Skip to content
Volume 42, Issue 2
  • ISSN: 0032-1400


Interest is growing in using polymeric electrode materials containing platinum group metals complexes in molecular electrochemistry. Here, the synthesis of functionalised polypyrrole film electrodes, formed by the oxidative electropolymerisation of pyrrole-substituted rhodium, iridium and palladium complexes is reviewed, and recent results are presented concerning the electrocatalytic reduction of protons and the hydrogenation of unsaturated organic substrates in aqueous electrolyte. Metal hydride intermediates and their involvement in reactions at the electrodes are considered, as are preliminary results of asymmetric electrosynthesis on a molecular electrode material.


Article metrics loading...

Loading full text...

Full text loading...

  • Article Type: Research Article
This is a required field
Please enter a valid email address
Approval was a Success
Invalid data
An Error Occurred
Approval was partially successful, following selected items could not be processed due to error