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1887
Volume 65, Issue 1
  • ISSN: 2056-5135

Abstract

Platinum-based knitted gauzes are the most efficient catalysts for the production of nitric oxide, as a precursor to the manufacture of nitric acid and caprolactam. Decades of research and optimisation have resulted in a greater understanding of ammonia oxidation kinetics and associated metal movement within these catalyst packs, along with the development of beneficial binary and ternary alloys. The design of a pack has evolved from the simple addition or removal of metal to modelling the optimal installed metal content and distribution. This review discusses the fundamental kinetics and metal loss for ammonia oxidation catalysts in nitric acid applications and outlines how they can, in conjunction with prevailing platinum group metal (pgm) market conditions and plant key performance indicators (KPIs), influence the optimal catalyst design.

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/content/journals/10.1595/205651321X16012842414480
2021-01-01
2024-11-21
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References

  1. R. Gubler, B. Suresh, H. He, Y. Yamaguchi, ‘Nitric Acid’, in “Chemical Economics Handbook”, IHS Markit, London, UK, May, 2020, 116 pp [Google Scholar]
  2. H. Frankland, C. Brown, H. Goddin, O. Kay, T. Bünnagel, Johnson Matthey Technol. Rev., 2017, 61, (3), 183 LINK https://www.technology.matthey.com/article/61/3/183-189/ [Google Scholar]
  3. C. W. Davis, E. I. Du Pont de Nemours, ‘Process of Oxidizing Ammonia’, US Patent 1,706,055; 1929 [Google Scholar]
  4. S. L. Handforth, J. N. Tilley, Ind. Eng. Chem., 1934, 26, (12), 1287 LINK https://doi.org/10.1021/ie50300a016 [Google Scholar]
  5. A. E. Heywood, Platinum Metals Rev., 1973, 17, (4), 118 LINK https://www.technology.matthey.com/article/17/4/118-129/ [Google Scholar]
  6. B. T. Horner, Platinum Metals Rev., 1993, 37, (2), 76 LINK https://www.technology.matthey.com/article/37/2/76-85/ [Google Scholar]
  7. A. Bazhenov, G. Gushin, ‘Catalysts for Ammonia Oxidation’, Nitrogen+Syngas, September–October, 2017, 349, 1 LINK http://www.plaurum.sk/u/files/1bb94979b8c068417a1d109414fb5412.pdf/NS-349-Russia-lrprf3.pdf [Google Scholar]
  8. Y. Ning, Z. Yang, H. Zhao, Platinum Metals Rev., 1996, 40, (2), 80 LINK https://www.technology.matthey.com/article/40/2/80-87/ [Google Scholar]
  9. H. Gölitzer, D. Köenigs, J. Neumann, T. Stoll, Umicore AG & Co KG,, ‘Three-Dimensional Catalyst Gauzes Knitted in Two Layers’, European Patent, 1,358,010; 2002 [Google Scholar]
  10. M. C. E. Groves, ‘Nitric Acid’, in “Kirk-Othmer Encyclopedia of Chemical Technology”, John Wiley & Sons Inc, Hoboken, USA, 2020 LINK https://doi.org/10.1002/0471238961.1409201803120118.a01.pub3 [Google Scholar]
  11. T. Pignet, L. D. Schmidt, J. Catal., 1975, 40, (2), 212 LINK https://doi.org/10.1016/0021-9517(75)90249-3 [Google Scholar]
  12. M. Warner, B. S. Haynes, Proc. Combust. Inst., 2015, 35, (2), 2215 LINK http://dx.doi.org/10.1016/j.proci.2014.06.110 [Google Scholar]
  13. J. Pérez-Ramírez, E. V. Kondratenko, G. Novell-Leruth, J. M. Ricart, J. Catal., 2009, 261, (2), 217 LINK https://doi.org/10.1016/j.jcat.2008.11.018 [Google Scholar]
  14. L. Hannevold, O. Nilsen, A. Kjekshus, H. Fjellvåg, Appl. Catal. A: Gen., 2005, 284, (1–2), 163 LINK https://doi.org/10.1016/j.apcata.2005.01.033 [Google Scholar]
  15. J. A. Busby, A. G. Knapton, A. E. R. Budd, Proc. Fert. Soc., 1978, 169, 39 [Google Scholar]
  16. J. Mugo, G. Jones, 2018
  17. Fraunhofer ISI, ECOFYS BV and Öko-Institut eV,, “Methodology for the Free Allocation of Emission Allowances in the EU ETS Post 2012: Sector Report for the Chemical Industry”, Study Contract 07.0307/2008/515770/ETU/C2, Ecofys Project Number PECSNL082164, European Commission, Brussels, Belgium, November, 2009, 101 pp LINK https://ec.europa.eu/clima/sites/clima/files/ets/allowances/docs/bm_study-chemicals_en.pdf [Google Scholar]
  18. A. N. Salanov, E. A. Suprun, A. N. Serkova, N. M. Chesnokova, E. F. Sutormina, L. A. Isupova, V. N. Parmon, Kinet. Catal., 2020, 61, (3), 421 LINK https://doi.org/10.1134/S0023158420030179 [Google Scholar]
  19. E. Bergene, O. Tronstad, A. Holmen, J. Catal., 1996, 160, (2), 141 LINK https://doi.org/10.1006/jcat.1996.0133 [Google Scholar]
  20. R. J. Farrauto, H. C. Lee, Ind. Eng. Chem. Res., 1990, 29, (7), 1125 LINK https://doi.org/10.1021/ie00103a006 [Google Scholar]
  21. M. Wilson, H. Goddin, 2017
  22. O. Nilsen, A. Kjekshus, H. Fellvåg, Appl. Catal. A: Gen., 2001, 207, (1–2), 43 LINK https://doi.org/10.1016/S0926-860X(00)00615-3 [Google Scholar]
  23. M. R. Lyubovsky, V. V. Barelko, J. Catal., 1994, 149, (1), 23 LINK https://doi.org/10.1006/jcat.1994.1269 [Google Scholar]
  24. E. V. Kondratenko, J. Pérez-Ramírez, Appl. Catal. A: Gen., 2005, 289, (1), 97 LINK https://doi.org/10.1016/j.apcata.2005.04.017 [Google Scholar]
  25. G. M. Lawrence, Proc. Safe. Prog., 1989, 8, (1), 33 LINK https://doi.org/10.1002/prsb.720080111 [Google Scholar]
  26. F. Sperner, W. Hohmann, Platinum Metals Rev., 1976, 20, (1), 12 LINK https://www.technology.matthey.com/article/20/1/12-20/ [Google Scholar]
  27. A. Cowley, “Pgm Market Report”, Johnson Matthey, London, UK, February, 2020, 40 pp LINK http://www.platinum.matthey.com/documents/new-item/pgm%20market%20reports/pgm_market_report_february_2020.pdf [Google Scholar]
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