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Volume 38, Issue 2
  • ISSN: 0032-1400


In this review major developments associated with the synthesis, properties, structure and applications of polymer-immobilised clusters of platinum, palladium, ridium, rhodium, osmium and ruthenium, are presented. Special attention is paid to polymer analogous reactions with metal clusters and new directions involving the polymerisation and copolymerisation of cluster-containing monomers. Some specific features of fixing heterometallic clusters on polymers are examined and the more interesting application of PCNM in catalysis, and future developments in this direction, are discussed.


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