [Google Scholar]
  23. Grubbs R. H., Gibbons C., Kroll L. C., Bonds W. D., and Brubaker C. H. J. Am. Chem. Soc., 1973, 95, 2373 [Google Scholar]
  24. Collman J. P., Hegedus L. S., Cooke M. P., Norton J. R., Dolcetti G., and Marquardt D. N. J. Am. Chem. Soc., 1972, 94, 1789 [Google Scholar]
  25. Manassen J. Israel J. Chem., 1970, 8, 5 p [Google Scholar]
  26. B.P. Co. Ltd., British Patent 1,295,675, 1972 [Google Scholar]
  27. Bruner H. S., and Bailar J. C. J. Am. Chem. Soc., 1972, 49, 533 [Google Scholar]
  28. B.P. Co. Ltd., Dutch Patent 70.06,740, 1970 [Google Scholar]
  29. Svoboda P., Capka M., Chvalovský V., Bazant V., Hetflejs J., Jahr H., and Pracejus H. Angew. Chem., 1972, 12, 153 [Google Scholar]
  30. Capka M., Svoboda P., Kraus M., and Hetflejs J. Chem. & Ind., 1972, 650 [Google Scholar]
  31. B.P. Co. Ltd., British Patent 1,295,674, 1972 [Google Scholar]
  32. B.P. Co. Ltd., British Patent 1,277,736, 1972 [Google Scholar]
  33. Jardine F. H., Osborn J. A., and Wilkinson G. For example, see J. Chem. Soc., A, Inorg. Phys. Theor., 1967, 1574 [Google Scholar]
  34. Grubbs R. H., Kroll L. C., and Sweet E. M. J. Macromol. Sci., 1973, A7, 1047 [Google Scholar]
  35. Bercaw J.E., Marwick R.H., Ball L.G., and Brintzinger H.H. J. Am. Chem. Soc., 1972, 94, 1219 [Google Scholar]
  36. Moffat A. J. J. Catalysis, 1970, 18, 193 [Google Scholar]
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