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1887
Volume 60, Issue 4
  • ISSN: 2056-5135

Abstract

Natural gas is of increasing interest as an alternative fuel for vehicles and stationary engines that traditionally use gasoline and diesel fuels. Drivers for the adoption of natural gas include high abundance, lower price and reduced greenhouse gas emissions compared to other fossil fuels. Biogas is an option which could reduce such emissions further. The regulations which cap emissions from these engines currently include Euro VI and the US Environmental Protection Agency (EPA) greenhouse gas legislation. The regulated emissions limits for methane, nitrogen oxides (NOx) and particulate matter (PM) for both stoichiometric and lean burn compressed natural gas engines can be met by the application of either palladium-rhodium three-way catalyst (TWC) or platinum-palladium oxidation catalyst respectively. The drivers, policy and growth of this Pd based catalyst technology and its remaining challenges to be overcome in terms of cost and catalyst deactivation due to sulfur, water and thermal ageing are described in this short review.

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2016-01-01
2024-12-22
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References

  1. M. Maedge, ‘Methane as a Vehicle Fuel in Europe’, in: Gaseous Fuels for Road Vehicles, Institution of Mechanical Engineers, London, UK, 11th September, 2014 LINK http://events.imeche.org/ViewEvent?code=S1807 [Google Scholar]
  2. NaturalGas.org: http://naturalgas.org/ (Accessed on 4th July 2016) LINK http://naturalgas.org/overview/background/
  3. A. Demirbas, “Methane Gas Hydrate”, Springer-Verlag, London, UK, 2010 LINK http://dx.doi.org/10.1007/978-1-84882-872-8 [Google Scholar]
  4. ‘Communication From the Commission to the European Parliament, the Council, the European Economic and Social Committee and the Committee of the Regions: A Roadmap for Moving to a Competitive Low Carbon Economy in 2050’, Brussels, Belgium, 8th March, 2011 LINK http://eur-lex.europa.eu/legal-content/EN/TXT/?uri=CELEX:52011DC0112 [Google Scholar]
  5. E. Bourbon, ‘Clean Cities Alternative Fuel Price Report, July 2014’, Energy Efficiency and Renewable Energy, US Department of Energy, Washington, DC, USA, 31st July, 2014 LINK http://www.afdc.energy.gov/uploads/publication/alternative_fuel_price_report_july_2014.pdf [Google Scholar]
  6. E. Bourbon, ‘Clean Cities Alternative Fuel Price Report, October 2015’, Energy Efficiency and Renewable Energy, US Department of Energy, Washington, DC, USA, 10th December, 2015 LINK http://www.afdc.energy.gov/uploads/publication/alternative_fuel_price_report_october_2015.pdf [Google Scholar]
  7. Heavy-Duty Vehicles: GHG Emissions & Fuel Economy, Other Standards and Provisions, Diesel net: https://www.dieselnet.com/standards/us/fe_hd.php (Accessed on 5th July 2016)
  8. EU Emission Standards for Heavy-Duty Diesel and Gas Engines: Transient Testing, Heavy-Duty Truck and Bus Engines, Diesel net: https://www.dieselnet.com/standards/eu/hd.php (Accessed on 4th July 2016)
  9. ‘FACT SHEET: Administration Takes Steps Forward on Climate Action Plan by Announcing Actions to Cut Methane Emissions’, The White House, Office of the Press Secretary, Washington, DC, USA, 14th January, 2015 LINK https://www.whitehouse.gov/the-press-office/2015/01/14/fact-sheet-administration-takes-steps-forward-climate-action-plan-anno-1 [Google Scholar]
  10. E. Jones, ‘EPA Releases First-Ever Standards to Cut Methane Emissions from the Oil and Gas Sector’, US EPA Press Office, Washington, DC, USA, 12th May, 2016 LINK https://www.epa.gov/newsreleases/epa-releases-first-ever-standards-cut-methane-emissions-oil-and-gas-sector [Google Scholar]
  11. E. Kim, H. Han, I. Im, N. Choi, ‘Development of Durable Pd-based Catalyst System for Lean-CNG Application’, in SAE 2014 Light Duty Emissions Control Symposium, Troy, Michigan, USA, 9th–10th December, 2014 LINK http://www.sae.org/events/lde/2014/ [Google Scholar]
  12. ‘Few Transportation Fuels Surpass the Energy Densities of Gasoline and Diesel’, US Energy Information Administration, US Department of Energy, Washington, DC, USA, 14th February, 2013 LINK http://www.eia.gov/todayinenergy/detail.cfm?id=9991 [Google Scholar]
  13. E. F. Sousa-Aguiar, F. B. Noronha, A. Faro Jr, Catal. Sci. Technol., 2011, 1, (5), 698 LINK http://dx.doi.org/10.1039/C1CY00116G [Google Scholar]
  14. S. J. Curran, R. M. Wagner, R. L. Graves, M. Keller, J. B. Green, Energy, 2014, 75, 194 LINK http://dx.doi.org/10.1016/j.energy.2014.07.035 [Google Scholar]
  15. P. van der Gaag, ‘Analysing Challenges of Producing Bio-LNG and Building the Infra for It’, in: Brussels Global Biomethane Congress, Brussels, Belgium, 10th October, 2012 LINK http://european-biogas.eu/wp-content/uploads/files/2013/11/12-Peter-van-der-Gaag-Analysing-Challenges-of-Producing-LBM-That-Is-Fit-to-Use-in-the-Existing-LNG-Distribution-Networks.pdf [Google Scholar]
  16. D. J. van Kasteren, ‘Upgrading Biogas to Bio LNG’, BioenNW, European Bioenergy Research Institute, Eindhoven, Netherlands, 31st October, 2014 LINK http://bioenergy-nw.eu/wp-content/uploads/2015/09/Upgrading-Biogas-to-BioLNG.pdf [Google Scholar]
  17. H. P. van Kemenade, R. J. van Benthum, J. J. H. Brouwers, Energy Technol., 2014, 2, (11), 874 LINK http://dx.doi.org/10.1002/ente.201402072 [Google Scholar]
  18. ‘Detailed carbon intensity data year 7 version 7.0’, in “Renewable Transport Fuel Obligation (RTFO) guidance: year 7”, Department for Transport, London, UK, 8th April, 2014 LINK https://www.gov.uk/government/publications/rtfo-guidance LINK https://www.gov.uk/government/uploads/system/uploads/attachment_data/file/301089/detailed-carbon-intensity-data-yr7.xls [Google Scholar]
  19. T. Rydberg, M. Belhaj, L. Bolin, M. Lindblad, Å. Sjödin, C. Wolf, ‘Market conditions for biogas vehicles’, IVL Report B1947, Swedish Environmental Research Institute, Göteborg, Sweden, 2010 LINK http://www3.ivl.se/rapporter/pdf/B1947.pdf [Google Scholar]
  20. D. Ciuparu, E. Perkins, L. Pfefferle, Appl. Catal. A: Gen., 2004, 263, (2), 145 LINK http://dx.doi.org/10.1016/j.apcata.2003.12.006 [Google Scholar]
  21. P. Gélin, M. Primet, Appl. Catal. B: Environ., 2002, 39, (1), 1 LINK http://dx.doi.org/10.1016/S0926-3373(02)00076-0 [Google Scholar]
  22. M. Honkanen, M. Kärkkäinen, T. Kolli, O. Heikkinen, V. Viitanen, L. Zeng, H. Jiang, K. Kallinen, M. Huuhtanen, R. L. Keiski, J. Lahtinen, E. Olsson, M. Vippola, Appl. Catal. B: Environ., 2016, 182, 439 LINK http://dx.doi.org/10.1016/j.apcatb.2015.09.054 [Google Scholar]
  23. K. Narui, H. Yata, K. Furuta, A. Nishida, Y. Kohtoku, T. Matsuzaki, Appl. Catal. A: Gen., 1999, 179, (1–2), 165 LINK http://dx.doi.org/10.1016/S0926-860X(98)00306-8 [Google Scholar]
  24. A. Ersson, H. Kušar, R. Carroni, T. Griffin, S. Järås, Catal. Today, 2003, 83, (1–4), 265 LINK http://dx.doi.org/10.1016/S0920-5861(03)00247-5 [Google Scholar]
  25. G. Corro, C. Cano, J. L. G. Fierro, J. Mol. Catal. A: Chem., 2010, 315, (1), 35 LINK http://dx.doi.org/10.1016/j.molcata.2009.08.023 [Google Scholar]
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