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Volume 68, Issue 1
  • ISSN: 2056-5135
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  • oa Benchmarking Stability of Iridium Oxide in Acidic Media under Oxygen Evolution Conditions: A Review: Part I

    Probing degradation of iridium-based oxide catalysts

  • Authors: James Murawski1, Soren B. Scott1, Reshma Rao1, Katie Rigg2, Chris Zalitis2, James Stevens2, Jonathan Sharman2, Gareth Hinds3 and Ifan E. L. Stephens1
  • Affiliations: 1 Department of Materials, Imperial College LondonExhibition Road, London, SW7 2AZUK 2 Johnson MattheyBlount’s Court, Sonning Common, Reading, RG4 9NHUK 3 National Physical LaboratoryTeddington, Middlesex, TW11 0LWUK
  • Source: Johnson Matthey Technology Review, Volume 68, Issue 1, Jan 2024, p. 121 - 146
  • DOI: https://doi.org/10.1595/205651323X16848455435118
    • Received: 10 Feb 2023
    • Accepted: 22 May 2023
    • Published online: 23 May 2023

Abstract

State-of-the-art proton exchange membrane (PEM) electrolysers employ iridium-based catalysts to facilitate oxygen evolution at the anode. To enable scale-up of the technology to the terawatt level, further improvements in the iridium utilisation are needed, without incurring additional overpotential losses or reducing the device lifetime. The research community has only recently started to attempt systematic benchmarking of catalyst stability. Short term electrochemical methods alone are insufficient to predict catalyst degradation; they can both underestimate and overestimate catalyst durability. Complementary techniques, such as inductively coupled plasma-mass spectrometry (ICP-MS), are required to provide more reliable assessment of the amount of catalyst lost through dissolution. In Part I, we critically review the state of the art in probing degradation of iridium-based oxide catalysts.

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Benchmarking Stability of Iridium Oxide in Acidic Media under Oxygen Evolution Conditions: A Review: Part I
Johnson Matthey Technology Review 68, 121 (2024); https://doi.org/10.1595/205651323X16848455435118
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