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Johnson Matthey Technology Review - Fast Track
Accepted manuscripts have been peer reviewed (where appropriate) and accepted for publication but have not yet been copyedited, house styled, proofread or typeset. The final published version may contain differences as a result of these procedures.
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Fast Track articles
21 - 26 of 26 Fast Track articles
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Magnetron Sputtering of Antibacterial and Antifungal Ta-Cu and Nb-Cu Coatings on 3D-Printed Porous Titanium Alloy Scaffolds
Available online: 15 May 2024More LessThis study evaluates the antimicrobial efficacy of Ta-Cu and Nb-Cu coatings, applied via magnetron sputtering on 3D-printed porous Ti6Al4V alloy scaffolds and gas-abrasive treated Ti6Al4V alloy, against Staphylococcus aureus and Candida albicans. Scanning electron microscopy with energy-dispersive X-ray analysis verified the application of coatings with 25 wt.% Cu, at thicknesses of 2 μm and 10 μm, to scaffolds (72% porosity) and roughened Ti6Al4V alloy (mean areal roughness of 4.6±1 µm). Thicker coatings showed superior antimicrobial activity; however, thin Nb-Cu coatings and uncoated alloy did not exhibit inhibitory effects. The release dynamics of Cu ions from Ta-Cu coatings into physiological solution, analysed over three days via inductively coupled plasma mass spectrometry, matched the inhibition zone growth. These findings support the potential of these coatings in developing endoprosthesis implants with enhanced antimicrobial properties.
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Effectiveness Evaluation of Pyrometallurgy and Hydrometallurgy Methods in The Recycling Process of Nd-Fe-B Permanent Magnet and Rare Earth Metals Recovery : A Review
Available online: 10 May 2024More LessNd-Fe-B is a rare earth element (REE) based permanent magnet material which consist of main magnetic phase Nd2Fe14B and minor phase Nd-rich or α-Fe. Nd-Fe-B permanent magnet has a remarkable maximum energy product (BHMax) reaching 474 kJ/m3 or nearly 60 MGOe, making Nd-Fe-B magnets as the ultimate permanent magnet material and widely used in various technological applications. A commercial Nd-Fe-B magnet contains 22-32 wt% of rare earth elements such as Nd, Dy, Pr, and La, which causes an increasing demand for rare earth elements. As a results, the availability of REE from natural resources are decreasing and several REE such as Nd, Dy, and Pr are in the critical category. The recycling process of Nd-Fe-B magnet waste to recover the containing REE is one possible solution to provide raw materials for permanent magnet industry and minimizing electronical devices waste. Pyrometallurgical and hydrometallurgical metal extraction process are commonly used for REE recovery process. These two methods are excellent for REE recovery and relatively easy to conduct, allowing pyrometallurgical and hydrometallurgical methods to be adopted on industrial scale to the availability of raw materials for Nd-Fe-B magnet industry.
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Slurry Jet Erosion Resistance of SS304 Reinforced with High Entropy Alloys through Friction Stir Processing
Available online: 08 May 2024More LessThe present work adopts friction stir processing to process SS304 with CoCrFeCuTi and AlSiBeTiV High Entropy Alloy (HEA) and analyse its erosion performance. The processed samples with CoCrFeCuTi and AlSiBeTiV display refined grain structure with uniform distribution of the reinforced HEAs. The microhardness for the sample with CoCrFeCuTi is 22.1% better than the AlSiBeTiV. The slurry jet erosion test conducted through different process parameters revealed 90° impingement angle and 10 m/s impact velocity with 10 wt% slurry concentration on the processed sample with CoCrFeCuTi offered better erosion resistance. Oblique angle endured high erosion rate due to the ploughing effect of abrasive erodent than normal angle deforming the surface. Increasing velocity increased the erosion rate by increased material removal. Slurry concentration forms a cloud-like layer at higher concentrations lowering the erosion rate. The subsequent microstructural evaluation showed the failure mode through the formation of platelets, micro-cuts, ploughing, and plastic deformation.
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Effect of Hf on the Microstructure and Mechanical Property of Pt-15Ir-xHf-0.5Y Alloy
Available online: 23 April 2024More LessThe influence of Hf content on the recrystallization and aging behavior of hot-rolled Pt-15Ir-xHf-0.5Y alloy was investigated by SEM, EBSD and hardness tests. The results show that the alloy texture evolves from a multi-peak one biased towards rolling direction-transverse direction (RD-TD) in the hot rolling state to a multi-peak one symmetrical along the normal direction (ND) after recrystallization annealing. The fibrous grains become equiaxial after recrystallization annealing, increase of Hf content refines the grains. Pt-15Ir-xHf-0.5Y alloy exhibits age-hardening behavior at the temperature range of 600°C~900°C, which is due to the precipitation of (Pt, Ir)5Y phase. Increasing Hf addition effectively improves the hardness through promoting the precipitated amount of (Pt, Ir)5Y phase. However, the internal oxidation within grain boundaries is deteriorated with the high-content Hf addition. The results of this study provide an insight into tailoring the microstructures and mechanical properties of the Pt-Ir high-temperature alloys.
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A New Approach to Ti-HA Bio Composite: Pressure-Assisted Coating on the Antibacterial and Electrochemical Properties of Ti6Al4V
Available online: 23 April 2024More LessThis study aims to coat Ti6Al4V alloy with Ti-xHA (x=2.5-10wt.%) mixture to improve its surface properties. A new approach using a powder metallurgical pressure-assisted sintering method was applied to the coating process. The in-situ sintering and coating process was performed at 950°C for 45 min in a vacuum atmosphere of 10-4 mbar. A pressure of 50MPa was applied during the sintering process. Staphylococcus aureus (ATCC 29213) and Escherichia coli (ATCC 25922) cultures were used to determine the antibacterial activity of the sintered and coated samples. The electrochemical properties of the samples were studied by Tafel extrapolation and potentiodynamic polarization tests. The results showed that the coating layer containing wt.%7.5 of HA increased the antibacterial property against gram-positive and gram-negative bacterial cultures. Furthermore, it was determined that the icorr value of the material decreased, and the corrosion resistance improved with an increasing HA ratio. In addition, no active-passive oxidation zone formation was observed up to 2000 mV in the HA-added samples.
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Autonomous Structural Health Monitoring and Remaining Useful Life Estimation of Floating Offshore Wind Turbine Cables
Available online: 08 April 2024More LessAbstract— Floating offshore wind (FOW) farms are key in meeting Europe’s renewable energy targets, harnessing wind energy from waters 60m or deeper, where bottom-fixed farms are unfeasible. Additionally, floating structures allow for the installation of larger turbines than stationary farms, which in turn leads to a greater energy output. However, cable failures dramatically impact the energy transmission from the farms and cause most of the financial losses. Monitoring and maintenance tasks are challenging due to the harsh ocean conditions. The FLOW-CAM project, supported by European Union’s HORIZON 2020 program, studies the structural health monitoring (SHM) of defects in the power cables of the FOW farms which encompass inspection and detection applications. An SHM system integrated with a remotely operated vehicle (ROV) was developed for underwater inspection and maintenance, supporting collection and presentation of essential data through an advanced interface. Image data from underwater systems are analyzed using computer vision techniques. Investigations into cable defect detection and the estimation of corrosion and remaining useful life have been held to monitor cable health, achieving results close to reality. FLOW-CAM’s collective works establish a basis for advancing underwater inspection and maintenance, concentrating on the development of practical and effective tools and strategies to optimize the functionality and reliability of FOW farms.
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