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1887
Volume 37, Issue 1
  • ISSN: 0032-1400

Abstract

It is well known that the performance of platinum electroplating baths can deteriorate suddenly during operation. This review suggests that 195-platinum nuclear magnetic resonance spectroscopy is a powerful technique for investigating the changes in the composition of the solution that lead to a loss in current efficiency and/or poor deposit quality and, indeed, may be used for the routine monitoring of the state of health of operational baths. This technique can also be used to gain an understanding of the complex chemistry of modern platinum electroplating baths and so assist in the continuing search for commercial baths with superior performance.

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1993-01-01
2024-06-14
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References

  1. Baumgärtner M.E., and Raub Ch. J. Platinum Metals Rev., 1988, 32, (4), 188 [Google Scholar]
  2. Skinner P.E. Platinum Metals Rev., 1989, 33, (3), 102 [Google Scholar]
  3. Johnson Matthey European Appl. 358, 375; 1989 [Google Scholar]
  4. Le Penven R., Pletcher D., and Levason W. J. Appl Eectrochem., 1992, 22, 415 [Google Scholar]
  5. Akitt J. W. Many texts cover FT NMR spectroscopy, see NMR and Chemistry”, 2nd Edn., Chapman and Hall, 1983; [Google Scholar]
  6. Harris R. K. Nuclear Magnetic Resonance Spectroscopy”, Longmans, 1986 [Google Scholar]
  7. Pregosin P. S. Coord Chem. Rev., 1982, 44, 247 [Google Scholar]
  8. Kidd R G., Goodfellow R. J., Harris R. K., and Mann B. E. NMR and the Periodic Table”, eds. Academic Press, London, 1978 [Google Scholar]
  9. Goodfellow R. J., and Mason J. Multinuclear NMR”, ed. Plenum Press, New York, 1987 [Google Scholar]
  10. Pregosin P. S. Transition Metal NMR”, Elsevier, Amsterdam, 1991 [Google Scholar]
  11. Appleton T. G., Hall J. R., and Ralph S. F. Inorg. Chem., 1985, 24, 4685 [Google Scholar]
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  • Article Type: Research Article
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