Skip to content
1887
Volume 60, Issue 2
  • ISSN: 2056-5135

Abstract

Neutron scattering is a severely underused technique for studies of catalysts. In this review we describe how and why neutrons are useful to catalysis. We illustrate the range of systems that have been studied by both elastic and inelastic neutron scattering. These range from structural studies of adsorbates in zeolites to determination of the structure of surface adsorbates, characterisation of nanoparticles, the measurement and mechanism of diffusion and spectroscopic characterisation of adsorbed species. We conclude with how to access neutron facilities and some future prospects for the application of these techniques to industrially useful materials.

Loading

Article metrics loading...

/content/journals/10.1595/205651316X691230
2016-01-01
2024-11-24
Loading full text...

Full text loading...

/deliver/fulltext/jmtr/60/2/JMTR-60-2-Parker.html?itemId=/content/journals/10.1595/205651316X691230&mimeType=html&fmt=ahah

References

  1. N. Floquet, J. P. Coulomb, J. P. Bellat, J. M. Simon, G. Weber, G. Andre, J. Phys. Chem. C, 2007,111, (49), 18182 LINKhttp://dx.doi.org/10.1021/jp0746502 [Google Scholar]
  2. M. Bianchini, F. Fauth, E. Suard, J.-B. Leriche, C. Masquelier, L. Croguennec, Acta Cryst. B, 2015,71, 688 LINKhttp://dx.doi.org/10.1107/S2052520615017199 [Google Scholar]
  3. F. G. Kinyanjui, S. T. Norberg, I. Ahmed, S. G. Eriksson, S. Hull, Solid State Ionics, 2012,225, 312 LINKhttp://dx.doi.org/10.1016/j.ssi.2012.05.018 [Google Scholar]
  4. T. Kandemir, D. Wallacher, T. Hansen, K.-D. Liss, R. N. d’Alnoncourt, R. Schlögl, M. Behrens, Nucl. Instrum. Meth. A, 2012,673, 51 LINKhttp://dx.doi.org/10.1016/j.nima.2012.01.019 [Google Scholar]
  5. T. Kandemir, F. Girgsdies, T. C. Hansen, K.-D. Liss, I. Kasatkin, E. L. Kunkes, G. Wowsnick, N. Jacobsen, R. Schlögl, M. Behrens, Angew. Chem. Int. Ed., 2013,52, (19), 5166LINKhttp://dx.doi.org/10.1002/anie.201209539 [Google Scholar]
  6. T. Egami, S. J. L. Billinge, “Underneath the Bragg Peaks: Structural Analysis of Complex Materials”, 2nd edition, Pergamon Materials Series, Volume 16, Elsevier Ltd, Amsterdam, The Netherlands, 2012 [Google Scholar]
  7. S. F. Parker, K. Refson, A. C. Hannon, E. Barney, S. J. Robertson, P. Albers, J. Phys. Chem. C, 2010,114, (33), 14164 LINKhttp://dx.doi.org/10.1021/jp103847d [Google Scholar]
  8. J. F. C. Turner, C. J. Benmore, C. M. Barker, N. Kaltsoyannis, J. M. Thomas, W. I. F. David, C. R. A. Catlow, J. Phys. Chem. B, 2000,104, (32), 7570 LINKhttp://dx.doi.org/10.1021/jp0017994 [Google Scholar]
  9. S. F. Parker, D. T. Bowron, S. Imberti, A. K. Soper, K. Refson, E. S. Lox, M. Lopez, P. Albers, Chem. Commun., 2010,46, (17), 2959 LINKhttp://dx.doi.org/10.1039/c001779e [Google Scholar]
  10. M. Bée, “Quasielastic Neutron Scattering”, Adam Hilger, Bristol, UK, 1988 [Google Scholar]
  11. H. Jobic, Curr. Opin. Solid State Mater. Sci., 2002,6, (5), 415 LINKhttp://dx.doi.org/10.1016/S1359-0286(02)00111-0 [Google Scholar]
  12. A. J. O’Malley, C. R. A. Catlow, Phys. Chem. Chem. Phys., 2015,17, (3), 1943 LINKhttp://dx.doi.org/10.1039/C4CP04898A [Google Scholar]
  13. A. J. O’Malley, C. R. A. Catlow, M. Monkenbusch, H. Jobic, J. Phys. Chem. C, 2015,119, (48), 26999 LINKhttp://dx.doi.org/10.1021/acs.jpcc.5b08048 [Google Scholar]
  14. A. J. O’Malley, S. F. Parker, A. Chutia, M. R. Farrow, I. P. Silverwood, V. García-Sakai, C. R. A. Catlow, Chem. Commun., 2016,52, (14), 2897 LINKhttp://dx.doi.org/10.1039/C5CC08956E [Google Scholar]
  15. P. C. H. Mitchell, S. F. Parker, A. J. Ramirez-Cuesta, J. Tomkinson, “Vibrational Spectroscopy with Neutrons: With Applications in Chemistry, Biology, Materials Science and Catalysis”, Series on Neutron Techniques and Applications, Volume 3, World Scientific, Singapore, 2005LINKhttp://dx.doi.org/10.1142/5628 [Google Scholar]
  16. S. F. Parker, D. Lennon, P. W. Albers, Appl. Spectrosc., 2011,65, (12), 1325 LINKhttp://dx.doi.org/10.1366/11-06456 [Google Scholar]
  17. I. P. Silverwood, N. G. Hamilton, C. J. Laycock, J. Z. Staniforth, R. M. Ormerod, C. D. Frost, S. F. Parker, D. Lennon, Phys. Chem. Chem. Phys., 2010,12, (13), 3102 LINKhttp://dx.doi.org/10.1039/b919977b [Google Scholar]
  18. A. R. McFarlane, I. P. Silverwood, R. Warringham, E. L. Norris, R. M. Ormerod, C. D. Frost, S. F. Parker, D. Lennon, RSC Adv., 2013,3, (37), 16577 LINKhttp://dx.doi.org/10.1039/C3RA42435A [Google Scholar]
  19. A. R. McFarlane, I. P. Silverwood, E. L. Norris, R. M. Ormerod, C. D. Frost, S. F. Parker, D. Lennon, Chem. Phys., 2013,427, 54 LINKhttp://dx.doi.org/10.1016/j.chemphys.2013.10.012 [Google Scholar]
  20. N. G. Hamilton, I. P. Silverwood, R. Warringham, J. Kapitán, L. Hecht, P. B. Webb, R. P. Tooze, S. F. Parker, D. Lennon, Angew. Chem. Int. Ed., 2013,52, (21), 5608 LINKhttp://dx.doi.org/10.1002/anie.201210179 [Google Scholar]
  21. R. Warringham, D. Bellaire, S. F. Parker, J. Taylor, R. A. Ewings, C. M. Goodway, M. Kibble, S. R. Wakefield, M. Jura, M. P. Dudman, R. P. Tooze, P. B. Webb, D. Lennon, J. Phys.: Conf. Ser., 2014,554, 012005 LINKhttp://dx.doi.org/10.1088/1742-6596/554/1/012005 [Google Scholar]
  22. R. Warringham, A. R. McFarlane, D. A. MacLaren, P. B. Webb, R. P. Tooze, J. Taylor, R. A. Ewings, S. F. Parker, D. Lennon, J. Chem. Phys., 2015,143, 174703 LINKhttp://dx.doi.org/10.1063/1.4935054 [Google Scholar]
  23. P. W. Albers, K. Möbus, S. D. Wieland, S. F. Parker, Phys. Chem. Chem. Phys., 2015,17, (7), 5274 LINKhttp://dx.doi.org/10.1039/C4CP05681G [Google Scholar]
  24. Neutronsources.org, Neutron Centres,: http://neutronsources.org/neutron-centres.html (Accessed on 17th February 2016)
  25. ISIS, Science and Technology Facilities Council,, Rutherford Appleton Laboratory, UK: http://www.isis.stfc.ac.uk (Accessed on 17th February 2016)
  26. Institut Laue-Langevin, Grenoble, France: www.ill.eu (Accessed on 17th February 2016)
  27. Oak Ridge National Laboratory, Spallation Neutron Source, US Department of Energy,: http://neutrons.ornl.gov/sns (Accessed on 17th February 2016)
  28. Japan Proton Accelerator Research Complex,, Ibaraki, Japan: j-parc.jp/index-e.html (Accessed on 17th February 2016)
  29. S. F. Parker, Chem. Commun., 2011,47, (7), 1988LINK http://dx.doi.org/10.1039/c0cc04991c [Google Scholar]
  30. European Spallation Source,, Tunavägen, Lund, Sweden: www.europeanspallationsource.se/ (Accessed on 17th February 2016)
/content/journals/10.1595/205651316X691230
Loading
/content/journals/10.1595/205651316X691230
Loading

Data & Media loading...

  • Article Type: Research Article
This is a required field
Please enter a valid email address
Approval was a Success
Invalid data
An Error Occurred
Approval was partially successful, following selected items could not be processed due to error
Please enter a valid_number test