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1887
Volume 31, Issue 3
  • ISSN: 0032-1400

Abstract

Since the original demonstrations of homogeneous organometallic catalysis under mild conditions in the 1960s there has been much progress. A central focus for development has been asymmetric synthesis, through the use of optically active ligands. Chiral chelating biphosphines have played a key role in these advances, which have led to: asymmetric hydrogenation as a route to amino-acids and Vitamin E precursors, kinetic resolution in directed hydrogenation, asymmetric isomerisation of olefins in a route to citronellol, and asymmetric catalytic C-C bond formation. This review highlights recent developments.

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1987-01-01
2024-12-21
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References

  1. R.H. Crabtree, Acc. Chem. Res., 1979, 12, (9), 331 [Google Scholar]
  2. B. M. Trost, T. R. Verhoeven, “Comprehensive Organometallic Chemistry”, [Google Scholar]
  3. G. Wilkinson, F. G. A. Stone, E. W. Abel, ed. Pergamon, Oxford, 1982, 8, p. 799
  4. P. R. Auburn, P. B. Mackenzie, B. Bosnich, J. Am. Chem. Soc., 1985, 107, (7), 2033; [Google Scholar]
  5. P. B. Mackenzie, J. Whelan, B. Bosnich, ibid., 1985, 107, (7), 2046
  6. T. Hayashi, A. Yamamoto, T. Hagihara, Y. Ito, Tetrahedron Lett., 1986, 27, (2), 191; [Google Scholar]
  7. T. Hayashi, A. Yamamoto, Y. Ito, J. Chem. Soc., Chem. Commun., 1986, (14), 1090; [Google Scholar]
  8. T. Hayashi, A. Yamamoto, Y. Ito, Chem. Lett., 1987, (1), 177 [Google Scholar]
  9. T. Hayashi, M. Kumada, For a general discussion see “Asymmetric Synthesis”, [Google Scholar]
  10. J. D. Morrison, ed. Academic Press, 1985, 5, p. 147 ff.
  11. T. Hayashi, M. Konishi, Y. Okamoto, K. Kabeta, M. Kumada, J. Org. Chem., 1986, 51, (20), 3772 [Google Scholar]
  12. H. B. Kagan, T. P. Dang, J. Am. Chem. Soc., 1972, 94, (18), 6429 [Google Scholar]
  13. C. R. Landis, J. Halpern, J. Am. Chem. Soc., 1987, 109, (6), 1746; [Google Scholar]
  14. J. M. Brown, P. J. Maddox, J. Chem. Soc., Chem. Commun., 1987, in press; [Google Scholar]
  15. J. M. Brown, P. A. Chaloner, “Homogeneous Catalysis with Metal Phosphine Complexes”, [Google Scholar]
  16. ed. L. H. Pignolet, Plenum Press, New York, 1983, p. 137
  17. J. M. Brown, Angew. Chem. Int. Ed. Engl., 1987, 26, (3), 190, and references therein [Google Scholar]
  18. A. Miyashita, A. Yasuda, H. Takaya, K. Toriumi, T. Ito, T. Souchi, R. Noyori, (a)J. Am. Chem. Soc., 1980, 102, (27), 7932; [Google Scholar]
  19. T. Ikariya, Y. Ishii, H. Kawano, T. Awai, M. Saburi, S. Yoshikawa, S. Akutagawa, (b)J. Chem. Soc., Chem. Commun., 1985, (13), 922; [Google Scholar]
  20. R. Noyori, M. Ohta, Y. Hsiao, M. Kitamura, T. Ohta, H. Takaya, J. Am. Chem. Soc., 1986, 108, (22), 7117; [Google Scholar]
  21. H. Takaya, T. Ohta, N. Sayo, H. Kumobayashi, S. Akutagawa, S. Inoue, I. Kasahara, R. Noyori, (c)J. Am. Chem. Soc., 1987, 109, (5), 1596 [Google Scholar]
  22. K. Tani, T. Yamagata, S. Akutagawa, H. Kumobayashi, T. Taketomi, H. Takaya, A. Miyashita, R. Noyori, S. Otsuka, J. Am. Chem. Soc., 1984, 106, (18), 5208 [Google Scholar]
  23. G. Consiglio, P. Pino, L. I. Flowers, C. U. Pittman, J. Chem. Soc., Chem. Commun., 1983, (11), 612; [Google Scholar]
  24. C. U. Pittman, Y. Kawabata, L. I. Flowers, ibid., 1982, (9), 473
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