Skip to content
1887
Volume 66, Issue 2
  • ISSN: 2056-5135

Abstract

This study aims to investigate the interactions between collagen and tanning processes performed by ecol-tan®, phosphonium, EasyWhite Tan®, glutaraldehyde, formaldehyde-free replacement synthetic tannin (syntan), condensed (mimosa) and hydrolysed (tara) vegetable tanning agents as alternatives to conventional basic chromium sulfate, widely used in the leather industry. Collagen stabilisation with tanning agents was determined by comparative thermal analysis methods: differential scanning calorimetry (DSC), thermogravimetric analysis (TGA) and conventional shrinkage temperature () measurement. Analysis techniques and tanning agents were compared and bonding characteristics were ranked by the thermal stabilisation they provided. Chromium tanning agent was also compared with the alternative tanning systems. The results provide a different perspective than the conventional view to provide a better understanding of the relationship between tanning and thermal stability of leather materials.

Loading

Article metrics loading...

/content/journals/10.1595/205651322X16225583463559
2021-06-01
2024-11-23
Loading full text...

Full text loading...

/deliver/fulltext/jmtr/66/2/Karavana_16a_Imp.html?itemId=/content/journals/10.1595/205651322X16225583463559&mimeType=html&fmt=ahah

References

  1. M. Sathish, A. Dhathathreyan, J. R. Rao, ACS Sustain. Chem. Eng., 2019, 7, (4), 3875 LINK https://doi.org/10.1021/acssuschemeng.8b04876 [Google Scholar]
  2. T. Covington, “Tanning Chemistry: The Science of Leather”, The Royal Society of Chemistry, Cambridge, UK, 2009 [Google Scholar]
  3. E. Onem, A. Yorgancioglu, H. A. Karavana, O. Yilmaz, J. Therm. Anal. Calorim., 2017, 129, (1), 615 LINK https://doi.org/10.1007/s10973-017-6175-x [Google Scholar]
  4. A. D. Covington, R. Thomson, ‘The Chemistry of Tanning Materials’, in “Conservation of Leather and Related Materials”, eds. M. Kite, Elsevier Ltd, Abingdon, UK, 2006, pp. 2235 LINK https://doi.org/10.4324/9780080454665-11 [Google Scholar]
  5. Q. Yao, Y. Wang, H. Chen, H. Huang, B. Liu, ChemistrySelect, 2019, 4, (2), 670 LINK https://doi.org/10.1002/slct.201802952 [Google Scholar]
  6. N. Örk, H. Özgünay, M. M. Mutlu, Z. Öndoğan, Tekst. Konf., 2014, 24, (4), 413 LINK https://dergipark.org.tr/en/pub/tekstilvekonfeksiyon/issue/23646/251881 [Google Scholar]
  7. “Future Trends in the World Leather and Leather Products Industry and Trade”, United Nations Industrial Development Organization, Vienna, Austria, 2010, 120 pp LINK https://leatherpanel.org/sites/default/files/publications-attachments/future_trends_in_the_world_leather_and_leather_products_industry_and_trade.pdf [Google Scholar]
  8. B. S. Scopel, C. Baldasso, A. Dettmer, R. M. C. Santana, J. Am. Leather Chem. Assoc., 2018, 113, (4), 122 LINK https://journals.uc.edu/index.php/JALCA/article/view/1522 [Google Scholar]
  9. M. Renner, E. Weidner, H. Geihsler, J. Am. Leather Chem. Assoc., 2013, 108, (8), 289 LINK https://journals.uc.edu/index.php/JALCA/article/view/3485 [Google Scholar]
  10. G. Krishnamoorthy, S. Sadulla, P. K. Sehgal, A. B. Mandal, J. Cleaner Prod., 2013, 42, 277 LINK https://doi.org/10.1016/j.jclepro.2012.11.004 [Google Scholar]
  11. H. A. Karavana, B. Baüaran, A. Aslan, B. O. Bitlisli, G. Gülümser, Tekst. Konf., 2011, 21, (3), 305 [Google Scholar]
  12. Y. Dilek, B. Baüaran, A. Sancakli, B. O. Bitlisli, A. Yorgancioğlu, J. Soc. Leath. Tech. Chem., 2019, 103, (3), 129 [Google Scholar]
  13. R. Aravindhan, B. Madhan, J. R. Rao, J. Am. Leather Chem. Assoc., 2015, 110, (3), 80 LINK https://journals.uc.edu/index.php/JALCA/article/view/3599 [Google Scholar]
  14. V. Beghetto, L. Agostinis, V. Gatto, R. Samiolo, A. Scrivanti, J. Clean. Prod., 2019, 220, 864 LINK https://doi.org/10.1016/j.jclepro.2019.02.034 [Google Scholar]
  15. K. J. Sreeram, R. Aravindhan, J. R. Rao, B. U. Nair, J. Am. Leather Chem. Assoc., 2010, 105, (12), 401 LINK https://journals.uc.edu/index.php/JALCA/article/view/3237 [Google Scholar]
  16. V. J. Sundar, C. Muralidharan, Environ. Process., 2020, 7, (1), 255 LINK https://doi.org/10.1007/s40710-020-00422-x [Google Scholar]
  17. J. M. V. Williams, J. Soc. Leath. Tech. Chem., 2000, 84, 359 [Google Scholar]
  18. T. Bosch, A. M. Manich, J. Carilla, J. Cot, A. Marsal, H. J. Kellert, H. P. Germann, J. Am. Leather Chem. Assoc., 2002, 97, (11), 441 [Google Scholar]
  19. P. Budrugeac, V. Trandafir, M. G. Albu, J. Therm. Anal. Calorim., 2003, 72, (2), 581 LINK https://doi.org/10.1023/a:1024533801497 [Google Scholar]
  20. Y. Wang, J. Guo, H. Chen, Z. Shan, J. Therm. Anal. Calorim., 2010, 99, (1), 295 LINK https://doi.org/10.1007/s10973-009-0561-y [Google Scholar]
  21. C. Carüote, E. Badea, L. Miu, G. Della Gatta, J. Therm. Anal. Calorim., 2016, 124, (3), 1255 LINK https://doi.org/10.1007/s10973-016-5344-7 [Google Scholar]
  22. L. Yang, Y. Liu, Y. Wu, L. Deng, W. Liu, C. Ma, L. Li, J. Therm. Anal. Calorim., 2016, 123, (1), 413 LINK https://doi.org/10.1007/s10973-015-4873-9 [Google Scholar]
  23. P. Budrugeac, J. Therm. Anal. Calorim., 2015, 120, (1), 103 LINK https://doi.org/10.1007/s10973-014-4252-y [Google Scholar]
  24. K. M. Nalyanya, R. K. Rop, A. S. Onyuka, T. Kilee, P. O. Migunde, R. G. Ngumbu, J. Therm. Anal. Calorim., 2016, 126, (2), 725 LINK https://doi.org/10.1007/s10973-016-5535-2 [Google Scholar]
  25. W. Xu, J. Li, F. Liu, Y. Jiang, Z. Li, L. Li, J. Therm. Anal. Calorim., 2017, 128, (2), 1107 LINK https://doi.org/10.1007/s10973-016-5974-9 [Google Scholar]
  26. L. Rosu, C.-D. Varganici, A.-M. Crudu, D. Rosu, J. Therm. Anal. Calorim., 2018, 134, (1), 583 LINK https://doi.org/10.1007/s10973-018-7076-3 [Google Scholar]
  27. P. Yang, X. He, W. Zhang, Y. Qiao, F. Wang, K. Tang, J. Therm. Anal. Calorim., 2017, 127, (3), 2005 LINK https://doi.org/10.1007/s10973-016-5813-z [Google Scholar]
  28. ‘Leather – Physical and Mechanical Tests – Determination of Shrinkage Temperature up to 100oC’, BS EN ISO 3380:2015, British Standards Institution, London, UK, 30th September, 2015 LINK https://doi.org/10.3403/02730702u [Google Scholar]
  29. K. H. Gustavson, “The Chemistry and Reactivity of Collagen”, Academic Press, New York, USA, 1956 [Google Scholar]
  30. Y. Li, Z. H. Shan, S. X. Shao, K. Q. Shi, J. Soc. Leath. Tech. Chem., 2006, 90, (5), 214 [Google Scholar]
  31. S. Shao, K. Shi, Y. Li, L. Jiang, C. Ma, Chin. J. Chem. Eng., 2008, 16, (3), 446 LINK https://doi.org/10.1016/S1004-9541(08)60103-2 [Google Scholar]
  32. R. Li, Y. Z. Wang, Z. H. Shan, M. Yang, W. Li, H. L. Zhu, J. Soc. Leath. Tech. Chem., 2016, 100, (1), 19 [Google Scholar]
  33. V. Plavan, M. Koliada, V. Valeika, J. Soc. Leath. Tech. Chem., 2017, 101, (5), 260 [Google Scholar]
  34. C. Capparucci, F. Gironi, V. Piemonte, Asia-Pac. J. Chem. Eng., 2011, 6, (4), 606 LINK https://doi.org/10.1002/apj.455 [Google Scholar]
  35. Z. Sebestyén, E. Jakab, E. Badea, E. Barta-Rajnai, C. Şendrea, Z. Czégény, J. Anal. Appl. Pyrolysis, 2019, 138, 178 LINK https://doi.org/10.1016/j.jaap.2018.12.022 [Google Scholar]
  36. S. V. Kanth, G. C. Jayakumar, S. C. Ramkumar, B. Chandrasekaran, J. R. Rao, B. U. Nair, J. Am. Leather Chem. Assoc., 2012, 107, (5), 106 LINK https://journals.uc.edu/index.php/JALCA/article/view/3398 [Google Scholar]
  37. E. Onem, G. Gulumser, M. Renner, O. Yesil-Celiktas, J. Supercrit. Fluids, 2015, 104, 259 LINK https://doi.org/10.1016/j.supflu.2015.07.002 [Google Scholar]
  38. R. Saleem, A. Adnan, F. A. Qureshi, Indian J. Chem. Technol., 2015, 22, (1–2), 48 LINK http://nopr.niscair.res.in/handle/123456789/32338 [Google Scholar]
  39. P. Budrugeac, A. Cucos, L. Miu, J. Therm. Anal. Calorim., 2014, 116, (1), 141 LINK https://doi.org/10.1007/s10973-013-3414-7 [Google Scholar]
/content/journals/10.1595/205651322X16225583463559
Loading
/content/journals/10.1595/205651322X16225583463559
Loading

Data & Media loading...

  • Article Type: Research Article
This is a required field
Please enter a valid email address
Approval was a Success
Invalid data
An Error Occurred
Approval was partially successful, following selected items could not be processed due to error
Please enter a valid_number test