Skip to content
1887
Volume 37, Issue 1
  • ISSN: 0032-1400

Abstract

It is well known that the performance of platinum electroplating baths can deteriorate suddenly during operation. This review suggests that 195-platinum nuclear magnetic resonance spectroscopy is a powerful technique for investigating the changes in the composition of the solution that lead to a loss in current efficiency and/or poor deposit quality and, indeed, may be used for the routine monitoring of the state of health of operational baths. This technique can also be used to gain an understanding of the complex chemistry of modern platinum electroplating baths and so assist in the continuing search for commercial baths with superior performance.

Loading

Article metrics loading...

/content/journals/10.1595/003214093X3711723
1993-01-01
2024-05-17
Loading full text...

Full text loading...

/deliver/fulltext/pmr/37/1/pmr0037-0017.html?itemId=/content/journals/10.1595/003214093X3711723&mimeType=html&fmt=ahah

References

  1. Baumgärtner M.E., and Raub Ch. J. Platinum Metals Rev., 1988, 32, (4), 188 [Google Scholar]
  2. Skinner P.E. Platinum Metals Rev., 1989, 33, (3), 102 [Google Scholar]
  3. Johnson Matthey European Appl. 358, 375; 1989 [Google Scholar]
  4. Le Penven R., Pletcher D., and Levason W. J. Appl Eectrochem., 1992, 22, 415 [Google Scholar]
  5. Akitt J. W. Many texts cover FT NMR spectroscopy, see NMR and Chemistry”, 2nd Edn., Chapman and Hall, 1983; [Google Scholar]
  6. Harris R. K. Nuclear Magnetic Resonance Spectroscopy”, Longmans, 1986 [Google Scholar]
  7. Pregosin P. S. Coord Chem. Rev., 1982, 44, 247 [Google Scholar]
  8. Kidd R G., Goodfellow R. J., Harris R. K., and Mann B. E. NMR and the Periodic Table”, eds. Academic Press, London, 1978 [Google Scholar]
  9. Goodfellow R. J., and Mason J. Multinuclear NMR”, ed. Plenum Press, New York, 1987 [Google Scholar]
  10. Pregosin P. S. Transition Metal NMR”, Elsevier, Amsterdam, 1991 [Google Scholar]
  11. Appleton T. G., Hall J. R., and Ralph S. F. Inorg. Chem., 1985, 24, 4685 [Google Scholar]
http://instance.metastore.ingenta.com/content/journals/10.1595/003214093X3711723
Loading
/content/journals/10.1595/003214093X3711723
Loading

Data & Media loading...

  • Article Type: Research Article
This is a required field
Please enter a valid email address
Approval was a Success
Invalid data
An Error Occurred
Approval was partially successful, following selected items could not be processed due to error