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1887
Volume 68, Issue 3
  • ISSN: 2056-5135

Abstract

Removal of sulfur compounds from transportation fuels is a requirement in the worldwide effort to reduce emissions from transportation fuels. Refineries use the hydrodesulfurisation (HDS) process to reduce sulfur compounds in fuels. However, the HDS process requires high hydrogen pressure and temperature, making it costly. An alternative to the HDS process is oxidative desulfurisation solvent extraction, which requires low-temperature operating conditions. In this regard, deep eutectic solvents (DESs) are attractive for researchers to desulfurise transportation fuels solvent extraction due to their low-cost. In our study, DESs were synthesised using phenylacetic acid (PAA) and salicylic acid (SAA) as hydrogen bond acceptors (HBAs) and tetraethylene glycol (TTEG) as hydrogen bond donor (HBD) in the mole ratio of 1:2. DESs were characterised by using Fourier transform infrared (FTIR) spectroscopy. Physicochemical properties of DESs, such as density, viscosity and refractive index, were also measured. The synthesised DESs were used to extract organosulfur compounds from model fuel and actual diesel. An oxidation study was carried out for model fuel and diesel, followed by solvent extraction using these synthesised DESs. The extraction efficiency for PAA/TTEG(1:2) and SAA/TTEG(1:2) was achieved as 50.16% and 38.89% for model fuel at a temperature of 30°C using a solvent to feed ratio of 1.0 while for diesel, it was 38% and 37%. However, it increased to 77%, 68% and 54%, 73%, respectively, for PAA/TTEG(1:2) and SAA/TTEG(1:2) when the feedstocks were oxidised. These results showed better extraction performance of DES PAA/TTEG(1:2) than that of SAA/TTEG(1:2) at low temperature 30°C using combined extractive catalytic oxidative desulfurisation. Hence, the DES synthesised using SAA and TTEG in the molar ratio of 1:2 works better as an extraction solvent for removing organic sulfur compounds from fuels at low temperatures.

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2023-10-04
2024-10-14
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References

  1. F. Lima, L. C. Branco, A. J. D. Silvestre, I. M. Marrucho, Fuel, 2021, 293, 120297 LINK https://doi.org/10.1016/j.fuel.2021.120297 [Google Scholar]
  2. R. Javadli, A. de Klerk, Appl. Petrochem. Res., 2012, 1, (1–4), 3 LINK https://doi.org/10.1007/s13203-012-0006-6 [Google Scholar]
  3. P. Sikarwar, V. Gosu, V. Subbaramaiah, Rev. Chem. Eng., 2019, 35, (6), 669 LINK https://doi.org/10.1515/revce-2017-0082 [Google Scholar]
  4. B. Rodríguez-Cabo, H. Rodríguez, E. Rodil, A. Arce, A. Soto, Fuel, 2014, 117, 882 LINK https://doi.org/10.1016/j.fuel.2013.10.012 [Google Scholar]
  5. S. Kumar, S. M. Nanoti, M. O. Garg, B. R. Nautiyal, P. Ghosh, P. Yadav, Nisha, ‘Integrated Process for Simultaneous Removal and Value Addition to the Sulfur and Aromatics Compounds of Gas Oil’, Council of Scientific and Industrial Research, New Delhi, India, US Patent, 10,190,064, 2019 [Google Scholar]
  6. Nisha, B. R. Nautiyal, P. Yadav, S. K. Singh, Indian J. Chem. Technol., 2019, 26, 458 [Google Scholar]
  7. S. Kumar, V. C. Srivastava, R. Raghuvanshi, S. M. Nanoti, N. Sudhir, Energy Fuels, 2015, 29, (7), 4634 LINK https://doi.org/10.1021/acs.energyfuels.5b00834 [Google Scholar]
  8. M. Y. Mohammed, T. M. Al-Bayati, A. M. Ali, AIP Conf. Proc., 2022, 2443, (1), 030026 LINK https://doi.org/10.1063/5.0091945 [Google Scholar]
  9. A. T. Kadhum, T. M. Albayati, AIP Conf. Proc., 2022, 2443, (1), 030039 LINK https://doi.org/10.1063/5.0092049 [Google Scholar]
  10. F. Boshagh, M. Rahmani, K. Rostami, M. Yousefifar, Energy Fuels, 2021, 36, (1), 98 LINK https://doi.org/10.1021/acs.energyfuels.1c03396 [Google Scholar]
  11. S. T. Ahmed, C. Muhammad, A. B. Muhammad, I. M. Danmallam, S. A. Zauro, B. A. Rafi, Petrol. Sci. Eng., 2023, 7, (1), 7 LINK https://doi.org/10.11648/j.pse.20230701.12 [Google Scholar]
  12. N. Saini, P. Yadav, K. Kumar, P. Ghosh, Mater. Today Proc., 2023, 73, (1), 189 LINK https://doi.org/10.1016/j.matpr.2022.10.009 [Google Scholar]
  13. M. Y. Mohammed, A. M. Ali, T. M. Albayati, Chem. Eng. Res. Design, 2022, 182, 659 LINK https://doi.org/10.1016/j.cherd.2022.03.047 [Google Scholar]
  14. M. Y. Mohammed, T. M. Albayati, A. M. Ali, Chem. Africa, 2022, 5, (5), 1715 LINK https://doi.org/10.1007/s42250-022-00447-9 [Google Scholar]
  15. Y. A. A. Al-Khodor, T. M. Albayati, Chem. Africa, 2022, 6, (2), 747 LINK https://doi.org/10.1007/s42250-022-00482-6 [Google Scholar]
  16. C. Florindo, F. Lima, B. D. Ribeiro, I. M. Marrucho, Curr. Opin. Green Sustain. Chem., 2019, 18, 31 LINK https://doi.org/10.1016/j.cogsc.2018.12.003 [Google Scholar]
  17. A. P. Abbott, J. C. Barron, K. S. Ryder, D. Wilson, Chem. Eur. J., 2007, 13, (22), 6495 LINK https://doi.org/10.1002/chem.200601738 [Google Scholar]
  18. A. P. Abbott, D. Boothby, G. Capper, D. L. Davies, R. K. Rasheed, J. Am. Chem. Soc., 2004, 126, (29), 9142 LINK https://doi.org/10.1021/ja048266j [Google Scholar]
  19. A. P. Abbott, Curr. Opin. Green Sustain. Chem., 2022, 36, 100649 LINK https://doi.org/10.1016/j.cogsc.2022.100649 [Google Scholar]
  20. R. Puttaswamy, C. Mondal, D. Mondal, D. Ghosh, Sust. Mater. Technol., 2022, 33, e00477 LINK https://doi.org/10.1016/j.susmat.2022.e00477 [Google Scholar]
  21. R. Gupta, B. Vats, A. K. Pandey, M. K. Sharma, P. Sahu, A. K. Yadav, Sk. M. Ali, S. Kannan, J. Phys. Chem. B, 2019, 124, (1), 181 LINK https://doi.org/10.1021/acs.jpcb.9b08197 [Google Scholar]
  22. N. Saini, K. Kumar, ‘Deep Eutectic Solvents in CO2 Capture’, in ‘CO2-Philic Polymers, Nanocomposites and Chemical Solvents’, Ch. 8, eds. A. Kumar Nadda, S. Sharma, S. Kalia, Elsevier Inc, Amsterdam, The Netherlands, 2023 LINK https://doi.org/10.1016/B978-0-323-85777-2.00012-3 [Google Scholar]
  23. I. Wazeer, M. K. Hadj-Kali, I. M. Al-Nashef, Molecules, 2020, 26, (1), 75 LINK https://doi.org/10.3390/molecules26010075 [Google Scholar]
  24. S. K. Shukla, J.-P. Mikkola, Phys. Chem. Chem. Phys., 2018, 20, (38), 24591 LINK https://doi.org/10.1039/c8cp03724h [Google Scholar]
  25. D. Y. C. Leung, G. Caramanna, M. M. Maroto-Valer, Renew. Sustain. Energy Rev., 2014, 39, 426 LINK https://doi.org/10.1016/j.rser.2014.07.093 [Google Scholar]
  26. D. Deng, Y. Jiang, X. Liu, Z. Zhang, N. Ai, J. Chem. Thermodyn., 2016, 103, 212 LINK https://doi.org/10.1016/j.jct.2016.08.015 [Google Scholar]
  27. L. Sun, Z. Zhu, T. Su, W. Liao, D. Hao, Y. Chen, Y. Zhao, W. Ren, H. Ge, H. , Appl. Catal. B: Environ., 2019, 255, 117747 LINK https://doi.org/10.1016/j.apcatb.2019.117747 [Google Scholar]
  28. S. E. E. Warrag, C. J. Peters, M. C. Kroon, Curr. Opin. Green Sustain. Chem., 2017, 5, 55 LINK https://doi.org/10.1016/j.cogsc.2017.03.013 [Google Scholar]
  29. M. Q. Farooq, G. A. Odugbesi, N. M. Abbasi, J. L. Anderson, Sustain. Chem. Eng., 2020, 8, (49), 18286 LINK https://doi.org/10.1021/acssuschemeng.0c06926 [Google Scholar]
  30. D. Chandran, M. Khalid, R. Walvekar, N. M. Mubarak, S. Dharaskar, W. Y. Wong, T. C. S. M. Gupta, J. Mol. Liq., 2019, 275, 312 LINK https://doi.org/10.1016/j.molliq.2018.11.051 [Google Scholar]
  31. M. Y. Mohammed, A. M. Ali, T. M. Albayati, Chem. Africa, 2022, 6, (3), 1595 LINK https://doi.org/10.1007/s42250-022-00568-1 [Google Scholar]
  32. A. Abbasi, F. Feyzi, Pet. Sci. Technol., 2021, 40, (6), 751 LINK https://doi.org/10.1080/10916466.2021.2007123 [Google Scholar]
  33. W. Liu, W. Jiang, W. Zhu, W. Zhu, H. Li, T. Guo, W. Zhu, H. Li, J. Mol. Catal. A: Chem., 2016, 424, 261 LINK https://doi.org/10.1016/j.molcata.2016.08.030 [Google Scholar]
  34. L. Xu, Y. Luo, H. Liu, J. Yin, H. Li, W. Jiang, W. Zhu, H. Li, H. Ji, J. Mol. Liq., 2021, 338, 116620 LINK https://doi.org/10.1016/j.molliq.2021.116620 [Google Scholar]
  35. Mohd. F. Majid, H. F. Mohd Zaid, C. Fai Kait, K. Jumbri, J. W. Lim, A. N. Masri, S. M. Mat Ghani, H. Yamagishi, Y. Yamamoto, B. Yuliarto, Processes, 2020, 8, (7), 848 LINK https://doi.org/10.3390/pr8070848 [Google Scholar]
  36. W. Liu, T. Li, G. Yu, J. Wang, Z. Zhou, Z. Ren, Fuel, 2020, 265, 116967 LINK https://doi.org/10.1016/j.fuel.2019.116967 [Google Scholar]
  37. W. Ye, T. Wang, Energy Fuels, 2023, 37, (7), 4973 LINK https://doi.org/10.1021/acs.energyfuels.2c04072 [Google Scholar]
  38. H. Lee, S. Kang, Y. Jin, D. Jung, K. Park, K. Li, J. Lee, Fuel, 2020, 264, 116848 LINK https://doi.org/10.1016/j.fuel.2019.116848 [Google Scholar]
  39. Q. Wang, T. Zhang, S. Zhang, Y. Fan, B. Chen, Sep. Purif. Technol., 2020, 231, 115923 LINK https://doi.org/10.1016/j.seppur.2019.115923 [Google Scholar]
  40. N. Sudhir, P. Yadav, B. R. Nautiyal, R. Singh, H. Rastogi, H. Chauhan, Sep. Sci. Technol., 2019, 55, (3), 554 LINK https://doi.org/10.1080/01496395.2019.1569061 [Google Scholar]
  41. N. Saini, B. R. Nautiyal, R. Singh, Pet. Sci. Technol., 2022, 40, (14), 1772 LINK https://doi.org/10.1080/10916466.2022.2030356 [Google Scholar]
  42. K. Shahbaz, S. Baroutian, F. S. Mjalli, M. A. Hashim, I. M. Al Nashef, Thermochim. Acta, 2012, 527, 59 LINK https://doi.org/10.1016/j.tca.2011.10.010 [Google Scholar]
  43. N. R. Rodriguez, J. Ferre Guell, M. C. Kroon, J. Chem. Eng. Data, 2016, 61, (2), 865 LINK https://doi.org/10.1021/acs.jced.5b00717 [Google Scholar]
  44. O. Ciocirlan, O. Iulian, J. Serb. Chem. Soc., 2009, 74, (3), 317 LINK https://doi.org/10.2298/jsc0903317c [Google Scholar]
  45. N. R. Rodriguez, T. Gerlach, D. Scheepers, M. C. Kroon, I. Smirnova, J. Chem. Thermodyn., 2017, 104, 128 LINK https://doi.org/10.1016/j.jct.2016.09.021 [Google Scholar]
  46. N. F. Gajardo-Parra, V. P. Cotroneo-Figueroa, P. Aravena, V. Vesovic, R. I. Canales, J. Chem. Eng. Data, 2020, 65, (11), 5581 LINK https://doi.org/10.1021/acs.jced.0c00715 [Google Scholar]
  47. R. Gautam, N. Kumar, J. G. Lynam, J. Mol. Struct., 2020, 1222, 128849 LINK https://doi.org/10.1016/j.molstruc.2020.128849 [Google Scholar]
  48. R. K. Ibrahim, M. Hayyan, M. A. Alsaadi, S. Ibrahim, A. Hayyan, M. A. Hashim, Stud. Univ. Babes-Bolyai Chem., 2017, 62, 433https://doi.org/10.24193/subbchem.2017.4.37 [Google Scholar]
  49. M. K. AlOmar, M. Hayyan, M. A. Alsaadi, S. Akib, A. Hayyan, M. A. Hashim, J. Mol. Liq., 2016, 215, 98 LINK https://doi.org/10.1016/j.molliq.2015.11.032 [Google Scholar]
  50. C. Shu, T. Sun, Sep. Sci. Technol., 2016, 51, (8), 1336 LINK https://doi.org/10.1080/01496395.2016.1155602 [Google Scholar]
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