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Volume 70, Issue 3
  • ISSN: 2056-5135
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  • oa Unveiling the Potential of Platinum in Homogeneous Catalysis: A Review of Platinum--Heterocyclic Carbene Chemistry and Platinum-Catalysed Hydrosilylation Reactions: Part II

    Foundations and progress in catalytic hydrosilylation of alkenes and alkynes

  • Authors: Benon P. Maliszewski1ORCID icon, Eleonora Casillo1ORCID icon, Thomas Scattolin2ORCID icon, Fady Nahra1,3,*ORCID icon, Catherine S. J. Cazin1,§ORCID icon and Steven P. Nolan1,‡ORCID icon
  • 1 Department of Chemistry and Centre for Sustainable Chemistry, Ghent University, Krijgslaan 281–Building S3, 9000 Ghent, Belgium 2 Department of Chemical Sciences, University of Padova, Via Marzolo, 1-35131 Padova, Italy 3 Flemish Institute for Technological Research (VITO), Materials & Chemistry (MATCH) Unit, Boeretang 200, 2400 Mol, Belgium
    *[email protected]; §[email protected]; ‡[email protected]
  • Source: Johnson Matthey Technology Review, Volume 70, Issue 3, Jul 2026, e70301
  • DOI: https://doi.org/10.1595/205651326X17524853738449
    • Received: 27 May 2025
    • Accepted: 11 Jul 2025

Abstract

This is Part II of the review discussing the role of molecular platinum complexes in homogeneous catalysis, with a focus on platinum--heterocyclic carbene (NHC) pre-catalysts introduced in Part I (1). The following sections are devoted to the development of platinum-catalysed hydrosilylation of alkenes and alkynes, providing both historical context and an overview of the evolution in the mechanistic understanding of this reaction, as well as the most recent advancements and alternatives based on non-platinum catalysts.

© 2026 Johnson Matthey
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Unveiling the Potential of Platinum in Homogeneous Catalysis: A Review of Platinum-N-Heterocyclic Carbene Chemistry and Platinum-Catalysed Hydrosilylation Reactions: Part II
Johnson Matthey Technology Review 70, e70301 (2026); https://doi.org/10.1595/205651326X17524853738449
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/content/journals/10.1595/205651326X17524853738449
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