Skip to content
1887
  1. Home
  2. A-Z Publications
  3. Johnson Matthey Technology Review
  4. Volume 66, Issue 3
  5. Article
Volume 66, Issue 3
  • ISSN: 2056-5135
file format pdf download PDF

Abstract

There has been recent interest in the potential of nitrides, hydrides and carbides as novel heterogeneous catalysts for the production of ammonia in a sustainable manner on a local scale. It has been proposed that some of these materials can produce ammonia Mars-van Krevelen based mechanistic pathways. Generally, for metal-based heterogeneous catalysts, dissociative nitrogen activation is believed to be the rate determining step in ammonia synthesis. However, associative pathways, which are more akin to enzymatic nitrogen activation, are being increasingly invoked in the literature. Such pathways may provide an opportunity for the development of novel catalysts that operate under milder reaction conditions. This brief overview provides a summary of some of the recent developments in relation to nitrides, carbides and hydrides as applied to ammonia synthesis.

© Johnson Matthey
Loading

Article metrics loading...

/content/journals/10.1595/205651322X16493249558666
2022-04-07
2024-04-25
Loading full text...

Full text loading...

/deliver/fulltext/jmtr/66/3/Hargreaves_16a_Imp.html?itemId=/content/journals/10.1595/205651322X16493249558666&mimeType=html&fmt=ahah

References

  1. Pfromm P. H. J. Renew. Sustain. Energy, 2017, 9, (3), 034702 LINK https://doi.org/10.1063/1.4985090 [Google Scholar]
  2. Wang Q., Guo J., and Chen P. J. Energy Chem., 2019, 36, 25 LINK https://doi.org/10.1016/j.jechem.2019.01.027 [Google Scholar]
  3. ‘Why is There a CO2 Shortage and How Will it Hit Food Supplies?’, BBC, London, UK, 23rd September, 2021 LINK https://www.bbc.co.uk/news/explainers-58626935 [Google Scholar]
  4. Jacobsen C. J. H., Dahl S., Clausen B. S., Bahn S., Logadottir A., and Nørskov J. K. J. Am. Chem. Soc., 2001, 123, (34), 8404 LINK https://doi.org/10.1021/ja010963d [Google Scholar]
  5. Kojima R., and Aika K. Appl. Catal. A: Gen., 2001, 215, (1–2), 149 LINK https://doi.org/10.1016/s0926-860x(01)00529-4 [Google Scholar]
  6. Jacobsen C. J. H. Chem. Commun., 2000, (12), 1057 LINK https://doi.org/10.1039/b002930k [Google Scholar]
  7. Doornkamp C., and Ponec V. J. Mol. Catal. A: Chem., 2000, 162, (1–2), 19 LINK https://doi.org/10.1016/s1381-1169(00)00319-8 [Google Scholar]
  8. Hunter S. M., Mckay D., Smith R. I., Hargreaves J. S. J., and Gregory D. H. Chem. Mater., 2010, 22, (9), 2898 LINK https://doi.org/10.1021/cm100208a [Google Scholar]
  9. Gregory D. H., Hargreaves J. S. J., and Hunter S. M. Catal. Lett., 2011, 141, (1), 22 LINK https://doi.org/10.1007/s10562-010-0464-3 [Google Scholar]
  10. Hunter S. M., Gregory D. H., Hargreaves J. S. J., Richard M., Duprez D., and Bion N. ACS Catal., 2013, 3, (8), 1719 LINK https://doi.org/10.1021/cs400336z [Google Scholar]
  11. Zeinalipour-Yazdi C. D., Hargreaves J. S. J., and Catlow C. R. A. J. Phys. Chem. C, 2015, 119, (51), 28368 LINK https://doi.org/10.1021/acs.jpcc.5b06811 [Google Scholar]
  12. Zeinalipour-Yazdi C. D., Hargreaves J. S. J., and Catlow C. R. A. J. Phys. Chem. C, 2018, 122, (11), 6078 LINK https://doi.org/10.1021/acs.jpcc.7b12364 [Google Scholar]
  13. Ye T.-N., Park S.-W., Lu Y., Li J., Sasase M., Kitano M., Tada T., and Hosono H. Nature, 2020, 583, (7816), 391 LINK https://doi.org/10.1038/s41586-020-2464-9 [Google Scholar]
  14. Ye T.-N., Park S.-W., Lu Y., Li J., Sasase M., Kitano M., and Hosono H. J. Am. Chem. Soc., 2020, 142, (33), 14374 LINK https://doi.org/10.1021/jacs.0c06624 [Google Scholar]
  15. Wang P., Chang F., Gao W., Guo J., Wu G., He T., and Chen P. Nat. Chem., 2017, 9, (1), 64 LINK https://doi.org/10.1038/nchem.2595 [Google Scholar]
  16. Chang F., Guan Y., Chang X., Guo J., Wang P., Gao W., Wu G., Zheng J., Li X., and Chen P. J. Am. Chem. Soc., 2018, 140, (44), 14799 LINK https://doi.org/10.1021/jacs.8b08334 [Google Scholar]
  17. Laassiri S., Zeinalipour-Yazdi C. D., Bion N., Catlow C. R. A., and Hargreaves J. S. J. Faraday Discuss., 2021, 229, 281 LINK https://doi.org/10.1039/c9fd00131j [Google Scholar]
  18. Kobayashi Y., Tang Y., Kageyama T., Yamashita H., Masuda N., Hosokawa S., and Kageyama H. J. Am. Chem. Soc., 2017, 139, (50), 18240 LINK https://doi.org/10.1021/jacs.7b08891 [Google Scholar]
  19. Kitano M., Kujirai J., Ogasawara K., Matsuishi S., Tada T., Abe H., Niwa Y., and Hosono H. J. Am. Chem. Soc., 2019, 141, (51), 20344 LINK https://doi.org/10.1021/jacs.9b10726 [Google Scholar]
  20. Cao Y., Saito A., Kobayashi Y., Ubukata H., Tang Y., and Kageyama H. ChemCatChem, 2020, 13, (1), 191 LINK https://doi.org/10.1002/cctc.202001084 [Google Scholar]
  21. Ooya K., Li J., Fukui K., Iimura S., Nakao T., Ogasawara K., Sasase M., Abe H., Niwa Y., Kitano M., and Hosono H. Adv. Energy Mater., 2020, 11, (4), 2003723 LINK https://doi.org/10.1002/aenm.202003723 [Google Scholar]
  22. Wang Q., Pan J., Guo J., Hansen H. A., Xie H., Jiang L., Hua L., Li H., Guan Y., Wang P., Gao W., Liu L., Cao H., Xiong Z., Vegge T., and Chen P. Nat. Catal., 2021, 4, (11), 959 LINK https://doi.org/10.1038/s41929-021-00698-8 [Google Scholar]
  23. Yiliguma , Park S.-W., Li J., Sasase M., Kitano M., and Hosono H. ACS Catal., 2021, 11, (12), 7595 LINK https://doi.org/10.1021/acscatal.1c01646 [Google Scholar]
  24. Kojima R., and Aika K. Appl. Catal. A: Gen., 2001, 219, (1–2), 141 LINK https://doi.org/10.1016/s0926-860x(01)00676-7 [Google Scholar]
  25. AlShibane I., Daisley A., Hargreaves J. S. J., Hector A. L., Laassiri S., Rico J. L., and Smith R. I. ACS Sustain. Chem. Eng., 2017, 5, (10), 9214 LINK https://doi.org/10.1021/acssuschemeng.7b02168 [Google Scholar]
  26. Al Sobhi S., Bion N., Hargreaves J. S. J., Hector A. L., Laassiri S., Levason W., Lodge A. W., McFarlane A. R., and Ritter C. Mater. Res. Bull., 2019, 118, 110519 LINK https://doi.org/10.1016/j.materresbull.2019.110519 [Google Scholar]
  27. Al Sobhi S., Hargreaves J. S. J., Hector A. L., and Laassiri S. Dalton Trans., 2019, 48, (44), 16786 LINK https://doi.org/10.1039/c9dt03673c [Google Scholar]
  28. Daisley A., Costley-Wood L., and Hargreaves J. S. J. Top. Catal., 2021, 64, (17–20), 1021 LINK https://doi.org/10.1007/s11244-021-01432-1 [Google Scholar]
  29. Wise R. S., and Markel E. J. J. Catal., 1994, 145, (2), 335 LINK https://doi.org/10.1006/jcat.1994.1042 [Google Scholar]
  30. Wise R. S., and Markel E. J. J. Catal., 1994, 145, (2), 344 LINK https://doi.org/10.1006/jcat.1994.1043 [Google Scholar]
http://instance.metastore.ingenta.com/content/journals/10.1595/205651322X16493249558666
Loading
  • Article Type: Research Article

Most Cited Most Cited RSS feed

This is a required field
Please enter a valid email address
Approval was a Success
Invalid data
An Error Occurred
Approval was partially successful, following selected items could not be processed due to error