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Volume 67, Issue 3
  • ISSN: 2056-5135
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  • oa Electrochemical Synthesis of Monodisperse Platinum-Cobalt Nanocrystals

    Minimising environmental impact and increasing commercial viability

  • Authors: Daniel J. Rosen1, Duncan Zavanelli1 and Christopher B. Murray2
  • Affiliations: 1 Department of Materials Science and EngineeringUniversity of Pennsylvania, PhiladelphiaUSA 2 Department of Materials Science and Engineering and Department of ChemistryUniversity of Pennsylvania, PhiladelphiaUSA
  • Source: Johnson Matthey Technology Review, Volume 67, Issue 3, Jul 2023, p. 349 - 356
  • DOI: https://doi.org/10.1595/205651323X16799975192215
    • Received: 30 Nov 2022
    • Accepted: 03 Mar 2023
    • Published online: 28 Mar 2023

Abstract

The synthesis of platinum-cobalt nanocrystals (NCs) using colloidal solvothermal techniques is well understood. However, for monodisperse NCs to form, high temperatures and environmentally detrimental solvents are needed. We report a room temperature, aqueous method of platinum-cobalt NC synthesis using electrochemical reduction as the driving force for nucleation and growth. It is found that colloidal NCs will form in both the presence and absence of surfactant. Additionally, we report a monodisperse electrochemical deposition of NCs utilising a transparent conducting oxide electrode. The methods developed here will allow for a synthetic method to produce nanocatalysts with minimal environmental impact and should be readily applicable to other NC systems, including single- and multi-component alloys.

© Johnson Matthey
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2023-03-28
2024-12-26
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Electrochemical Synthesis of Monodisperse Platinum-Cobalt Nanocrystals
Johnson Matthey Technology Review 67, 349 (2023); https://doi.org/10.1595/205651323X16799975192215
/content/journals/10.1595/205651323X16799975192215
/content/journals/10.1595/205651323X16799975192215
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