Transition Metal Catalysed Synthesis of Oligo- and Polysilazanes: Their Use as Precursors to Silicon Nitride Containing Ceramic Materials

By Richard M. Laine

doi:10.1595/003214088X3226471

ISSN: 0032-1400

oa Transition Metal Catalysed Synthesis of Oligo- and Polysilazanes

Their Use as Precursors to Silicon Nitride Containing Ceramic Materials
By By Richard M. Laine¹
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Affiliations: ¹ The Polymeric Materials Laboratory in the Washington Technology Center and the Department of Materials Science and Engineering, University of Washington,Seattle, U.S.A.
Source: Platinum Metals Review, Volume 32, Issue 2, Apr 1988, p. 64 - 71
DOI: https://doi.org/10.1595/003214088X3226471
- Published online: 01 Jan 1988

Abstract

Organometallic polymer research offers many potential academic and industrial rewards because of the number of elemental variations possible. Unfortunately, there are no general synthetic methods as found for carbon based polymers. Transition metal catalysed dehydrocoupling reactions may prove to be generally applicable to the synthesis of silicon based organometallic polymers. We report here our efforts to synthesise organometallic polymers with a silicon-nitrogen backbone, polysilazanes, using the dehydrocoupling reaction. We also describe the synthesis of polysilazanes for use as precursors to silicon nitride.

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References

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/content/journals/10.1595/003214088X3226471

Transition Metal Catalysed Synthesis of Oligo- and Polysilazanes

Platinum Metals Review 32, 64 (1988); https://doi.org/10.1595/003214088X3226471

/content/journals/10.1595/003214088X3226471

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Article Type: Research Article

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oa Transition Metal Catalysed Synthesis of Oligo- and Polysilazanes

Their Use as Precursors to Silicon Nitride Containing Ceramic Materials

Abstract

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