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Volume 35, Issue 2
  • ISSN: 0032-1400
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Abstract

In recent years much interest has been focused on carbonylation reactions in aqueous or biphasic systems catalysed by platinum group metals complexes. This is due to the reactivity of platinum group metals ions as catalysts designed to activate small molecules. When used in C, chemistry a variety of reactions can be catalysed by these complexes, in particular by ruthenium complexes. Ruthenium has several oxidation states and co-ordination numbers, and is relatively cheap. Additionally, ruthenium catalysts are stable and their reaction conditions are usually mild, making them excellent for homogeneous catalysis. Various reactions of ruthenium carbonyl complexes and ruthenium saloph dichloride complexes with carbon monoxide have been investigated in this laboratory, and are considered here.

© Johnson Matthey
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1991-01-01
2024-11-12
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References

  1. M. T. Gillies, “C1 based chemicals from H, and CO,”Noyes Data Corporation, New Jersey, U.S.A., 1982 [Google Scholar]
  2. M. M. Taqui Khan, A. E. Martell, “Homogeneous Catalysis by Metal Complexes,” Vol. 1, Academic Press, N. Y., 1976 [Google Scholar]
  3. B. Cornils, “New Synthesis with CO,” ed. J. Falbe, Springer, Berlin, 1980, pp. 1–181 [Google Scholar]
  4. Yu. V. Gulerich, N. A. Bumagin, I. P. Beletskaya, J. Tsuji, P. Pino, “Organic Synthesis via Metal Carbonyls,” Vol. 2, ed. I. Wender, Wiley, N. Y., 1977, p. 595; [Google Scholar]
  5. A. Spencer, R. D. Gillard, J. A. McClevet, “Comprehensive Coordination Chemistry,” ed. G. Wilkinson, Pergamon, Oxford, 1987, Ch. 61.2, p. 230 and references therein [Google Scholar]
  6. I. Wender, Catal. Rev. Sci. Eng., 1976, 14, 97; [Google Scholar]
  7. D. Foster, Adv. Organomet. Chem., 1979, 17, 255 [Google Scholar]
  8. M. M. Taqui Khan, G. Ramachandraiah, A. Prakash Rao, Inorg. Chem., 1986, 25, 665 [Google Scholar]
  9. M. M. Taqui Khan, G. Ramachandraiah, R. S. Shukla, Inorg. Chem., 1988, 27, 3274 [Google Scholar]
  10. M. M. Taqui Khan, Amjad Hussain, K. Venkatasubramanian, G. Ramachandraiah, V. Oomen, J. Mol. Catal., 1988, 44, 117 [Google Scholar]
  11. M. M. Taqui Khan, Pure Appl. Chem., 1983, 55, 159 [Google Scholar]
  12. M. M. Taqui Khan, Amjad Hussain, G. Ramachandraiah, M. A. Moiz, Inorg. Chem., 1986, 25, 3023 [Google Scholar]
  13. M. M. Taqui Khan, R. C. Bhardwaj, C. Bhardwaj, J. Chem. Soc, Chem. Commun., 1985, 1690 [Google Scholar]
  14. M. M. Taqui Khan, R. C. Bhardwaj, C. Bhardwaj, Angevo. Chem., Int. Ed. Engl., 1988, 27, 923 [Google Scholar]
  15. M. M. Taqui Khan, S. A. Samad, M. R. H. Siddiqui, J. Mol. Catal., 1989, 53, 23 [Google Scholar]
  16. M. M. Taqui Khan, S. A. Samad, Z. Shirin, M. R. H. Siddiqui, J. Mol Catal., 1989, 54, 81 [Google Scholar]
  17. M. M. Taqui Khan, Z. Shirin, M. R. H. Siddiqui, K. Venkatasubramanian, Inorg. Ckem. (Submitted) [Google Scholar]
  18. M. M. Taqui Khan, S. B. Halligudi, S. Shukla, Angew. Chem., Int. Ed. Engl, 1988, 27, 734 [Google Scholar]
  19. M. M. Taqui Khan, S. B. Halligudi, S. H. R. Abdi, J. Mol. Catal, 1988, 48, 313 [Google Scholar]
  20. M. M. Taqui Khan, S. B. Halligudi, S. H. R. Abdi, S. Shukla, J. Mol. Catal, 1990, 61, 275 [Google Scholar]
  21. M. M. Taqui Khan, S. B. Halligudi, S. H. R. Abdi, J. Mol Catal, 1988, 48, 325 [Google Scholar]
  22. M. M. Taqui Khan, S. B. Halligudi, S. H. R. Abdi, S. Shukla, J. Mol. Catal, 1988, 48, 25 [Google Scholar]
  23. M. M. Taqui Khan, S. B. Halligudi, S. H. R. Abdi, J. Mol. Catal, 1988, 44, 179 [Google Scholar]
  24. M. M. Taqui Khan, S. A. Mirza, A. Prakash Rao, C. Sreelata, J. Mol. Catal, 1988, 44, 107 [Google Scholar]
  25. M. M. Taqui Khan, C. Sreelata, S. A. Mirza, G. Ramachandraiah, S. H. R. Abdi, Inorg. Chem. Acta, 1988, 154, 103 [Google Scholar]
  26. M. M. Taqui Khan, S. B. Halligudi, S. Shukla, A. Shaikh, J. Mol Catal, 1990, 57, 307 [Google Scholar]
  27. M. M. Taqui Khan, S. B. Halligudi, N. Shukla, J. Mol. Catal, 1990, 59, 303 [Google Scholar]
  28. J. S. Stainko, S. Chaipaymgpundu, R. S. Sundberg, R. F. Bryan, I. F. Taylor, H. Taube, J. Am. Chem. Soc, 1970, 92, 5580; J. Am. Chem. Soc, 1974, 96, 381 [Google Scholar]
  29. R. B. Anderson, “Catalysis”, Vol. 4, ed P. H. Emmett, Reinhold, N. Y., 1957, p. 1 [Google Scholar]
  30. P. J. Denny, D. A. Whan, “Catalysis”, Vol. 2, London, 1978, p. 46 [Google Scholar]
  31. A. Dedieu, P. Escaffre, J. M. Frances, P. Kalck, A. Thorez, Nouv. J. Chim., 1986, 10, 631 [Google Scholar]
  32. B. Beson, P. Kalck, A. A. Thorez, European Appl. 179004; [Google Scholar]
  33. P. E. Scaffre, A. Thorez, P. Kalck, J. Chem. Soc., Chem. Commun., 1987, 146 [Google Scholar]
  34. R. G. Arnold, J. A. Nelson, J. J. Verbanc, Chem. Rev., 1957, 57, 47 [Google Scholar]
  35. K. Univerferth, R. Hontsch, K. Schwetlick, J. Prakt. Chem., 1974, 321, 86; [Google Scholar]
  36. S. Fukuoka, M. Chono, M. Kohno, Chemtech, 1984, 14, (11), 670 [Google Scholar]
  37. V. I. M. Yuvenskii, B. K. Nefedov, Russ. Chem. Rev., 1980, 56, 470 [Google Scholar]
  38. G. Mandinelli, M. Nali, B. Rindone, S. Tollari, J. Mol. Catal, 1987, 39, 71 [Google Scholar]
  39. F. Benedini, M. Nali, B. Rindone, S. Tollari, S. Cenini, G. Lamonica, F. Posta, J. Mol Catal, 1986, 34, 155 [Google Scholar]
  40. S. Fukuoka, M. Chono, M. Kohno, J. Chem. Soc, Chem. Commun., 1984, 399 [Google Scholar]
  41. S. Fukuoka, M. Chono, M. Kohno, Chemtech, 1984, 14, (11), 670 [Google Scholar]
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Carbonylation Reactions in Aqueous or Mixed Solvent Systems
Platinum Metals Review 35, 70 (1991); https://doi.org/10.1595/003214091X3527082
/content/journals/10.1595/003214091X3527082
/content/journals/10.1595/003214091X3527082
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  • Article Type: Research Article

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