A Brief Review on Additive Manufacturing Processes for Lightweight Metal Matrix Composites
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doi: 10.1595/205651323X16601431334489
A Brief Review on Additive Manufacturing Processes for Lightweight Metal Matrix Composites
Recent advances in selection, reinforcement, preparation and processing and their influence on material properties
Article Synopsis
Many additive manufacturing (AM) processes have been developed to fabricate lightweight metal matrix composites (LMMCs) from constituent materials. However, the improvement in mechanical properties is significantly affected by the added reinforcing materials in the LMMC compared to metallic materials and their alloys. Recent advances in understanding the selecting criteria and effect of the reinforcement, preparation methods and AM process on the properties of LMMCs are summarised in this review. The preparation methods of particle-reinforced LMMCs include ex situ and in situ synthesis. The effect of various reinforcement and AM processes such as powder bed fusion (PBF) processes and direct energy deposition (DED) processes on the mechanical properties of LMMC parts are discussed.
1. Introduction
Metal matrix composites (MMCs) have evolved significantly since their appearance in the 1960s. Because of their high price, their applications were initially limited to the aerospace and defence industries. It was not until the 1980s that new applications were investigated, thanks to the development of high-quality, low-cost reinforcements. For their capacity to meet engineering and structural needs, MMCs are currently of interest in the transportation (particularly automobile, rail and marine), construction, electronics and sports industries (1). The unusual and sometimes surprising features of MMCs, significantly superior to metallic alloys, are the basis for this interest.
Generally, lightweight metallic materials, specifically titanium and aluminium, are characterised by poor wear resistance, limiting their further development (2). An effective means of enhancing their resistance is to reinforce them with hard materials: carbides (silicon carbide, titanium carbide and boron carbide), nitrides (silicon nitride, aluminium nitride), carbon allotropes (carbon nanotubes and graphene) and oxides (alumina, silica) are currently the most used reinforcement materials (3, 4). Additionally, as hard materials are not necessarily suitable for stiffness and fatigue resistance, combining two or more materials leads to composites capable of satisfying varying industrial requirements. Moreover, the material properties are highly affected by the operating conditions (stress, temperature, humidity) and the nature of loading (fatigue, impact, fluctuation). Such composite materials allow the user to benefit from different functional properties provided by the light metal matrix and reinforcement. These materials are called LMMCs.
Depending on the distribution of reinforcement and its type (particles or fibres), there are three types of LMMCs: (a) particle-reinforced LMMCs; (b) short fibre- or whisker-reinforced LMMCs; and (c) continuous fibre- or sheet-reinforced LMMCs. The primary industrial methods for manufacturing LMMCs can be roughly divided into three main groups: (a) solid-state processes (i.e. powder metallurgy, mechanical alloying, diffusion bonding and physical vapour deposition); (b) semi-solid processes (i.e. thixoforging and compocasting); and (c) liquid-state processes (stir casting, ultrasonic-assisted casting, pressure infiltration processes and spray deposition). Alternatively, the manufacture of LMMCs can be classified into three main concepts: (a) casting; (b) diffusion bending; and (c) powder metallurgy. Among them, powder metallurgy is the only method used to manufacture LMMCs reinforced by whiskers or particles that exhibit outstanding specific stiffness, strength, isotropic properties and ease of near-net-shape production (5). Liquid-state methods result in inhomogeneous dispersions of reinforcement throughout the LMMCs, resulting in either reinforcement-rich or light-metal-rich regions.
Additionally, traditional methods (i.e. stir casting and powder metallurgy) show many limitations, namely the possible reaction of the reinforcement with the melt or a tendency to settle during casting. The size and morphology of particles (such as spherical or angular particulates, prismatic sections and flat sheets) are the two critical parameters in injection moulding (6). Furthermore, both methods are subject to agglomeration of the reinforcement phase and require post-processing or machining to obtain desired geometry, structure and properties, which is another disadvantage for industrial production. Moreover, the increased tool wear from the reinforcement phase could result in an expensive process. Hence, recent efforts have been made to address these challenges to broaden the application of LMMCs. These efforts have been focused on using metal AM techniques, a recently developed technology that has rapidly become a promising method for fabricating complex-shaped components.
Initially developed in 1986, AM can be defined as assembling materials to fabricate objects using three-dimensional (3D) model data, usually layer by layer, as opposed to subtractive manufacturing methods, such as traditional machining (7). AM provides a processing route to fabricate complex shaped parts with a high level of design accuracy and flexibility while benefiting from the advantages of the AM technique, such as the elimination of the need for post-intermediate tooling. AM, therefore, reduces the manufacturing time, provides opportunities to minimise material waste and energy consumption, and gives the best design for lean production. More companies use LMMC composites to design parts of varying complexity in the AM market. However, even though the term is increasingly used, it is unclear what LMMCs are and how to prepare their parts. In this review, based on the relevant and recent literature, the description of LMMCs, preparation methods of composite powder and metal AM processes for LMMCs (mostly PBF and DED) will be discussed in detail, as depicted in Figure 1.
2. Overview of the Metal Additive Manufacturing Processes for Fabricating Lightweight Metal Matrix Composites
According to ASTM F2792-12 (7), AM can be divided into seven categories based on adhesion and bonding techniques. Figure 2 summarises the categories, the processes and the materials used for each technique. Another classification can be made depending on the state of the raw material (8): liquid processes (i.e. vat photopolymerisation and material jetting); molten or filament processes (i.e. material extrusions); powder processes (i.e. PBF, binder jetting and DED) and solid layer processes (i.e. sheet lamination).
Metal AM can be classified into two main groups: direct and indirect methods. In the case of direct methods, the component is directly fabricated without any additional post-processing; the processes include PBF and DED. In an indirect process such as binder jetting, as a binder is used for shaping, post-processing (debinding and sintering) it is required to consolidate the materials and, therefore, increase the density of the components (9). In general, AM methods have shown the ability to create lightweight metal parts in a clean construction environment with reduced fabrication time and outstanding characteristics. Nevertheless, only a few of them focus on particle-reinforced LMMCs. Metal AM could enable the manufacture of either particle- or fibre-reinforced LMMCs. However, most of the existing literature about LMMCs focuses on particle-reinforced LMMCs. As a result, sheet lamination (SL) might not be applicable for processing LMMC materials with complex geometries (10). In the light of the above, this review focuses on particle-reinforced LMMCs fabricated by powder-based AM processes, namely PBF and DED.
2.1 Powder Bed Fusion Processes
PBF processes were one of the first commercialised AM processes. Originally developed at the University of Texas at Austin, USA, selective laser sintering (SLS) was the first commercially available PBF process. Figure 3 shows the primary mode of operation of SLS. All other PBF processes derive from them in one or more ways to improve productivity, allow the processing of different materials and avoid specific patented features. Consequently, PBF processes share several essential characteristics, namely: (a) one or multiple heat sources to induce fusion between the powder particles; (b) a method to control the fusion of the powder particles in a predetermined region of each layer; and (c) mechanisms for adding and smoothing the powder layers (11).
PBF processes can be classified depending on the heat sources: thermal fusion (i.e. SLS); laser fusion (i.e. SLS, selective laser melting (SLM) and direct metal laser sintering (DMLS)); electron beam fusion (i.e. electron beam melting (EBM)); and agent or energy fusion (i.e. multi-jet fusion). The two most well-known heat sources are lasers and electron beams. However, as electron beam requires different machine architectures than laser, laser PBF and EBM processes will be addressed separately. Table I shows a comparison of the characteristics of these AM processes. Based on these characteristics, SLM and EBM processes offer better surface finish and lower layer thickness compared to DED. Therefore, direct metal deposition (DMD) is more suitable for manufacturing relatively large parts at high processing speeds but with a coarser surface finish, while SLM and EBM are more suitable for manufacturing more precise and complex small objects.
Table I
2.1.1 Laser Powder Bed Fusion Processes
In 1994, the company EOS GmbH, Germany, patented its process called DMLS, while in 1996, the Fraunhofer Institute of Laser Technology ILT, Germany, introduced SLM. Although the term DMLS implies sintering as in SLS, it is crucial to understand that metal AM processes are nowadays based on fusion and not on sintering. The difference between sintering and melting is quite simple: melting means the metal goes from solid to liquid due to high temperature. On the other hand, sintering does not allow the metal to melt because the temperature used is not high enough. As a result, the metal particles are agglomerated together, leaving a void and holes.
As previously mentioned, laser powder bed fusion (LPBF) is one of the direct AM processes. A speed-controlled laser scans selected positions in the powder bed and fuse the powder by either partial melting (SLS and DMLS) or complete melting (SLM). The sintering processes result in the production of ex situ reinforced LMMCs. In the metal SLS process, composite powder grains consisting of the structural material, binder and reinforcement are used. The low-melt powders (metal matrix) can partially melt during the SLS process and form a bond with the unmelted high-melt powders. The composite powder can be obtained by mechanically alloying a mixture of two or more powders, allowing the powder particles to be repeatedly ground, raked and welded together. Even with potential application in several fields, manufacturing is limited in the SLS process because of its products’ low dimensional accuracy and surface roughness (16).
DMLS is similar to the SLS process from the perspective of being a powder deposition method. However, the DMLS process does not require any plastic binder mix to hold the composite powder together. Similarly, there is no need for other sintering or infiltration processes to produce LMMC parts for different applications. Nevertheless, the shot-peening process and polishing are secondary finishing operations (17). The shot-peening process controls residual stresses through surface compression, while polishing is used to reduce surface roughness.
SLM is similar to SLS, except it requires more energy because complicated pieces are made at a higher temperature to fuse or melt the powders during the SLM process. However, the SLM process could fabricate in situ reinforced LMMCs by activating chemical reactions between the components present in the composite powder. Although the SLM process suffers from limitations caused by the fact that the dimensional accuracy is second-rate, the SLM technique is the most widely used in the literature for the fabrication of LMMCs. The characteristics and properties of the resulting composite powder are of critical importance and significantly determine the quality of the product. When using ceramic particles as reinforcement, each constituent’s type, size, morphology and volume fraction may be considered crucial factors for controlling the microstructural homogeneity, laser absorptivity, processability and therefore the mechanical properties of LMMCs fabricated by SLM (18). For instance, according to many attempts, the mixture of ceramics with lower laser absorption using SLM will deteriorate the properties of the part when compared to matrix alloys (18, 19). Recently, Liu et al. (20) investigated the effect of process parameters on SLM SiC/AlSi10Mg composites. They demonstrated the highest densities and tensile strength because of silicon and magnesium silicide precipitation hardening, silicon carbide dispersion strengthening and α-alumina solid solution strengthening.
2.1.2 Electron Beam Melting
The EBM system was first commercialised by Arcam AB, Sweden, in 2002. The principle is the same as the SLM process, except that the composite powder is melted with an electron beam instead of a laser source. In the EBM process, a stream of electrons produced by an electron beam is guided with a magnetic field to melt layer upon layer of powdered composite fully and create an object that matches the specifications outlined by a computer aided design model. To avoid oxidation that can compromise highly reactive materials, manufacturing occurs in a vacuum chamber. The EBM process is distinguished by a higher energy density than the LPBF process, enabling the EBM method to have powder layers with a higher thickness (greater than 50 μm). Accordingly, the particle size distribution of the starting composite powder may be within the range of 45–150 μm (larger than LPBF, which is in the range of 15–50 μm) (5). Since the electron beam is wider than the laser beam, EBM can be much faster than LPBF processes, but the latter produces smoother and more accurate parts. The EBM process is more energy-friendly and allows for a more uniform distribution of the thermal field and a much higher throughput (16). In addition, mechanical properties are highly improved using EBM in parallel to reinforcement, which is surely proved by the wear behaviour of TiC+Ti3SiC2+Ti5Si3 reinforced Ti6Al4V alloy, demonstrating an improved microhardness and wear resistance (21).
2.2 Direct Energy Deposition Processes
DED is based on synchronous powder feeding technology, allowing a 3D part to be directly manufactured with very complex geometric features. The composite powder is fed into the printing spot using a nozzle, and an electron beam or a laser will create the molten pool and the melt path. Several DED processes are available today, including direct laser deposition, laser consolidation, laser metal deposition, laser engineered net shaping and laser cladding. In the DED process, deposition begins with a computer aided design model, and printing proceeds layer by layer on a building plate or a substrate part (Figure 4). A shielding gas such as argon protects the molten materials from oxidation and ensures better powder flow in the melt. However, unfortunately, it also induces some defects in the structure, such as pores and layered voids (22). However, an appropriate support structure is required to avoid distortion when manufacturing complex geometries with overhanging features (6). In addition, the cooling rate is very high (102~105 K s–1), so the resulting microstructure is ultrafine (23).
The DED processes can manufacture both ex situ and in situ reinforced LMMCs. The DED process is desirable for manufacturing large parts with a lower production cost than other AM methods such as SLM. However, the powders are often larger, requiring a higher energy density, resulting in faster build rates than the PBF processes and poorer surface quality. Even though surface finishing is often a requirement for all metal AM techniques, the surface finish quality is poor in DED compared to PBF. LMMC parts may need to be further treated with additional finishing operations to achieve the desired surface quality. Therefore, DED is a practical approach to preparing LMMCs with high bonding strength because the high energy density of the laser beam will lead to the metallurgical bonding between the light metal matrix and the reinforcement.
3. Lightweight Metal Matrix Composites and their Progress
3.1 Effect of Preparation Methods
Many attempts have been recently made to accelerate the improvement of LMMC properties to meet the growing demand for lightweight structural components with a high stiffness-to-weight ratio in the automotive, aerospace and marine fields. One such attempt is to prepare composites reinforced with hard and stable ‘ex situ’ particles. In the ex situ technique, the reinforcement is externally synthesised and then pre-mixed with the light metal matrix or introduced separately into the melt pool during manufacturing. Recently, mechanical mixing methods have attracted much attention due to their convenience, speed, cost-effectiveness and applicability to a wide range of materials. Accordingly, regular mixing and ball milling are considered the most widely applied processes for the pretreatment of composite powders. The ball milling method enhances the dispersion of reinforcing particles in micro- or nano-composite powders. The ball milling method can be characterised by the repeated deformation, cold welding and fracture of the powder particles caused by the high-energy impacts of particle/particle and ball/particle collisions.
Regular mixing is based on the same concept as ball milling, except for not using beads. Consequently, there is an absence of decoration of the metal powder particles, which leads to the separation of the different constituents during the powder deposition step, especially in the SLM process (24). For example, Cheng et al. (25) used a powder mixture of (TiB2+TiC)/AlSi10Mg (1.5 wt% and 1.5 wt% of titanium boride and titanium carbide particles, respectively) for SLM, produced by ball milling. They revealed that the composites exhibited very high ultimate tensile strength (552.4 MPa) and excellent ductility (12%), about 1.4% and 2.67% times higher than AlSi10Mg. Highly reinforced aluminium composite powders were fabricated by mechanically alloying AlSi10Mg and titanium boride, whose morphology and composition were adapted to the LPBF process conditions. Graphene/AlSi10Mg composite powder was also produced by ball milling followed by the PBF process (26). Zhang et al. (27) reported a powder mixture of silicon carbide particles with AlSi10Mg alloys produced by ball milling and prepared SiC/AlSi10Mg composites by SLM with the highest microhardness (208.5 HV0.1), tensile strength (450 MPa), yield strength (408 MPa) and modulus (90 GPa).
Another attempt is to prepare in situ reinforced LMMCs, involving the synthesis of reinforcement in the light metal matrix by chemical reactions that melt during the AM process. Compared to the ex situ reinforced LMMCs, the in situ reinforced LMMCs exhibit higher density. However, this is due to the agglomeration of the reinforced particles, entrapped gas formation and weak interfacial bonding between the light metal matrix and the reinforced particles in the case of ex situ reinforced LMMCs (28). Because of the formation of unique intermetallic phases, more stable and finer reinforced particles, stronger interfacial bonding and more homogeneous reinforcement particles, the mechanical properties obtained through in situ reinforced LMMCs were superior to those obtained through ex situ reinforced LMMCs (28, 29). Regardless of the preparation method, the increase in particle size and applied energy results in the transformation of the aggregation into a uniform dispersion of reinforcements (29). Shi et al. (30) successfully prepared in situ particle reinforced aluminium matrix composites starting from Fe2O3/AlSi12 powder mixture. Pan et al. (31) recently prepared Ti6Al4V/TiBw via electrode induction melting gas atomisation as the feedstock for EBM. In situ nano-titanium boride reinforced AlSi10Mg composites were also produced by Tang et al. (32).
3.2 Effect of Reinforcements on Lightweight Metal Matrix Composites
A reinforcement must respect a certain number of conditions to obtain a quality material. Firstly, the nature of the reinforcement, its morphology and its properties must be considered. In addition, the reinforcement’s chemical, physical and mechanical compatibility with the light metal matrix must be carefully analysed. Chemical compatibility issues are related to chemical reactions at phase boundaries and chemical interaction with the environment during the production process. The light metal matrix should have good ductility, compliance and strength to transfer power loads to the reinforcing particles uniformly and continuously to ensure physical compatibility.
Additionally, local stresses in the light metal matrix induced by defects or dislocation should not generate local concentrations on the reinforcing particle. Furthermore, a significant difference in expansion coefficient and melting temperature of the matrix and the reinforcement can create processing problems such as cracks and unwanted reactions (5). A mismatch of thermal expansion between the light metal matrix and the reinforcement leads to the creation of thermally induced stresses, which has implications for the determination of the mechanical properties of LMMCs (33). The component (matrix or reinforcement) with a higher coefficient of expansion will be subject to tensile stresses generated as a consequence of global cooling and heating of the structure, as well as local cooling and heating events when a temperature gradient develops (33). When thermal stresses (or residual tensile stresses) generated are higher than the yield strength of the metal matrix, they induce either a debonding between the reinforcement particles and the matrix, or crack propagation leading to damage accumulation in the light metal matrix (34). Accordingly, the expansion coefficient of the light metal matrix must be higher than that of the reinforcement.
Reinforcements are usually made of hard materials with a compressive strength greater than their tensile strength. An important point to note is that the light metal matrix and the reinforcement need to be in thermodynamic equilibrium or striving to reach it. The thermodynamic equilibrium criterion for solids at constant pressure and temperature is the minimum of the Gibbs energy; the Gibbs energy indicates the change in energy during the chemical reaction and shows the possibility of chemical reactions between the light metal matrix and the reinforcement. Accordingly, the Gibbs energy variation minimum corresponds to a stable equilibrium between the matrix and the reinforcement (35). In addition to selecting reinforcing conditions, a suitable reinforced material should adhere to the composite powder preparation process requirements.
As previously mentioned, most reinforcements are ceramics. Table II provides a detailed description of the various properties of Ti6Al4V and AlSi10Mg as a function of reinforcement content. The data were collected from many sources with different reinforcement/Ti6Al4V (or AlSi10Mg) combinations and different AM techniques. A comparison of the performance of the resulting materials shows that the mechanical properties of composites depend on the nature of the reinforcement and its properties. Thus, hydroxyapatite (HA) has poor mechanical properties compared to metals and ceramics, which explains the low ultimate tensile strength and ultimate compressive strength of HA/Ti6Al4V compared to uncharged Ti6Al4V. As ceramics are hard materials, their incorporation as reinforcements leads to reducing deformation at the break of the composites. The same applies to other mechanical properties; the harder and stronger the reinforcement, the better the properties of the resulting composites. For example, changes in titanium carbide content had very profound effects on the hardness and compressive properties of TiC/Ti6Al4V (42, 44).
Table II
Mechanical Properties of Lightweight Metal Matrix Composites Fabricated via Additive Manufacturing Processes
Metal matrix | Reinforcement
|
Additive manufacturing process | Tensile properties
|
Compressive properties
|
Hardness | Reference | |||||
---|---|---|---|---|---|---|---|---|---|---|---|
Type | Content | Yield strength (σs), MPa | Ultimate strength (σu), MPa | Elongation (ɛ), % | Yield strength (σs), MPa | Ultimate strength (σu), MPa | Elongation (ɛ), % | ||||
AlSi10Mg | TiN | 2 wt% | SLM | – | – | – | – | – | – | 145 HV | (36) |
4 wt% | SLM | 315.4 | 491.2 | 7.5 | – | – | – | 156.9HV | (37) | ||
SiC | – | SLM | – | – | – | – | – | – | 218.5 HV0.1 | (38) | |
0–10 wt% | SLM | NS–450 | – | – | – | – | – | NS–208.5 HV0.1 | (27) | ||
CNT | 0 wt% | – | 350.0 | 5.5 | – | – | – | – | (39) | ||
0.5 wt% | SLM | – | 420.8 | 8.87 | – | – | 8.8 | 154.12 HV0.2 | |||
Ti6Al4V | B4C | 0–1 wt% | SLM | – | – | – | – | 1384–1747 | 14.2–33 | 375–546 HV | (40) |
0–1.5 wt%, 0–12 vol% | DED | – | 1000–1200 | – | – | – | – | 360–445 HV0.5 | (41) | ||
TiC | 0–15 vol% | DED | – | – | – | 997–1310 | 1381.0–1636.0 | 14.1–29.3 | 39–55 HRC | (42) | |
0–35 wt% | EBM | – | 850–950 | 2–7 | – | – | – | – | (43) | ||
0–50 vol% | DED | – | – | – | – | – | – | 379.77–736.71 HV | (44) | ||
HA | 0–5 wt% | EBM | – | 1110–123 | 13–5.56 | – | 1300–875 | – | 4.1–6.8 GPa | (45) | |
CNT | 0.8 wt% | DED | 1162 | 1255 | 3.2 | 1484 | 2170 | 23.8 | – | (46) | |
TiB2 | 0–10 wt% | DED | – | – | – | – | – | – | 440–480 HV | (47) | |
0–2 wt% | DMLS | – | – | – | – | – | – | 383–477 HV | (48) | ||
TiB2 whisker | 0–5.1 vol% | EBM | 838–1039 | 879–1121 | 13.1–8.9 | – | – | – | – | (31) | |
Cu | 0–5 vol% | EBM | 745–970 | 906–1126 | 10.5–3.4 | – | – | – | – | (49) | |
nYSZ | 0–2.5 wt% | LPBF | – | – | – | 837–1301 | 1280–1834 | 39–10 | 350–510 HV | (50) |
Strengthening mechanisms have been discussed in a few studies in order to predict the behaviour of the dispersion of the reinforcement in a lightweight metal matrix. For example, Afifa et al. (51) in their review suggest that the strengthening mechanisms for graphene-reinforced aluminium matrix include grain refinement, Orowan strengthening mechanism, stress load transfer and thermal expansion mismatch. Improvement of the tensile properties of 1 wt% TiB2/AlSi10Mg in work by Li et al. (52) was attributed to multiple load strengthening, solid solution strengthening and dispersion strengthening. In another study, Li et al. (53) improved the mechanical properties of AlSi10Mg by adding titanium boride. The results suggested Hall-Petch, load-bearing and Orowan strengthening mechanisms in this case.
4. Case Study: TiB2/AlSi10Mg Composites
The AM method adopted in the fabrication plays a crucial role in determining the properties of the final part. Titanium boride reinforcement has attracted much attention in the production of LMMCs (5). Therefore, TiB2/AlSi10Mg composite was chosen as a case study to investigate the importance and effect of each AM process. A summary of the effect of different AM processes on the mechanical properties of TiB2/AlSi10Mg composites is listed in Table III. Tan et al. (54) produced TiB2/AlSi10Mg composites through the DMD process. They found that macro-agglomeration decreased significantly with decreasing titanium boride content and displacement speed. Moreover, the porosity decreased with the increase of the displacement speed. According to their results, the hardness was significantly enhanced in the presence of titanium boride from 95 HV0.1 (AlSi10Mg) to 113 HV0.1 (2 wt% titanium boride) and to 125 HV0.1 (6 wt% titanium boride), respectively.
Table III
The Mechanical Properties of TiB2/AlSi10Mg Composites by Different Additive Manufacturing Technologies
Technology | TiB2 content | Features | Reference |
---|---|---|---|
DMD | 2 wt% | Vickers hardness = 113 HV0.1 | (54) |
6 wt% | Vickers hardness = 125 HV0.1 | ||
DMLS | 1 wt% nano-TiB2 | Microhardness = 99.2 ± 0.6 HV | (55) |
1 wt% nano-TiB2 | Microhardness = 97.5 ± 1.7 HV | (56) | |
Nanohardness = 1.15 ± 0.15 GPa | |||
Elastic modulus = 75.5 ± 3.2 GPa | |||
10 wt% micro-TiB2 | Microhardness = 97.5 ± 1.7 HV | (55) | |
10 wt% micro-TiB2 | Microhardness = 99.2 ± 0.6 HV | (56) | |
Nanohardness = 2.40 ± 4.8 GPa | |||
Elastic modulus = 78.6 ± 28.8 GPa | |||
SLM | 1 wt% | Microhardness = 120 HV | (52) |
Ultimate tensile strength = 380.0 MPa | |||
Yield strength = 250.4 MPa | |||
Elongation = 3.43% | |||
1 wt% | Hardness = 126 HV0.2 | (57) | |
1.5 wt% | Microhardness = 113.3 HV0.2 | (58) | |
Ultimate tensile strength = 375 MPa | |||
Yield strength = 260 MPa | |||
Elongation = 3.1% | |||
11.6 wt% | Microhardness = 191 ± 4 HV0.3 | (53) | |
Tensile strength = 530 ± 16 MPa | |||
Ductility = 15.5 ± 1.2% |
However, in research conducted by Lorusso et al. (55, 56), the effect of two different compositions (1 wt% of nanosize titanium boride and 10 wt% of microsize titanium boride) on the microstructure evolution, microhardness, nanohardness and elastic modulus of AlSi10Mg produced via DMLS was studied. Interestingly, they revealed that the average Vickers hardness and elastic modulus values are quite similar to those of the AlSi10Mg alloy. Thus, the titanium boride microparticles-containing composite showed a higher average microhardness (about 4.8 GPa) and well-defined areas of higher hardness dispersed in the softer lightweight matrix. This was attributed to an agglomeration effect of the reinforcement.
Li et al. (52) studied the mechanical characteristics of TiB2/AlSi10Mg composites fabricated via the SLM process. They reported that the microhardness of 1 wt% TiB2/AlSi10Mg was 120 HV, which was 20.97% higher than that obtained using the DMLS process. It can also be noted that the microhardness of SLM AlSi10Mg composites reinforced with 1 wt% titanium boride is higher than DMD AlSi10Mg composites reinforced with 1 wt% titanium boride (6.19% higher). The increase in microhardness of 1 wt% TiB2/AlSi10Mg produced via SLM was confirmed by Xi et al. (57) who found a value of 126 HV0.2. However, the composites showed a stabilised microhardness distribution, unlike those obtained using the DMLS process. This indicates that composite manufacturing by SLM gives optimal mechanical properties compared to other processes. Li et al. (52) also reported that the ultimate tensile strength, yield strength and elongation of 1 wt% TiB2/AlSi10Mg were 375 MPa, 250.4 MPa and 3.43%, respectively. The improvement in tensile properties compared to AlSi10Mg was attributed to multiple mechanisms, such as load strengthening, solid solution strengthening and dispersion strengthening. Elsewhere, Meng et al. (58) showed that the values of microhardness, ultimate tensile strength, yield strength and elongation of 1.5 wt% TiB2/AlSi10Mg composites are quite similar to the values 1 wt% TiB2/AlSi10Mg composites (52), although the 1.5 wt% TiB2/AlSi10Mg composites have slightly higher yield strength.
In another research carried out by Li et al. (53), the effect of adding a high content of titanium boride (11.6 wt%) on the mechanical properties of SLM-produced AlSi10Mg composites was investigated. The obtained composites had high tensile strength (530 MPa), excellent ductility (15.5%) and microhardness (191 HV0.3). This implies that increased reinforcement content leads to improved mechanical properties. The enhanced strength was mainly attributed to Hall-Petch, load-bearing and Orowan strengthening mechanisms, whereas the enhanced ductility was caused by the modification of grain boundaries by the addition of titanium boride nanoparticles.
5. Summary and Conclusion
Particle-reinforced LMMCs are made of light metals like magnesium, aluminium or titanium. Reinforcement is usually particles. The properties, performance and manufacture of LMMCs usually depend on the reinforcing characteristics. AM technologies offer a high level of flexibility for designing and manufacturing complex geometries and customised products. This review discussed frequently adopted metal AM processes like LPBF and DED to produce LMMCs. The effects of AM processes and reinforcement on the mechanical properties of LMMCs were discussed in detail and the mechanical properties of LMMCs with respect to their preparation method and reinforcement content were also summarised.
New research and development studies are now being undertaken to investigate and improve the properties of LMMC parts and AM technologies, opening up new applications in the automotive, aerospace, construction, rail and marine transport industries. Some future research perspectives and key findings include a variety of ceramic particle reinforcements which have been adopted and continue to be used to improve the properties of various light metal matrices. Scientists need to continue to research new nanoparticles which are not yet widely used as reinforcement. Further studies are also needed to reduce the agglomeration of reinforcements. More emphasis should be placed on ‘green’ LMMCs that are environmentally friendly and recyclable in nature. Lastly, AM of LMMCs has many challenges. Thus, using the appropriate process and optimal process parameters can minimise the challenges and achieve desirable properties.
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Glossary
3D |
three-dimensional |
AM |
additive manufacturing |
DED |
direct energy deposition |
DMD |
direct metal deposition |
DMLS |
direct metal laser sintering |
EBM |
electron beam melting |
LMMCs |
lightweight metal matrix composites |
LPBF |
laser powder bed fusion |
MMCs |
metal matrix composites |
PBF |
powder bed fusion |
SL |
sheet lamination |
SLM |
selective laser melting |
SLS |
selective laser sintering |