Skip to content
1887
Volume 62, Issue 2
  • ISSN: 2056-5135

Abstract

Fast pyrolysis for liquids has been developed in recent decades as a fast and flexible method to provide high yields of liquid products. An overview of this promising field is given, with a comprehensive introduction as well as a practical guide to those thinking of applying bio-oils or fast pyrolysis liquids in various applications. It updates the literature with recent developments that have occurred since the reviews cited herein. Part I gave an introduction to the background, science, feedstocks, technology and products available for fast pyrolysis (1). Part II details some of the promising applications as well as pre-treatment and bio-oil upgrading options. The applications include use of bio-oil as an energy carrier, precursor to second generation biofuels, as a biorefinery concept and upgrading to fuels and chemicals.

Loading

Article metrics loading...

/content/journals/10.1595/205651318X696738
2018-01-01
2024-05-02
Loading full text...

Full text loading...

/deliver/fulltext/jmtr/62/2/Bridgwater_II_16a_Imp.html?itemId=/content/journals/10.1595/205651318X696738&mimeType=html&fmt=ahah

References

  1. Bridgwater A. V. Johnson Matthey Technol. Rev., 2018, 62, (1), 118 LINK http://www.technology.matthey.com/article/62/1/118-130/ [Google Scholar]
  2. Czernik S., and Bridgwater A. V. Energy Fuels, 2004, 18, (2), 590 LINK https://doi.org/10.1021/ef034067u [Google Scholar]
  3. Bridgwater A. V. ‘Technical and Economic Assessment of Thermal Processes for Biofuels’, Report for Life Cycle and Techno-Economic Assessment of the Northeast Biomass to Liquids Project, NNFCC Project 08/018, Consultants on Process Engineering Ltd, Solihull, UK, June, 2009 LINK http://www.gluedlimited.co.uk/copeltd/pdf/AV_Bridgwater_Biofuels_Report2009.pdf [Google Scholar]
  4. Chiaramonti D., Oasmaa A., and Solantausta Y. Renew. Sust. Energy Rev., 2007, 11, (6), 1056 LINK https://doi.org/10.1016/j.rser.2005.07.008 [Google Scholar]
  5. Dang Q., Wright M. M., and Brown R. C. Environ. Sci. Technol., 2015, 49, (24), 14688 LINK https://doi.org/10.1021/acs.est.5b03548 [Google Scholar]
  6. Kamm B., Gruber P. R., and Kamm M. ‘Biorefineries – Industrial Processes and Products’, in “Ullmann’s Encyclopedia of Industrial Chemistry”, Wiley-VCH Verlag GmbH & Co KGaA, Weinheim, Germany, 2007 LINK https://doi.org/10.1002/14356007.l04_l01 [Google Scholar]
  7. Maggi R. E., Elliott D. C., ‘Upgrading Overview’, in “Developments in Thermochemical Biomass Conversion”, eds. Bridgwater A. V., and Boocock D. G. B. Springer Science+Business Media Dordrecht, The Netherlands, 1997, pp. 575588 LINK https://doi.org/10.1007/978-94-009-1559-6_45 [Google Scholar]
  8. Bridgwater A. V. Catal. Today, 1996, 29, (1–4), 285 LINK https://doi.org/10.1016/0920-5861(95)00294-4 [Google Scholar]
  9. Bridgwater A. V. Appl. Catal. A: Gen., 1994, 116, (1–2), 5 LINK https://doi.org/10.1016/0926-860X(94)80278-5 [Google Scholar]
  10. Zhang Q., Chang J., Wang T., and Xu Y. Energy Convers. Manage., 2007, 48, (1), 87 LINK https://doi.org/10.1016/j.enconman.2006.05.010 [Google Scholar]
  11. Diebold J. P., Czernik S., Scahill J. W., Philips S. D., and Feik C. J. ‘Hot-Gas Filtration to Remove Char from Pyrolysis Vapours Produced in the Vortex Reactor at NREL’, NREL/CP-430-7215, Biomass Pyrolysis Oil Properties and Combustion Meeting, Estes Park, USA, 26th–28th September, 1994, pp. 90108 LINK www.osti.gov/scitech/servlets/purl/1114056 [Google Scholar]
  12. Shihadeh A. L. ‘Rural Electrification from Local Resources: Biomass Pyrolysis Oil Combustion in a Direct Injection Diesel Engine’, PhD Thesis, Department of Mechanical Engineering, Massachusetts Institute of Technology, Massachusetts, USA, September, 1998 LINK http://hdl.handle.net/1721.1/43601 [Google Scholar]
  13. Sitzmann J., and Bridgwater A. V. ‘Upgrading Fast Pyrolysis Oils by Hot Vapour Filtration’, 15th European Energy from Biomass Conference & Exhibition, Berlin, Germany, 7th–11th May, 2007, pp. 13781383 [Google Scholar]
  14. Diebold J. P., and Czernik S. Energy Fuels, 1997, 11, (5), 1081 LINK https://doi.org/10.1021/ef9700339 [Google Scholar]
  15. Ikura M., Mirmiran S., Stanciulescu M., and Sawatzky H. “Pyrolysis Liquid-in-Diesel Oil Microemulsions”, US Patent, 5,820,640; 1998 [Google Scholar]
  16. Baglioni P., Chiaramonti D., Bonini M., Soldaini I., Tondi G., ‘Bio-Crude-Oil/Diesel Oil Emulsification: Main Achievements of the Emulsification Process and Preliminary Results of Tests on Diesel Engine’, in “Progress in Thermochemical Biomass Conversion”, ed. and Bridgwater A. V. Blackwell Science Ltd, Oxford, UK, 2001, pp. 15251539 LINK https://doi.org/10.1002/9780470694954.ch126 [Google Scholar]
  17. Chiaramonti D., Bonini M., Fratini E., Tondi G., Gartner K., Bridgwater A. V., Grimm H. P., Soldaini I., Webster A., and Baglioni P. Biomass Bioenerg., 2003, 25, (1), 85 LINK https://doi.org/10.1016/S0961-9534(02)00183-6 [Google Scholar]
  18. Chiaramonti D., Bonini M., Fratini E., Tondi G., Gartner K., Bridgwater A. V., Grimm H. P., Soldaini I., Webster A., and Baglioni P. Biomass Bioenerg., 2003, 25, (1), 101 LINK https://doi.org/10.1016/S0961-9534(02)00184-8 [Google Scholar]
  19. Alcala A., and Bridgwater A. V. Fuel, 2013, 109, 417 LINK https://doi.org/10.1016/j.fuel.2013.02.058 [Google Scholar]
  20. Radlein D. ‘The Production of Chemicals from Fast Pyrolysis Bio-Oils’, in “Fast Pyrolysis of Biomass: A Handbook”, CPL Press, Newbury, UK, 1999, pp. 164188 [Google Scholar]
  21. ‘Food Flavouring (Smoke)’, Task 34, IEA Bioenergy, International Energy Agency, Paris, France:http://task34.ieabioenergy.com/food-flavoring/ (Accessed on 22nd February 2018) [Google Scholar]
  22. ‘Hydroxyacetaldehyde’, Task 34, IEA Bioenergy, International Energy Agency, Paris, France:http://task34.ieabioenergy.com/hydroxyacetaldehyde/ (Accessed on 22nd February 2018) [Google Scholar]
  23. Hodge J. E. J. Agric. Food Chem., 1953, 1, (15), 928 LINK https://doi.org/10.1021/jf60015a004 [Google Scholar]
  24. ‘Levoglucosan: Historical Developments and Current Status of Levoglucosan Production and Uses’, Task 34, IEA Bioenergy, International Energy Agency, Paris, France:http://task34.ieabioenergy.com/levoglucosan/ (Accessed on 22nd February 2018) [Google Scholar]
  25. Blanco-Sanchez P., Lad J., and Bridgwater A. V. ‘Glucose Production from Anhydrosugars by Acid Hydrolysis’, 6th International Symposium on Energy from Biomass and Waste, International Waste Working Group, Venice, Italy, 14th–17th November, 2016 [Google Scholar]
  26. ‘Acetic Acids: Made from Beechwood’, proFagus GmbH, Bodenfelde, Germany: http://profagus.de/en/acetic-acids/ (Accessed on 9th November, 2017) [Google Scholar]
  27. Elliott D. C., Baker E. G., ‘Hydrotreating Biomass Liquids to Produce Hydrocarbon Fuels’, in “Energy from Biomass and Wastes X”, ed. and Klass D. L. IGT, Chicago, USA, 1987, pp. 765784 [Google Scholar]
  28. Baker E. G., Elliott D. C., ‘Catalytic Upgrading of Biomass Pyrolysis Oils’, in “Research in Thermochemical Biomass Conversion”, eds. Bridgwater A. V., and Kuester J. L. Elsevier Science Publishers Ltd, London, UK, 1988, pp. 883895 LINK https://doi.org/10.1007/978-94-009-2737-7_67 [Google Scholar]
  29. Baker E. G., Elliott D. C., ‘Catalytic Hydrotreating of Biomass-Derived Oils’, in “Pyrolysis Oils from Biomass: Producing, Analyzing and Upgrading”, eds. Soltes J., and Milne T. A. 376, American Chemical Society, Washington, DC, USA, 1988, pp. 228240 LINK https://doi.org/10.1021/bk-1988-0376.ch021 [Google Scholar]
  30. Elliott D. C., Neuenschwander G. N., ‘Liquid Fuels by Low-Severity Hydrotreating of Biocrude’, in “Developments in Thermochemical Biomass Conversion”, eds. Bridgwater A. V., and Boocock D. G. B. 1, Springer Science+Business Media, Dordrecht, The Netherlands, 1997, pp. 611621 [Google Scholar]
  31. Maggi R., Delmon B., ‘Characterization of Bio-Oils Produced by Pyrolysis’, in “Advances in Thermochemical Biomass Conversion”, ed. and Bridgwater A. V. 1, Springer Science+Business Media, Dordrecht, The Netherlands, 1993, pp. 10861094 LINK https://doi.org/10.1007/978-94-011-1336-6_83 [Google Scholar]
  32. Grange P., Laurent E., Maggi R., Centeno A., and Delmon B. Catal. Today, 1996, 29, (1–4), 297 LINK https://doi.org/10.1016/0920-5861(95)00295-2 [Google Scholar]
  33. Jones S. B., Holladay J. E., Valkenburg C., Stevens D. J., Walton C. W., Kinchin C., Elliott D. C., and Czernik S. “Production of Gasoline and Diesel from Biomass via Fast Pyrolysis, Hydrotreating and Hydrocracking: A Design Case”, PNNL-18284, Pacific Northwest National Laboratory, Richland, Washington, USA, February, 2009, 76 pp LINK https://www.pnnl.gov/main/publications/external/technical_reports/PNNL-18284.pdf [Google Scholar]
  34. Eijsbouts S., Mayo S. W., and Fujita K. Appl. Catal. A: Gen., 2007, 322, 58 LINK https://doi.org/10.1016/j.apcata.2007.01.008 [Google Scholar]
  35. ‘UOP and Ensyn to Form Joint Venture to Offer Second Generation Biomass Technology’, Honeywell UOP, Illinois, USA, 10th September, 2008 LINK https://www.uop.com/?press_release=uop-and-ensyn-to-form-joint-venture-to-offer-second-generation-biomass-technology [Google Scholar]
  36. Elliott D. C., and Hart T. R. Energy Fuels, 2009, 23, (2), 631 LINK https://doi.org/10.1021/ef8007773 [Google Scholar]
  37. Lane J. ‘KiOR: The Inside True Story of a Company Gone Wrong’, Biofuels Digest, Miami, USA, 17th May, 2016 LINK http://www.biofuelsdigest.com/bdigest/2016/05/17/kior-the-inside-true-story-of-a-company-gone-wrong [Google Scholar]
  38. Fehrenbacher K. ‘A Biofuel Dream Gone Bad’, Fortune, Time Inc, New York City, USA, 4th December, 2015 LINK http://fortune.com/kior-vinod-khosla-clean-tech/ [Google Scholar]
  39. ‘Technology’, Anellotech: http://anellotech.com/technology (Accessed on 28th January 2018) [Google Scholar]
  40. Diebold J. P., and Scahill J. W. Energy Prog., 1988, 8, (1), 59 [Google Scholar]
  41. Cheng Y. T., and Huber G. W. Green Chem., 2012, 14, (11), 3114 LINK https://doi.org/10.1039/C2GC35767D [Google Scholar]
  42. ‘What We Do’, Inaeris Technologies: http://www.inaeristech.com/technology.html (Accessed 9th November 2017) [Google Scholar]
  43. “Future Roles of FCC and Hydroprocessing Units in Modern Refineries Fluid Catalytic Cracking”, Hydrocarbon Publishing Co, Paoli, USA, March, 2009 LINK http://www.hydrocarbonpublishing.com/store10/product.php?productid=C00901&srchkey= [Google Scholar]
  44. Freeman C. J., Jones S. B., Padmaperuma A. B., Santosa M., Valkenburg C., and Shinn J. “Initial Assessment of U.S. Refineries for Purposes of Potential Bio-Based Oil Insertions”, PNNL-22432, Pacific Northwest National Laboratory, Richland, Washington, USA, April, 2013, 35 pp LINK www.pnl.gov/main/publications/external/technical_reports/PNNL-22432.pdf [Google Scholar]
  45. Huber G. W., and Corma A. Angew. Chem. Int. Ed., 2007, 46, (38), 7184 LINK https://doi.org/10.1002/anie.200604504 [Google Scholar]
  46. de Rezende Pinho A., de Almeida M. B. B., Mendes F. L., Talmadge M. S., Kinchin C. M., and Chum H. L. Fuel, 2017, 188, 462 LINK https://doi.org/10.1016/j.fuel.2016.10.032 [Google Scholar]
  47. Thegarid N., Fogassy G., Schuurman Y., Mirodatos C., Stefanidis S., Iliopoulou E. F., Kalogiannis K., and Lappas A. A. Appl. Catal. B: Environ., 2014, 145, 161 LINK https://doi.org/10.1016/j.apcatb.2013.01.019 [Google Scholar]
  48. Sharma R. K., and Bakhshi N. N. Energy Fuels, 1993, 7, (2), 306 LINK https://doi.org/10.1021/ef00038a022 [Google Scholar]
  49. Adjaye J. D., and Bakhshi N. N. Fuel Process. Technol., 1995, 45, (3), 185 LINK https://doi.org/10.1016/0378-3820(95)00040-E [Google Scholar]
  50. Calis H. P. A., Haan J. P., Boerrigter H., van der Drift A., Peppink G., van den Broek R., Faaij A. P. C., Venderbosch R. H., ‘Preliminary Techno-Economic Analysis of Large-Scale Synthesis Gas Manufacturing from Imported Biomass’, in “Pyrolysis and Gasification of Biomass and Waste”, ed. and Bridgwater A. V. Proceedings from Strasbourg, 30th September–1st October, 2002, CPL Press Newbury, UK, 2003, pp. 403418 [Google Scholar]
  51. Morehead H. ‘Siemens Gasification and IGCC Update’, Gasification Technologies 2008, Washington, DC, 7th October, 2008 [Google Scholar]
  52. Volkmann D. ‘Update on Technology and Projects’, Gasification Technologies Conference, Washington DC, USA, October, 2004 LINK http://www.gasification-syngas.org/uploads/eventLibrary/21VOLK.pdf [Google Scholar]
  53. Dahmen N., Abeln J., Eberhard M., Kolb T., Leibold H., Sauer J., Stapf D, and Zimmerlin B. WIREs Energy Environ., 2017, 6, (3), e236 LINK https://doi.org/10.1002/wene.236 [Google Scholar]
  54. Robota H. J., Richard L. A., Deshmukh S., LeViness S., Leonarduzzi D., and Roberts D. Catal. Surv. Asia, 2014, 18, (4), 177 LINK https://doi.org/10.1007/s10563-014-9175-x [Google Scholar]
  55. Bridgwater A. V., ‘Pyrolysis of Biomass’, in “Transformations to Effective Use: Biomass Power for the World”, eds. van Swaaij W., Kersten S., and Palz W. Pan Stanford Publishing Pte Ltd, Singapore, 2015, pp. 473514 [Google Scholar]
http://instance.metastore.ingenta.com/content/journals/10.1595/205651318X696738
Loading
/content/journals/10.1595/205651318X696738
Loading

Data & Media loading...

  • Article Type: Research Article
This is a required field
Please enter a valid email address
Approval was a Success
Invalid data
An Error Occurred
Approval was partially successful, following selected items could not be processed due to error