Phosphoramidite-Controlled Asymmetric Hydrogenation with Rhodium Catalysts

By David J. Ager; André H. M. de Vries; Johannes G. de Vries

doi:10.1595/147106706X111582

ISSN: 0032-1400

oa Phosphoramidite-Controlled Asymmetric Hydrogenation with Rhodium Catalysts
Authors: By David J. Ager¹, André H. M. de Vries² and Johannes G. de Vries²
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Affiliations: ¹ DSM, PMB 150, 9650 Strickland Road, Suite 103, Raleigh, NC 27615U.S.A. ² DSM Research, Advanced Synthesis, Catalysis and DevelopmentPO Box 18, 6160 MD, GeleenThe Netherlands
Source: Platinum Metals Review, Volume 50, Issue 2, Apr 2006, p. 54 - 63
DOI: https://doi.org/10.1595/147106706X111582
- Published online: 01 Jan 2006

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Abstract

Phosphoramidites, and in particular those derived from BINOL, the MonoPhos family of ligands, have proven extremely useful for the asymmetric hydrogenation of carbon–carbon unsaturation using a rhodium catalyst. Many classes of alkenes can be reduced by these catalyst systems. The use of high-throughput experimentation can be applied to the synthesis of MonoPhos ligands and their subsequent screening, in order to find an appropriate candidate for a specific transformation. Suitable mixtures of ligands can also be found by these high-throughput methods.

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Phosphoramidite-Controlled Asymmetric Hydrogenation with Rhodium Catalysts

Platinum Metals Review 50, 54 (2006); https://doi.org/10.1595/147106706X111582

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oa Phosphoramidite-Controlled Asymmetric Hydrogenation with Rhodium Catalysts

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