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1887
Volume 41, Issue 3
  • ISSN: 0032-1400

Abstract

The syntheses and catalytic behaviour of rhodium catalysts encapsulated in zeolites are reported. Several parameters are investigated in this catalyst system, including the auxiliary ligands and the zeolite supports used. It is demonstrated that the zeolite support can be crucial in determining the types of products formed from catalytic hydroformylation reactions. The results are rationalised in terms of fundamental principles of organometallic chemistry. This enhances the understanding of these catalyst systems at a molecular level and demonstrates that a synergy exists between the development of new, efficient catalyst systems and understanding chemistry at a fundamental level.

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1997-01-01
2024-10-13
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References

  1. B. Cornils, W. A. Herrmann, C. W. Kohlpaintner, Nachr. Chern., Tech. Lab., 1993, 41, 546 [Google Scholar]
  2. D. Evans, J. A. Osborn, G. Wilkinson, J. A. Osborn, J. F. Young, G. Wilkinson, C. H. Slaugh, H. Mulineaux, (a) J. Chem. Soc. (A), 1968, 3133. This paper gives the first complete account of homogeneous rhodium hydroformylation; however, some results were reported earlier by (b) Chem. Commun., 1965, 17 and independently communicated by (c) German Patent Appi.1,186,455; 1961 and U.S. Patent 3, 239, 566; 1966 [Google Scholar]
  3. B. Cornils, L. Marko, “Methoden der Organischen Chemie”, Houben-Weyl, 4th Edn., Vol. E18, Thieme, Stuttgart, New York, 1986, Part 2, p. 759 [Google Scholar]
  4. M. Beller, B. Cornils, W. A. Herrmann, J. Mol Catai. A, 1995, 104, 17 [Google Scholar]
  5. J. K. MacDougall, D. J. Cole-Hamilton, Chem. Commun., 1990, 165 [Google Scholar]
  6. M. C. Simpson, A. W. S. Currie, J. M. Andersen, D. J. Cole-Hamilton, M. J. Green, J. Chem. Soe, Dalton Trans., 1996, 1793 [Google Scholar]
  7. E. Mantovani, N. Palladino, A. Zanobi, J. Mol. Catai, 1977/78, 31, 385 [Google Scholar]
  8. E. J. Rode, M. E. Davis, B. E. Hanson, J. Catai., 1985, 96, 574 [Google Scholar]
  9. A. Fusi, R. Psaro, C. Dossi, L. Garlaschelli, F. Cozzi, J. Mol Catai. A, 1996, 107, 255 [Google Scholar]
  10. D. Kotkar, P. K. Ghosh, Chem. Commun., 1986, 650 [Google Scholar]
  11. J. M. Andersen, A. W S. Currie, Chem. Commun., 1996, 1543 [Google Scholar]
  12. A. W. S. Currie, J. M. Andersen, Catal. Lett., 1997, 44, 109 [Google Scholar]
  13. G. Ozin, S. Ozkar, Chem. Mater., 1992, 4, 511 [Google Scholar]
  14. J. M. Andersen, H. M. A. Hunter,
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