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1887
Volume 32, Issue 2
  • ISSN: 0032-1400

Abstract

Organometallic polymer research offers many potential academic and industrial rewards because of the number of elemental variations possible. Unfortunately, there are no general synthetic methods as found for carbon based polymers. Transition metal catalysed dehydrocoupling reactions may prove to be generally applicable to the synthesis of silicon based organometallic polymers. We report here our efforts to synthesise organometallic polymers with a silicon-nitrogen backbone, polysilazanes, using the dehydrocoupling reaction. We also describe the synthesis of polysilazanes for use as precursors to silicon nitride.

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1988-01-01
2024-06-21
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References

  1. Wynne K. J., and Allcock H. R. See for example “Inorganic and Organometallic Polymers”, Am. Chem. Soc. Symp. Ser., ed. Zeldin M., 1988, Vol. 360 [Google Scholar]
  2. Laine R. M., and Blum Y. D.
  3. Curtis M. D., and Epstein P. S. Adv. Organomet. Chem., 1981, 19, 213 [Google Scholar]
  4. Aitken C. A., Harrod J. F., and Samuel E. J. Am. Chem. Soc., 1986, 108, 4059 [Google Scholar]
  5. Seyferth D., Wiseman G. H., “Ultrastructure Processing of Ceramics, Glasses and Composites”, ed. Hench L. L., and Ulrich D. R. 1984, pp. 265275, and references therein
  6. Zoeckler M. T., and Laine R. M. J. Org. Chem., 1983, 48, 2539 [Google Scholar]
  7. Blum Y. D., and Laine R. M. Organometallics, 1986, 5, 2801 [Google Scholar]
  8. Blum Y. D., Laine R. M., Schwartz K. B., Rowcliffe D. J., Bening R. C., Cotts D. B., “Better Ceramics Through Chemistry II”, Mat. Res. Symp. Proc., Vol. 73, ed. Brinker C. J., Clark D. E., and Ulrich D. R. 1986, pp. 389394 [Google Scholar]
  9. Laine R. M., Blum Y. D., Hamlin R. D., Chow A., and Ulrich D. R. “Organometallic Polymers as Precursors to Ceramic Materials: Silicon Nitride and Silicon Oxynitride”, “Ultrastructure Processing of Ceramics, Glasses and Composites II”, ed. Mackenzie D. J., 1988, in press
  10. Biran C., Blum Y. D., Laine R, M., Glaser R., and Tse D. S.
  11. Eisendtadt A., Giandomenico C., Fredericks M. F., and Laine R. M. Organometallics, 1985, 4, 2033 [Google Scholar]
  12. Laine R. M., and Balavoine G.
  13. Laine R. M., Blum Y., Tse D., and Glaser R. op. cit., (Ref. 1), pp. 124142 [Google Scholar]
  14. Chow A. W., Hamlin R. D., Blum Y., and Laine R. M. Polym. Sci., 1986, in press [Google Scholar]
  15. Schwartz K. B., Rowcliffe D. J., Blum Y. D., Laine R. M., “Better Ceramics Through Chemistry II”, Mat. Res. Symp. Proc., Vol. 73, ed. Brinker C. J., Clark D. E., and Ulrich D. R. 1986, pp. 407412 [Google Scholar]
  16. Laine R. M., and Blum Y. D.
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  • Article Type: Research Article
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