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oa Commercial Development of Palladium(0) Catalysts for Highly Selective Cross-Coupling Reactions
New preformed L2Pd(0) (L = tertiary phosphine) catalysts now available
- Source: Platinum Metals Review, Volume 56, Issue 2, Apr 2012, p. 110 - 116
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- 01 Jan 2012
Abstract
Palladium-catalysed cross-coupling has huge importance for the synthesis of many organic molecules at both laboratory and industrial scale. A range of commercially available preformed (R3P)2Pd(0) catalysts have now been developed and are available from Johnson Matthey. Some unique and highly selective applications of these palladium catalysts for various cross-coupling reactions, including novel reactions such as carbohalogenation reactions, Negishi coupling of aryl chlorides and copper-free Sonogashira coupling, are highlighted in this review.
© Johnson Matthey