Skip to content
1887
Volume 35, Issue 1
  • ISSN: 0032-1400

Abstract

Geometrical isomers of platinum(II) and palladium(II) differ substantially in their chemical and biological properties. Under certain conditions one isomeric compound can transform into another. It is essential for chemists to be aware of the probable direction of the isomerisation process, and to predict which isomer is likely to be relatively more stable. The rules in this paper will permit such judgements to be made.

Loading

Article metrics loading...

/content/journals/10.1595/003214091X3512831
1991-01-01
2024-12-21
Loading full text...

Full text loading...

/deliver/fulltext/pmr/35/1/pmr0035-0028.html?itemId=/content/journals/10.1595/003214091X3512831&mimeType=html&fmt=ahah

References

  1. A. Werner, “Lehrbuch der Stereochemie”, Gustav Fischer, Jena, 1904, p. 338 [Google Scholar]
  2. Yu. N. Kukushkin, “Chemistry of Coordination Compounds”, Vysshaya Shkola, Moscow, 1985, p. 455 [Google Scholar]
  3. B. Rosenberg, L. Van, J. E. Trosko, V. H. Mansour, Nature, 1969, 222, (5191), 385 [Google Scholar]
  4. B. Rosenberg, Metal Ions Biol. Syst., 1980, 11, 127 [Google Scholar]
  5. I. I. Chemyaev, V. A. Sokolov, V. A. Palkin, 1954, issue 28, p. 142
  6. Yu. N. Kukushkin, E. S. Postnikova, Zh. Prikl. Khim., 1972, 45, (1), 180 [Google Scholar]
  7. Yu. N. Kukushkin, V. N. Spevak, Zh. Neorg. Khim., 1971, 16, (2), 435 [Google Scholar]
  8. Yu. N. Kukushkin, Koord. Khim., 1979, 5, (12), 1856 [Google Scholar]
  9. Yu. N. Kukushkin, Koord. Khim., 1982, 8, (2), 201 [Google Scholar]
  10. M. P. Brown, R. J. Puddephatt, C. E. E. Upton, S. W. Lavington, J. Chem. Soc., Dalton Trans., 1974, 1613 [Google Scholar]
  11. F. E. Wood, A. L. Batch, Inorg. Chim. Acta, 1983, 76, 163 [Google Scholar]
  12. C. K. Jørgensen, Inorg. Chem., 1964, 3, 1201 [Google Scholar]
  13. J. Auffret, P. Courtot, R. Pichon, J.-Y. Salaun, J. Chem. Soc, Dalton Trans., 1987, 1687 [Google Scholar]
/content/journals/10.1595/003214091X3512831
Loading
  • Article Type: Research Article
This is a required field
Please enter a valid email address
Approval was a Success
Invalid data
An Error Occurred
Approval was partially successful, following selected items could not be processed due to error
Please enter a valid_number test