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1887
Volume 27, Issue 3
  • ISSN: 0032-1400

Abstract

Ruthenium and its complexes can be used to catalyse the oxidation, both homogeneous and heterogeneous, of a wide range of organic substrates. These include olefins, alkynes, arenes, alcohols, aldehydes, ketones, ethers, sulphides, amines, and phosphines. A wide variety of oxidants can be used under mild conditions; conversions and selectivities are usually high, and the catalyst can be easily recovered. Ruthenium can also be used to catalyse the oxidative destruction of pollutants in both gas and liquid phases.

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1983-01-01
2024-11-05
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References

  1. C. Djerassi, R. Engle, J. Am. Chem. Soc., 1953, 75, 3838 [Google Scholar]
  2. L. M. Berkowitz, P. N. Rylander, J. Am. Chem. Soc., 1958, 80, 6682. [Google Scholar]
  3. R. Pappo, A. Becker, Isr. Res. Counc. Bull., 1956, 5A, 300 [Google Scholar]
  4. S. Sarel, Y. Yanuka,, J. Org. Chem., 1959, 24, 2018 [Google Scholar]
  5. P.N. Rylander,, Engelhard Tech. Bull., 1969,9, 135 [Google Scholar]
  6. R. L. Augustine,, “Oxidation” Vol. 1, ed. Marcel Dekker, New York, 1969 [Google Scholar]
  7. T. Yamanaka, Kagaku Kogyo, 1979, 30, (6), 619; [Google Scholar]
  8. Chem. Abstr., 1979, 91, 1129 53 [Google Scholar]
  9. T. Yamanaka, Kagaku Kogyo, 1979, 30, (7), 747; [Google Scholar]
  10. Chem. Abstr., 1979, 91, 1994 60 [Google Scholar]
  11. D. G. Lee, M. van, W. S. Trahanovsky, Oxidation in Organic Chemistry”, Part B, ed. Academic Press, New York, 1973 [Google Scholar]
  12. P. Müller, J. Godoy, Tetrahedron Lett., 1981, 22, (25), 2361 [Google Scholar]
  13. K. B. Sharpless, K. Akashi, K. Oshima, Tetrahedron Lett., 1976, (29), 2503 [Google Scholar]
  14. S. L. Regen, G. M. Whitesides, J. Org. Chem., 1972, 37, (11), 1832 [Google Scholar]
  15. P. H. J. Carlsen, T. Katsuki, V. S. Martin, K. B. Sharpless, J. Org. Chem., 1981, 46, (19), 3936 [Google Scholar]
  16. P. H. J. Carlsen, K. B. Sharpless,
  17. T. A. Foglia, P. A. Barr, A. J. Malloy, M. J. Costanzo, J. Am. Oil Chem. Soc., 1977, 54, (11), 870A [Google Scholar]
  18. K. Kawamoto, T. Yoshioka, European Patent Appl.21, 118; 1981 [Google Scholar]
  19. K. A. Keblys, M. Dubeck, U.S. Patent 3,409,649; 1968 [Google Scholar]
  20. W.-D. Schröer, W. Friedrichsen, Liebigs Ann. Chem., 1978, 1978, (9), 1648 [Google Scholar]
  21. Mitsubishi Petrochemical Co., Ltd., Japanese Patent, 80,087,739; 1980; Chem. Ābstr., 1981, 94, 103012 [Google Scholar]
  22. K. H. Holm, D. G. Lee, L. Skattebøl, Acta Chem. Scand., 1978, B32, (9), 693 [Google Scholar]
  23. M. Schroder, Chem. Rev., 1980, 80, (2), 187 [Google Scholar]
  24. M. E. Pudel, L. G. Privalova, Z. K. Maizus,, L. V. Revenko,, M. L. Khidekel, I. V. Kalechits, Neftekhimiya, 1973, 13, 64 [Google Scholar]
  25. J. O. Turner, J. E. Lyons, German Patent 2,231,678; 1973 [Google Scholar]
  26. B. A. Moyer, M. S. Thompson, T. J. Meyer, J. Am. Chem. Soc., 1980, 102, (7), 2310 [Google Scholar]
  27. S. Cenini, A. Fusi, F. Porta, Gazz. Chim. Ital., 1978, 108, ( 34), 109 [Google Scholar]
  28. H. Gopal, A. J. Gordon, Tetrahedron Lett., 1971, (31), 2941 [Google Scholar]
  29. M. J. Jung, B. W. Metcalf, B. Lippert, P. Casara, Biochem., (Washington), 1978, 17, (13), 2628 [Google Scholar]
  30. D. C. Cronauer, L. G. Baumgard, U.S. Patent 3,865,870; 197 [Google Scholar]
  31. S. N. Massie, U.S. Patent 3,775,472; 1973 [Google Scholar]
  32. D. E. Applequist, J. W. Wheeler, Tetrahedron Lett., 1977, (39), 3411 [Google Scholar]
  33. U. A. Spitzer, D. G. Lee, J. Org. Chem., 1974, 39, (16), 2468 [Google Scholar]
  34. M. Schröder, W. P. Griffith, J. Chem. Soc., Chem. Commun., 1979, (1), 58 [Google Scholar]
  35. M. Matsumoto, S. Ito, J. Chem. Soc., Chem. Commun., 1981, (17), 907 [Google Scholar]
  36. R. S. Givens, D. R. Rademacher, J. Med. Chem., 1974, 17, (4), 457 [Google Scholar]
  37. H. Tomioka, K. Takai, K. Oshima, H. Nozaki, Tetrahedron Lett., 1981, 22, (17), 1605 [Google Scholar]
  38. S. Wolfe, S. K. Hasan, J. R. Campbell, Chem. Commun., 1970, (21), 1420 [Google Scholar]
  39. H. Gopal, T. Adams, R. M. Moriarty, Tetrahedron, 1972, 28, (16), 4259 [Google Scholar]
  40. J. A. Caputo, R. Fuchs, Tetrahedron Lett., 1967, (47), 4729 [Google Scholar]
  41. M. Krumpolc, J. Rocek, Org. Synth., 1981, 60, 20 [Google Scholar]
  42. Y. Sasson, J. Blum, Tetrahedron Lett., 1971, (24), 2167 [Google Scholar]
  43. A. I. Dalton Jr.,, H. J. Doran, R. D. H. Murray,, U.S. Patent 4,225,694; 1980 [Google Scholar]
  44. M. N. Sheng, U.S. Patent 3,997,578; 1976 [Google Scholar]
  45. Mitsui Petrochemical Industries, Ltd., Japanese Patent, 80, 102, 528; 1980; Chem. Abstr., 1981, 94, 46774 [Google Scholar]
  46. K. N. Reddy, V. Devi, P. K. Saiprakash, Natl. Acad. Sci. Lett., (India), 1981, 4, (7), 297; [Google Scholar]
  47. Chem. Abst., 1982, 96, 85864 [Google Scholar]
  48. G. Descotes, J. P. Praly, D. Sinou, J. Mol. Catal., 1979, 6, (6), 421 [Google Scholar]
  49. P. S. Radhakrishnamurti, D. K. Mahapatro, Ind. J. Chem., 1979, 18A, (1), 53 [Google Scholar]
  50. A. B. Smith III, R. M. Scarborough Jr.,, Synth. Comm., 1980, 10, (3), 205 [Google Scholar]
  51. I. V. Howell, M. A. Ledlie, R. C. Pitkethly, British Patent 1,404,513; 1975 [Google Scholar]
  52. M. A. Ledlie, I. V. Howell, Tetrahedron Lett., 1976, (10), 785 [Google Scholar]
  53. R. Tang, S. E. Diamond, N. Neary, F. Mares, J. Chem. Soc., Chem. Commun., 1978, (13), 562 [Google Scholar]
  54. N. Tangari, V. Tortorella, J. Chem. Soc., Chem. Commun., 1975, (3), 71 [Google Scholar]
  55. J. C. Sheehan, R. W. Tulis, J. Org. Chem., 1974, 39, (15), 2264 [Google Scholar]
  56. D. M. Piatak, H. B. Bhat, E. Caspi, J. Org. Chem., 1969, 34, (1), 112 [Google Scholar]
  57. D. M. Piatak, O. Ekundayo, Steroids, 1973, 21, 475 [Google Scholar]
  58. D. C. Ayres, C. M. Scott, Environ. Sci. Technol., 1979, 13, (11), 1383 [Google Scholar]
  59. V. Cariati, V. Viani, British Patent 1,549,363; 1979 [Google Scholar]
  60. N. Okada, Y. Nakanishi, Y. Harada, German Patent 2,735,892; 1978 [Google Scholar]
  61. Osaka Gas Co., Ltd., Japanese Patent 80,086,854; 1980, Chem. Abstr., 1980, 93, 244898 [Google Scholar]
  62. D.C. Ayres,, Platinum Metals Rev., 1981, 25, (4), 160 [Google Scholar]
  63. K. Yang, J. F. Scamehorn, J. D. Reedy, R. C. Lindberg, German Patent 2,640,906; 1977 [Google Scholar]
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