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image of Sustainable Lubrication Solutions: Rheological and Tribological Analysis of ZDDP-Enhanced Castor and Cashew Nut Shell Oil Biogenic Greases
  • oa Sustainable Lubrication Solutions: Rheological and Tribological Analysis of ZDDP-Enhanced Castor and Cashew Nut Shell Oil Biogenic Greases

  • Authors: Ravikiran1,2, K. R. Prakash1,2, M. V. Praveen Kumar3, D. V. Ravi Kumar4, Mayur D. Pawar5, M. K. Venkatesh6, M. N. Gururaja7, K. Santosh Pawan8, Gopal Kaliyaperumal9, S. Raghunandan10, C. Hemanth Kumar11 and C. Durga Prasad12
  • 1 Department of Mechanical Engineering, The National Institute of Engineering, Mysuru, Karnataka, India 2 The National Institute of Engineering, Affiliated to Visvesvaraya Technological University, Karnataka, India 3 Department of Mechanical Engineering, GITAM, Deemed to be University, Bengaluru, Karnataka, India 4 Department of Mechanical Engineering, Global Academy of Technology, Bengaluru, Karnataka, India 5 Department of Mechanical Engineering, Ballari Institute of Technology and Management, Ballari 583104, Karnataka, India 6 Department of Mechanical Engineering, Dayananda Sagar College of Engineering, Bengaluru, Karnataka, India 7 Department of Mechanical Engineering, Dayananda Sagar Academy of Technology and Management, Bengaluru-560082, Karnataka, India 8 Department of Mechanical Engineering, Cambridge Institute of Technology, Bengaluru, Karnataka, India 9 Department of Mechanical Engineering, New Horizon College of Engineering, Bengaluru, India 10 Department of Mechanical Engineering, Maharaja Institute of Technology, Thandavapura, Mysuru, Karnataka, India 11 Symbiosis Institute of Technology, Pune, India, Symbiosis International (Deemed University), Pune, India 12 Department of Mechanical Engineering, RV Institute of Technology and Management, Bengaluru, Karnataka, India
  • Source: Johnson Matthey Technology Review
    Available online: 11 August 2025
  • DOI: https://doi.org/10.1595/205651326X17549280158352
    • Received: 10 Jun 2025
    • Revised: 02 Aug 2025
    • Accepted: 11 Aug 2025
    • Published online: 11 Aug 2025

Abstract

Bio-greases offer a more sustainable alternative to synthetic-based greases, mitigating ecological harm while ensuring effective lubrication in environmentally sensitive applications. This study examines the formulation and performance of bio-greases derived from renewable resources, such as vegetable oils and biogenic thickeners. It underscores their advantages over conventional petroleum-based lubricants, particularly in terms of biodegradability and non-toxicity. A novel blend of Cashew Nut Shell Oil (CNSO), combined with fumed silica as a thickener and ZDDP as an additive, was investigated to enhance wear resistance, biodegradability, and other lubricating properties. This study highlights the significance of thickener consistency in converting liquid base oils into semi-solid greases, which is essential for effective lubrication. Various assessments, including extreme pressure and tribological analyses, demonstrate that the bio-grease samples exhibit non-Newtonian shear-thinning behavior, with performance metrics suggesting potential applications in food processing and agriculture. The results indicate that the addition of additives such as ZDDP can considerably enhance the lubricating properties and decrease the coefficient of friction (COF) in bio-greases.

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2025-08-11
2025-10-04
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