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1887
Volume 68 Number 2
  • ISSN: 2056-5135
  • oa Mechanochemistry: A Green and Fast Method to Prepare a New Generation of Metal Supported Catalysts

    Rational design leads to novel properties

  • Authors: Maila Danielis1, Sara Colussi1, Núria J. Divins2, Lluís Soler2, Alessandro Trovarelli1 and Jordi Llorca2
  • Affiliations: 1 Dipartimento Politecnico, Università degli Studi di UdineVia del Cotonificio 108, 33100 UdineItaly 2 Departament d’Enginyeria Química, Institut de Tècniques Energètiques, Centre de Recerca de Ciència i Enginyeria Multiescala de Barcelona, Universitat Politècnica de Catalunya, EEBEEduard Maristany 10–14, 08019 BarcelonaSpain
  • Source: Johnson Matthey Technology Review, Volume 68, Issue 2, Apr 2024, p. 217 - 231
  • DOI: https://doi.org/10.1595/205651323X16933888986996
    • Received: 29 Jun 2023
    • Accepted: 29 Aug 2023
    • Published online: 30 Aug 2023

Abstract

In this review, we report on recent advances in the use of mechanochemistry to synthesise new catalytic materials. We report recent results obtained by our groups where a rational design of the milling parameters led to the synthesis of advanced materials with novel properties such as unconventional arrangements of metals on the surface of oxide support materials, highly dispersed metals or the stabilisation of species in particular oxidation states. These properties resulted in superior catalytic performances of the mechanochemically-synthesised catalysts compared to their counterparts prepared by traditional impregnation methods. To illustrate these advances, we review the progress made in two important fields of catalysis where noble metals are used: (i) emission control catalysis using palladium-based materials; (ii) the development of photocatalysts to produce hydrogen based on gold and palladium materials.

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2024-12-11
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/content/journals/10.1595/205651323X16933888986996
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