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1887
Volume 62, Issue 2
  • ISSN: 2056-5135
  • oa Toward Platinum Group Metal-Free Catalysts for Hydrogen/Air Proton-Exchange Membrane Fuel Cells

    Catalyst activity in platinum-free substitute cathode and anode materials

  • Authors: Frédéric Jaouen1, Deborah Jones1, Nathan Coutard2, Vincent Artero2, Peter Strasser3 and Anthony Kucernak4
  • Affiliations: 1 Institut Charles Gerhardt Montpellier, CNRS - Université Montpellier - ENSCM, Place Eugene Bataillon34095 Montpellier cedex 5France 2 Laboratoire de Chimie et Biologie des Métaux, Université Grenoble Alpes, CNRS, CEA, 17 rue des Martyrs38054 Grenoble cedex 9France 3 Technische Universität Berlin, Institut für ChemieStrasse des 17. Juni 124, 10623 BerlinGermany 4 Department of Chemistry, Imperial College LondonSouth Kensington Campus, London, SW7 2AZUK
  • Source: Johnson Matthey Technology Review, Volume 62, Issue 2, Apr 2018, p. 231 - 255
  • DOI: https://doi.org/10.1595/205651318X696828
    • Published online: 01 Jan 2018

Abstract

The status, concepts and challenges toward catalysts free of platinum group metal (pgm) elements for proton-exchange membrane fuel cells (PEMFC) are reviewed. Due to the limited reserves of noble metals in the Earth’s crust, a major challenge for the worldwide development of PEMFC technology is to replace Pt with pgm-free catalysts with sufficient activity and stability. The priority target is the substitution of cathode catalysts (oxygen reduction) that account for more than 80% of pgms in current PEMFCs. Regarding hydrogen oxidation at the anode, ultralow Pt content electrodes have demonstrated good performance, but alternative non-pgm anode catalysts are desirable to increase fuel cell robustness, decrease the H purity requirements and ease the transition from H derived from natural gas to H produced from water and renewable energy sources.

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