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1887
Volume 66, Issue 3
  • ISSN: 2056-5135

Abstract

Most of the global production of ammonia requires fossil fuels and is associated with considerable greenhouse gas emissions. Replacing fossil fuel ammonia with green or zero-carbon ammonia is a major focus for academia, industry and governments. Ammonia is a key component in fertiliser but is also attracting increasing interest as a carbon-free fuel for the maritime sector and as a hydrogen vector. This review describes the use of green (electrolysed) hydrogen in conventional Haber-Bosch plants and predicts adoption of the technology by 2030. Further into the future, direct green ammonia synthesis by electrocatalytic and photocatalytic means may present a cost-effective alternative to the Haber-Bosch process. Electrocatalytic and photocatalytic routes to ammonia are reviewed, the catalytic systems are compared and their potential for meeting the likely demand and cost for ammonia considered.

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2021-10-05
2024-10-09
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References

  1. J. R. Jennings, S. A. Ward, ‘Ammonia Synthesis: Thermodynamics of Ammonia Synthesis: Process Consequences’, in “Catalyst Handbook”, 2nd Edn., ed. M. V. Twigg, CRC Press, Boca Raton, USA, 1996, p. 390 [Google Scholar]
  2. ‘The Future of Food and Agriculture: Trends and Challenges’, Issue 1, Food and Agriculture Organization of the United Nations, Rome, Italy, 2017, 163 pp LINK https://www.fao.org/3/i6583e/i6583e.pdf [Google Scholar]
  3. J. W. Erisman, M. A. Sutton, J. Galloway, Z. Klimont, W. Winiwarter, Nat. Geosci., 2008, 1, (10), 636 LINK https://doi.org/10.1038/ngeo325 [Google Scholar]
  4. M. Aziz, A. T. Wijayanta, A. B. D. Nandiyanto, Energies, 2020, 13, (12), 3062 LINK https://doi.org/10.3390/en13123062 [Google Scholar]
  5. T. Brown, ‘US House Draft Bill Defines Ammonia as Low-Carbon Fuel’, Ammonia Energy Association, New York, USA, 13th February, 2020 LINK https://www.ammoniaenergy.org/articles/us-house-draft-law-includes-ammonia-as-low-carbon-fuel [Google Scholar]
  6. “Ammonia: Zero-Carbon Fertiliser, Fuel and Energy Store: Policy Briefing”, The Royal Society, London, UK, 19th February, 2020, 39 pp LINK https://royalsociety.org/topics-policy/projects/low-carbon-energy-programme/green-ammonia/ [Google Scholar]
  7. T. Ayvalý, S. C. E. Tsang, T. Van Vrijaldenhoven, Johnson Matthey Technol. Rev., 2021, 65, (2), 291 LINK https://www.technology.matthey.com/article/65/2/291-300/ [Google Scholar]
  8. B. Lee, J. Park, H. Lee, M. Byun, C. W. Yoon, H. Lim, Renew. Sustain. Energy Rev., 2019, 113, 109262 LINK https://doi.org/10.1016/j.rser.2019.109262 [Google Scholar]
  9. P. Gilbert, P. Thornley, ‘Energy and Carbon Balance of Ammonia Production from Biomass Gasification’, University of Manchester, UK, 2010, 9 pp, in host publication LINK https://www.research.manchester.ac.uk/portal/files/33615474/FULL_TEXT.PDF [Google Scholar]
  10. W. Thomas, ‘Fertiliser Industry Takes Leap of Faith on Green Ammonia’, CRU International Limited, London, UK, 25th June, 2021 LINK https://www.crugroup.com/knowledge-and-insights/insights/2021/fertilizer-industry-takes-leap-of-faith-on-green-ammonia/ [Google Scholar]
  11. G. Hochman, A. S. Goldman, F. A. Felder, J. M. Mayer, A. J. M. Miller, P. L. Holland, L. A. Goldman, P. Manocha, Z. Song, S. Aleti, ACS Sustain. Chem. Eng., 2020, 8, (24), 8938 LINK https://doi.org/10.1021/acssuschemeng.0c01206 [Google Scholar]
  12. D. R. MacFarlane, P. V. Cherepanov, J. Choi, B. H. R. Suryanto, R. Y. Hodgetts, J. M. Bakker, F. M. Ferrero Vallana, A. N. Simonov, Joule, 2020, 4, (6), 1186 LINK https://doi.org/10.1016/j.joule.2020.04.004 [Google Scholar]
  13. C. Schwiderek, ‘Green Ammonia Technology’, NH3 Event, 4th European Power to Ammonia Conference, Rotterdam, The Netherlands, 3rd–4th June, 2021 [Google Scholar]
  14. ‘‘Green’ Ammonia is the Key to Meeting the Twin Challenges of the 21st Century’, Siemens-Energy AG, Munich, Germany: https://www.siemens-energy.com/uk/en/offerings-uk/green-ammonia.html (Accessed on 1st February 2021) [Google Scholar]
  15. A. Buttler, H. Spliethoff, Renew. Sustain. Energy Rev., 2018, 82, (3), 2440 LINK https://doi.org/10.1016/j.rser.2017.09.003 [Google Scholar]
  16. R. M. Nayak-Luke, R. Bañares-Alcántara, Energy Environ. Sci., 2020, 13, (9), 2957 LINK https://doi.org/10.1039/D0EE01707H [Google Scholar]
  17. C. Smith, A. K. Hill, L. Torrente-Murciano, Energy Environ. Sci., 2020, 13, (2), 331 LINK https://doi.org/10.1039/C9EE02873K [Google Scholar]
  18. M. Hattori, S. Iijima, T. Nakao, H. Hosono, M. Hara, Nat. Commun., 2020, 11, 2001 LINK https://doi.org/10.1038/s41467-020-15868-8 [Google Scholar]
  19. B. Lin, L. Heng, B. Fang, H. Yin, J. Ni, X. Wang, J. Lin, L. Jiang, ACS Catal., 2019, 9, (3), 1635 LINK https://doi.org/10.1021/acscatal.8b03554 [Google Scholar]
  20. J. Zheng, F. Liao, S. Wu, G. Jones, T.-Y. Chen, J. Fellowes, T. Sudmeier, I. J. McPherson, I. Wilkinson, S. C. E. Tsang, Angew. Chem. Int. Ed., 2019, 58, (48), 17335 LINK https://doi.org/10.1002/anie.201907171 [Google Scholar]
  21. J. R. Chan, S. G. Lambie, H. J. Trodahl, D. Lefebvre, M. Le Ster, A. Shaib, F. Ullstad, S. A. Brown, B. J. Ruck, A. L. Garden, F. Natali, Phys. Rev. Mater., 2020, 4, (11), 115003 LINK https://doi.org/10.1103/PhysRevMaterials.4.115003 [Google Scholar]
  22. A. Daisley, J. S. J. Hargreaves, J. Energy Chem., 2019, 39, (12), 170 LINK https://doi.org/10.1016/j.jechem.2019.01.026 [Google Scholar]
  23. C. Smith, A. V. McCormick, E. L. Cussler, ACS Sustain. Chem. Eng., 2019, 7, (4), 4019 LINK https://doi.org/10.1021/acssuschemeng.8b05395 [Google Scholar]
  24. D. Saha, S. Deng, J. Chem. Eng. Data, 2010, 55, (12), 5587 LINK https://doi.org/10.1021/je100405k [Google Scholar]
  25. X. Luo, R. Qiu, X. Chen, B. Pei, J. Lin, C. Wang, ACS Sustain. Chem. Eng. 2019, 7, (11), 9888 LINK https://doi.org/10.1021/acssuschemeng.9b00554 [Google Scholar]
  26. T. N. Nguyen, I. M. Harreschou, J.-H. Lee, K. C. Stylianou, D. W. Stephan, Chem Commun., 2020, 56, (67), 9600 LINK https://doi.org/10.1039/D0CC00741B [Google Scholar]
  27. A. M. B. Furtado, Y. Wang, T. G. Glover, M. D. LeVan, Micro. Meso. Mater., 2011, 142, (2–3), 730 LINK https://doi.org/10.1016/j.micromeso.2011.01.027 [Google Scholar]
  28. C. Smith, L. Torrente-Murciano, Adv. Energy Mater., 2021, 11, (13), 2003845 LINK https://doi.org/10.1002/aenm.202003845 [Google Scholar]
  29. J. R. Gomez, J. Baca, F. Garzon, Int. J. Hydro. Energy, 2020, 45, (1), 721 LINK https://doi.org/10.1016/j.ijhydene.2019.10.174 [Google Scholar]
  30. H. Xu, K. Ithisuphalap, Y. Li, S. Mukherjee, J. Lattimer, G. Soloveichik, G. Wu, Nano Energy, 2020, 69, 104469 LINK https://doi.org/10.1016/j.nanoen.2020.104469 [Google Scholar]
  31. X. Chen, N. Li, Z. Kong, W.-J. Ong, X. Zhao, Mater. Horiz., 2018, 5, (1), 9 LINK https://doi.org/10.1039/C7MH00557A [Google Scholar]
  32. P. W. Atkins, J. De Paula, “Physical Chemistry”, 8th Edn., Oxford University Press, Oxford, UK, 2006, p. 221 [Google Scholar]
  33. M. Wang, S. Liu, T. Qian, J. Liu, J. Zhou, H. Ji, J. Xiong, J. Zhong, C. Yan, Nat. Commun., 2019, 10, 341 LINK https://doi.org/10.1038/s41467-018-08120-x [Google Scholar]
  34. F. B. Juangsa, A. R. Irhamna, M. Aziz, Int. J. Hydro. Energy, 2021, 46, (27), 14455 LINK https://doi.org/10.1016/j.ijhydene.2021.01.214 [Google Scholar]
  35. S. Giddey, S. P. S. Badwal, A. Kulkarni, Int. J. Hydro. Energy, 2013, 38, (34), 14576 LINK https://doi.org/10.1016/j.ijhydene.2013.09.054 [Google Scholar]
  36. G.-F. Chen, S. Ren, L. Zhang, H. Cheng, Y. Luo, K. Zhu, L.-X. Ding, H. Wang, Small Meth., 2019, 3, (6), 1800337 LINK https://doi.org/10.1002/smtd.201800337 [Google Scholar]
  37. S.-J. Li, D. Bao, M.-M. Shi, B.-R. Wulan, J.-M. Yan, Q. Jiang, Adv. Mater., 2017, 29, (33), 1700001 LINK https://doi.org/10.1002/adma.201700001 [Google Scholar]
  38. X. Wang, W. Wang, M. Qiao, G. Wu, W. Chen, T. Yuan, Q. Xu, M. Chen, Y. Zhang, X. Wang, J. Wang, J. Ge, X. Hong, Y. Li, Sci. Bull., 2018, 63, (19), 1246 LINK https://doi.org/10.1016/j.scib.2018.07.005 [Google Scholar]
  39. H. Tao, C. Choi, L.-X. Ding, Z. Jiang, Z. Han, M. Jia, Q. Fan, Y. Gao, H. Wang, A. W. Robertson, S. Hong, Y. Jung, S. Liu, Z. Sun, Chem, 2019, 5, (1), 204 LINK https://doi.org/10.1016/j.chempr.2018.10.007 [Google Scholar]
  40. X. Xu, X. Tian, B. Sun, Z. Liang, H. Cui, J. Tian, M. Shao, Appl. Catal. B: Environ., 2020, 272, 118984 LINK https://doi.org/10.1016/j.apcatb.2020.118984 [Google Scholar]
  41. X. Ren, J. Zhao, Q. Wei, Y. Ma, H. Guo, Q. Liu, Y. Wang, G. Cui, A. M. Asiri, B. Li, B. Tang, X. Sun, ACS Cent. Sci., 2019, 5, (1), 116 LINK https://doi.org/10.1021/acscentsci.8b00734 [Google Scholar]
  42. X. Yang, S. Sun, L. Meng, K. Li, S. Mukherjee, X. Chen, J. Lv, S. Liang, H.-Y. Zang, L.-K. Yan, G. Wu, Appl. Catal. B: Environ., 2021, 285, 119794 LINK https://doi.org/10.1016/j.apcatb.2020.119794 [Google Scholar]
  43. Z. Wang, K. Zheng, S. Liu, Z. Dai, Y. Xu, X. Li, H. Wang, L. Wang, ACS Sustain. Chem. Eng., 2019, 7, (13), 11754 LINK https://doi.org/10.1021/acssuschemeng.9b01991 [Google Scholar]
  44. S. Z. Andersen, M. J. Statt, V. J. Bukas, S. G. Shapel, J. B. Pedersen, K. Krempl, M. Saccoccio, D. Chakraborty, J. Kibsgaard, P. C. K. Vesborg, J. Nørskov, I. Chorkendorff, Energy Environ. Sci., 2020, 13, (11), 4291 LINK https://doi.org/10.1039/D0EE02246B [Google Scholar]
  45. I. J. McPherson, T. Sudmeier, J. P. Fellowes, I. Wilkinson, T. Hughes, S. C. E. Tsang, Angew. Chem. Int. Ed., 2019, 58, (48), 17433 LINK https://doi.org/10.1002/anie.201909831 [Google Scholar]
  46. J. Wang, S. Chen, Z. Li, G. Li, X, Liu, ChemElectroChem, 2020, 7, (5), 1067 LINK https://doi.org/10.1002/celc.201901967 [Google Scholar]
  47. C. Y. Ling, Y. Zhang, Q. Li, X. Bai, L. Shi, J. Wang, J. Am. Chem. Soc., 2019, 141, (45), 18264 LINK https://doi.org/10.1021/jacs.9b09232 [Google Scholar]
  48. B. M. Hoffman, D. Lukoyanov, Z.-Y. Yang, D. R. Dean, L. C Seefeldt, Chem. Rev., 2014, 114, (8), 4041 LINK https://doi.org/10.1021/cr400641x [Google Scholar]
  49. V. Kyriakou, I. Garagounis, E. Vasileiou, A. Vourros, Stoukides, Catal. Today, 2017, 286, 2 LINK https://doi.org/10.1016/j.cattod.2016.06.014 [Google Scholar]
  50. T. Murakami, T. Nishikiori, T. Nohira, Y. Ito, J. Am. Chem. Soc., 2003, 125, (2), 334 LINK https://doi.org/10.1021/ja028891t [Google Scholar]
  51. S. C. E. Tsang, J. Zheng, Oxford University Innovation Ltd, ‘Photocatalyst’, World Patent Appl. 2020/193,951 [Google Scholar]
  52. P. Sanjay, ‘With 2,245 MW of Commissioned Solar Projects, World’s Largest Solar Park is Now at Bhadla’, Mercom, India, 19th March, 2020 LINK https://mercomindia.com/world-largest-solar-park-bhadla/ [Google Scholar]
  53. K. Sieling, O. Günther-Borstel, H. Hanus, J. Agri. Sci., 1997, 128, (1), 79 LINK https://doi.org/10.1017/S0021859696004005 [Google Scholar]
  54. M. B. Ali, N. L. Brooks, R. G. McElroy, ‘Characteristics of US Wheat Farming: A Snapshot’, Statistical Bulletin No. SB 968, United States Department of Agriculture, Washington, DC, USA, June, 2000, 61 pp [Google Scholar]
  55. F. Brentrup, A. Hoxha, B. Christensen, ‘Carbon Footprint Analysis of Mineral Fertiliser Production in Europe and Other World Regions’, 10th International Conference on Life Cycle Assessment of Food, University College Dublin, Ireland, Dublin, 19th–21st October, 2016, 9 pp [Google Scholar]
  56. Q. Han, H. Jiao, L. Xiong, J. Tang, Mater. Adv., 2021, 2, (2), 564 LINK https://doi.org/10.1039/D0MA00590H [Google Scholar]
  57. X. Xue, R. Chen, C. Yan, P. Zhao, Y. Hu, W. Zhang, S. Yang, Z. Jin, Nano Res., 2019, 12, (6), 1229 LINK https://doi.org/10.1007/s12274-018-2268-5 [Google Scholar]
  58. H. Kisch, D. Bahnemann, J. Phys. Chem. Lett., 2015, 6, (10), 1907 LINK https://doi.org/10.1021/acs.jpclett.5b00521 [Google Scholar]
  59. H. Li, J. Shang, Z. Ai, L. Zhang, J. Am. Chem. Soc., 2015, 137, (19), 6393 LINK https://doi.org/10.1021/jacs.5b03105 [Google Scholar]
  60. Z. Li, Z. Gao, B. Li, L. Zhang, R. Fu, Y. Li, X. Mu, L. Li, Appl. Catal. B: Environ., 2020, 262, 118276 LINK https://doi.org/10.1016/j.apcatb.2019.118276 [Google Scholar]
  61. B. Sun, Z. Liang, Y. Qian, X. Xu, Y. Han, J. Tian, ACS Appl. Mater. Interfaces, 2020, 12, (6), 7257 LINK https://doi.org/10.1021/acsami.9b20767 [Google Scholar]
  62. S. Zhang, Y. Zhao, R. Shi, G. I. N. Waterhouse, T. Zhang, EnergyChem, 2019, 1, (2), 100013 LINK https://doi.org/10.1016/j.enchem.2019.100013 [Google Scholar]
  63. H. Li, J. Shang, Z. Ai, L. Zhang, J. Am. Chem. Soc., 2015, 137, (19), 6393 LINK https://doi.org/10.1021/jacs.5b03105 [Google Scholar]
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