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1887
Volume 28, Issue 3
  • ISSN: 0032-1400

Abstract

Recent work at the Johnson Matthey Research Centre has thrown fresh light upon the electronic effects in hydrogenation catalysis that underlie the whole nature of the catalytic act and in particular many of the effects that may manifest themselves as support metal interactions. The results show that currently accepted models of the catalytic act are incomplete, that ionic intermediates are sometimes important and that both the relative acidity of the reaction system and the redox potential of products and intermediates must be considered.

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/content/journals/10.1595/003214084X28398106
1984-01-01
2024-03-02
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References

  1. Studies in Surface Science and Catalysis; 11. Metal-Support and Metal-Additive Effects in Catalysis”, ed. Imelik B. Elsevier, Amsterdam, 1982 [Google Scholar]
  2. Tri Tran Mahn, Massardier J., Gallezot P., and Imelik B. 141148
  3. Sokolskii D. V. Hydrogenation in Solutions”, Akademii Nauk Kazahkskoi SSR, Alma-Ata 1962, translated by the Israel Program of Scientific Translations, Jerusalem, 1964 [Google Scholar]
  4. and Jannes G.Catalysis. Heterogeneous and Homogeneous”, ed. Delmon B., Elsevier, Amsterdam, 1975 [Google Scholar]
  5. Berglin T., and Schöön N.-H. Ind. Eng. Chem., Process Des. Dev., 1983, 22, (1), 150153 [Google Scholar]
  6. Beck F. Ber. Bunsenges Phys. Chem., 1965, 69, (3), 199206 [Google Scholar]
  7. Pourbaix M. Atlas of Electrochemical Equilibria in Aqueous Solutions”, Pergamon, Oxford, 1966 [Google Scholar]
  8. Birkett M. D., Kuhn A. T., and Bond G. C. Catalysis, Volume 6”, A Specialist Periodical Report, Royal Society of Chemistry, 1983, pp. 6189 [Google Scholar]
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  • Article Type: Research Article
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