Skip to content
1887
Volume 40, Issue 4
  • ISSN: 0032-1400

Abstract

In 1844 Karl Karlovitch Klaus, then an unknown professor at the University of Kazan, reported his discovery of a new platinum metal which he named ruthenium, afer Ruthenia, the latinised name for Russia. Besides studying the characteristics of ruthenium, Klaus conducted a wide ranging investigation of rhodium, iridium, osmium, and to a lesser extent, palladium and platinum. Thus, he may be regarded as the creator of the chemistry of the platinum metals, and the one who introduced the concept of the structure of the “double salts and bases” of platinum, which was developed some forty years later by Alfred Werner in his co-ordination theory Klaus also discovered the similarities and differences between elements in the triads: ruthenium-rhodium-palladium and osmium-iridium-platinum, so providing the justification for Dmitri Ivanovich Mendeleev to include all six platinum metals in Group VIII of the Periodic System. Klaus’s work thus marked an epoch in the investigation of the platinum metals, especially of ruthenium – the last one to be discovered.

Loading

Article metrics loading...

/content/journals/10.1595/003214096X404181188
1996-01-01
2024-11-25
Loading full text...

Full text loading...

/deliver/fulltext/pmr/40/4/pmr0040-0181.html?itemId=/content/journals/10.1595/003214096X404181188&mimeType=html&fmt=ahah

References

  1. N. N. Uschakova, Karl Karlovitch Klaus”, Nauka, Moscow, 1972, p. 8 [Google Scholar]
  2. Archives AN USSR, Russian Academy Sci., (Leninskii str., 14, 117 071 Moscow), arch. 66, list 2, file 59, p. 29, (Ref. 1,8) [Google Scholar]
  3. Op. cit., (Ref. 1), p. 13
  4. A. Th. Kupfer, Voyage dans l’Ural, entreprie en 1828”, Paris, 1833 [Google Scholar]
  5. Op. cit., (Ref. 1), p. 17
  6. Central State Historical Archives of Estonian SSR, (C.G.I.A. ESSR), arch. 402, University of Dorpat, list 2, file 785, p. 25 (Ref. 1, p. 29) [Google Scholar]
  7. Op. cit., (Ref. 1), p. 39
  8. A. S. Kluchevitch, Karl Karlovitch Klaus”, University of Kazan, 1972, pp. 820 [Google Scholar]
  9. B. N. Meuschutkin, Izv. Inst, po Izucheniju Platini, 1928, 6, p. 6 [Google Scholar]
  10. O. E. Zvyagintsev, K. K. Klaus, Jizni dejtelnost Karla Karlovitcha Klausa” ; in Izbran. trudi po chimii platinovich metallov”, Nauka, Moscow, 1954, 7 [Google Scholar]
  11. D. McDonald, Platinum Metals Rev., 1964, 8, (2), 67 [Google Scholar]
  12. Op. cit., (Ref. 10), pp. 78 [Google Scholar]
  13. K. Klaus, Gorn. Zh., 1845, 7, (3), pp. 157163 [Google Scholar]
  14. A. M. Butlerov, Izbr. trudi, Moscow, 1961, 3, 96 [Google Scholar]
  15. Op. cit., (Ref. 10), p. 8
  16. Op. cit., (Ref. 10), p. 40; Phil. Mag., 1845, 27, 230 [Google Scholar]
  17. C Claus, Bull. Cl. Phys.-Math., Acad. Set. St. Petersbourg, 1845, 3, (20), pp. 311316 [Google Scholar]
  18. Op. cit., (Ref. 17), 1845, 3, (23/24), pp. 353371;
  19. J. Pract. Chem., 1845, 34, (7/8), pp. 420438 [Google Scholar]
  20. Op. cit., (Ref. 17), 1845, 3, (3), pp. 3748;
  21. J. Praku Chem., 1844, (1), 32; Ibid., (8), pp. 479492 [Google Scholar]
  22. K. Klaus, Chimicheskoe issledovanie ostatkov uralskoij platinovoij rudi i metalla ruthenij”, Uch. zan. Kazan University, (Collection of Works), 1844, ( 3) [Google Scholar]
  23. K. Klaus, Chimicheskoe issledovanie ostatkov uralskoij platinovoij rudi i metalla ruthenij”, in “Kazan”, 1845 [Google Scholar]
  24. N. V. Fedorenko, Razvitie issledovanij platinovich metallov v Rossii”, Nauka, Moscow, 1985, pp. 7890 [Google Scholar]
  25. Op. cit., (Ref. 10), p. 83
  26. Jahres-bericht uber die Fortschritte der Chemie und Minerologie von Berzelius, 1845, Jg., 24. p. 28, (Ref. 2, p. 49) [Google Scholar]
  27. Y. I. Soloviyov, Woprosi Istorii Estestvoznanii i Techniki”, 1959, 7, pp. 148149 [Google Scholar]
  28. Op. cit., (Ref. 8), p. 29
  29. Jahres-bericht uber die Fortschritte der Chemie und Mineralogie von Berzelius, 1846, Jg., 25, pp. 205212, (Ref. 2, p. 53) [Google Scholar]
  30. Op. cit., (Ref. 22), pp. 6875
  31. S. I. Ginzburg, N. A. Ezerskaya, I. V. Prokofeva, N. V. Fedorenko, V. I. Shlenskaya, N. K. Belskii, Analytical Chemistry of Platinum Metals”, John Wiley and Sons, New York, 1975 [Google Scholar]
  32. C. Claus, Beitrage zur Chemie der platinmetalle”, Festschrift zur Jubelfeier des 50-Bestehens der Universität Kazan, Dorpat, 1854 [Google Scholar]
  33. Op. cit., (Ref. 10), p. 137
  34. Op. cit., (Ref. 10), p. 227
  35. Op. cit., (Ref. 22), p. 117
  36. Op. cit., (Ref. 10), pp. 241248
  37. D. Mendeleev, Osnovi Chimii”, St. Petersburg, 1871, pp. 833834 [Google Scholar]
  38. K. K. Klaus, Flori mestnii privoljsich stran”, St. Peterburg, 1852; [Google Scholar]
  39. Lokalfloren der Wolgagegenden von Dr C. Claus 8th Beitrage zur Pflanzenkunde des Russischen Reichs”, St. Petersburg, 1851 [Google Scholar]
  40. I. I. Varvinskiy, Gorn. Zh., 1836, 3, (3), pp. 327335 [Google Scholar]
  41. B. S. Yakobi, Gorn. Zh., 1861, pp. 32, 237, 400 [Google Scholar]
  42. Otchet o nauchnoy poezdke professora farmazii K. Klausa”, Nauchnay bibl., Tartusskogo Gos. Universiteta, Otdel rukopisey, Manuskript No. 243, (Ref. 2, p. 86) [Google Scholar]
  43. J. Ministerstva, Narodnogo Prosvescheiy, 1864, Ch. 12, (4–6), pp. 612621, (Ref. 1, p. 91) [Google Scholar]
  44. K. Klaus, Fragment einer monographie des Platins und der Platinmetalle, 1865–1883”, St. Petersburg, 1883, p. 62 [Google Scholar]
/content/journals/10.1595/003214096X404181188
Loading
/content/journals/10.1595/003214096X404181188
Loading

Data & Media loading...

  • Article Type: Research Article
This is a required field
Please enter a valid email address
Approval was a Success
Invalid data
An Error Occurred
Approval was partially successful, following selected items could not be processed due to error
Please enter a valid_number test