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1887
Volume 65, Issue 2
  • ISSN: 2056-5135

Abstract

The restructuring of the economy post-COVID-19 coupled to the drive towards Net Zero carbon dioxide emissions means we must rethink the way we use transport fuels. Fossil-carbon based fuels are ubiquitous in the transport sector, however there are alternative synthetic fuels that could be used as drop-in or replacement fuels. The main hurdles to achieving a transition to synthetic fuels are the limited availability of low-cost carbon dioxide at an appropriate purity, the availability of renewable hydrogen and, in the case of hydrocarbons, catalysts that are selective for small and particular chain lengths. In this paper we will consider some of the alternative fuels and methods that could reduce cost, both economically and environmentally. We recommend that increased effort in the rapid development of these fuels should be a priority in order to accelerate the possibility of achieving Net Zero without costly infrastructure changes. As ground transportation offers a more straightforward approach legislatively, we will look at oxygenated organic fuels as an alternative drop-in replacement for hydrocarbons.

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2021-01-01
2024-11-27
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References

  1. P. Styring, E. A. Quadrelli, K. Armstrong, “Carbon Dioxide Utilisation: Closing the Carbon Cycle”,Elsevier, Amsterdam, The Netherlands, 2015 LINK https://doi.org/10.1016/C2012-0-02814-1 [Google Scholar]
  2. J. Priestley, “Directions for Impregnating Water with Fixed Air: In Order to Communicate to it the Peculiar Spirit and Virtues of Pyrmont Water, and Other Mineral Waters of a Similar Nature”,J. Johnson, London, UK, 1772 LINK www.drinkingcup.net/1767-from-volcanos-to-soda-pop/ [Google Scholar]
  3. P. M. Maitlis, A. de Klerk, “Greener Fischer-Tropsch Processes: For Fuels and Feedstocks”,Wiley, Weinheim, Germany, 2013 LINK https://doi.org/10.1002/9783527656837 [Google Scholar]
  4. “Sustainable Synthetic Carbon Based Fuels for Transport: Policy Briefing”,The Royal Society, London, UK, September, 2019 LINK https://royalsociety.org/-/media/policy/projects/synthetic-fuels/synthetic-fuels-briefing.pdf [Google Scholar]
  5. W. Willems, ‘Sustainable Fuels for Future Mobility: The DME Opportunity for CI-Engines’,8th International DME Conference,Sacramento, CA, USA,10th–12th September, 2018 [Google Scholar]
  6. ‘Fossil and Alternative Fuels - Energy Content’,The Engineering Toolbox, 2008 LINK https://www.engineeringtoolbox.com/fossil-fuels-energy-content-d_1298.html [Google Scholar]
  7. ‘Fuels - Higher and Lower Calorific Values’,The Engineering Toolbox, 2003 LINK https://www.engineeringtoolbox.com/fuels-higher-calorific-values-d_169.html [Google Scholar]
  8. M. C. Molstad, B. F. Dodge, Ind. Eng. Chem., 1935, 27, (2), 134 LINK https://doi.org/10.1021/ie50302a005 [Google Scholar]
  9. G. A. Olah, Angew. Chem. Int. Ed., 2013, 52, 1, 104 LINK https://doi.org/10.1002/anie.201204995 [Google Scholar]
  10. C. Hobson, C. Márquez, “Renewable Methanol Report”,Methanol Institute, Singapore, December, 2018 LINK https://www.methanol.org/wp-content/uploads/2019/01/MethanolReport.pdf [Google Scholar]
  11. K. Larmier, W.-C. Liao, S. Tada, E. Lam, R. Verel, A. Bansode, A. Urakawa, A. Comas-Vives, C. Copéret, Angew. Chem. Int. Ed., 2017, 56, (9), 2318 LINK https://doi.org/10.1002/anie.201610166 [Google Scholar]
  12. V. D. B. C. Dasireddy, B. Likozar, Renew. Energy, 2019, 140, 452 LINK https://doi.org/10.1016/j.renene.2019.03.073 [Google Scholar]
  13. M. Behrens, F. Studt, I. Kasatkin, S. Kühl, M. Hävecker, F. Abild-Pedersen, S. Zander, F. Girgsdies, P. Kurr, B.-L. Kniep, M. Tovar, R. W. Fischer, J. K. Nørskov, R. Schlögl, Science, 2012, 336, (6083), 893 LINK https://doi.org/10.1126/science.1219831 [Google Scholar]
  14. M. Huš, V. D. B. C. Dasireddy, N. S. Štefaničič, B. Likozar, Appl. Catal. B: Environ., 2017, 207, 267 LINK https://doi.org/10.1016/j.apcatb.2017.01.077 [Google Scholar]
  15. J. T. Sun, I. S. Metcalfe, M. Sahibzada, Ind. Eng. Chem. Res., 1999, 38, (10), 3868 LINK https://doi.org/10.1021/ie990078s [Google Scholar]
  16. A. Prašnikar, A. Pavlišič, F. Ruiz-Zepeda, J. Kovač, B. Likozar, Ind. Eng. Chem. Res., 2019, 58, (29), 13021 LINK https://doi.org/10.1021/acs.iecr.9b01898 [Google Scholar]
  17. X. Wei, Z. Yin, K. Lyu, Z. Li, J. Gong, G. Wang, L. Xiao, J. Lu, L. Zhuang, ACS Catal., 2020, 10, (7), 4103 LINK https://doi.org/10.1021/acscatal.0c00049 [Google Scholar]
  18. W. Zhou, K. Cheng, J. Kang, C. Zhou, V. Subramanian, Q. Zhang, Y. Wang, Chem. Soc. Rev., 2019, 48, (12), 3193 LINK https://doi.org/10.1039/C8CS00502H [Google Scholar]
  19. W. Wang, S. Wang, X. Ma, J. Gong, Chem. Soc. Rev., 2011, 40, (7), 3703 LINK https://doi.org/10.1039/c1cs15008a [Google Scholar]
  20. J. Díez-Ramírez, P. Sánchez, A. Rodríguez-Gómez, J. L. Valverde, F. Dorado, Ind. Eng. Chem. Res., 2016, 55, (12), 3556 LINK https://doi.org/10.1021/acs.iecr.6b00170 [Google Scholar]
  21. T. Toyao, S. Kayamori, Z. Maeno, S. M. A. H. Siddiki, K.-i. Shimizu, ACS. Catal., 2019, 9, (9), 8187 LINK https://doi.org/10.1021/acscatal.9b01225 [Google Scholar]
  22. X. Jiang, N. Koizumi, X. Guo, C. Song, Appl. Catal. B: Environ., 2015, 170-171, 173 LINK https://doi.org/10.1016/j.apcatb.2015.01.010 [Google Scholar]
  23. S. Dang, H. Yang, P. Gao, H. Wang, X. Li, W. Wei, Y. Sun, Catal. Today, 2019, 330, 61 LINK https://doi.org/10.1016/j.cattod.2018.04.021 [Google Scholar]
  24. S. Xiao, Y. Zhang, P. Gao, L. Zhong, X. Li, Z. Zhang, H. Wang, W. Wei, Y. Sun, Catal. Today, 2017, 281, (2), 327 LINK https://doi.org/10.1016/j.cattod.2016.02.004 [Google Scholar]
  25. O.-S. Joo, K.-D. Jung, I. Moon, A. Ya. Rozovskii, G. I. Lin, S.-H. Han, S.-J. Uhm, Ind. Eng. Chem. Res. 1999, 38, (5), 1808 LINK https://doi.org/10.1021/ie9806848 [Google Scholar]
  26. J. Toyir, R. Miloua, N. E. Elkandri, M. Nawdali, H. Toufik, F. Miloua, M. Saito, Phys. Proc., 2009, 2, (3), 1075 LINK https://doi.org/10.1016/j.phpro.2009.11.065 [Google Scholar]
  27. G. Dolan, ‘Methanol: Emerging Global Energy Markets’,16th Annual State of the Energy Industry Forum, Washington, DC, USA, 23rd January, 2020 [Google Scholar]
  28. X. Su, X. Yang, B. Zhao, Y. Huang, J. Energy Chem., 2017, 26, (5), 854 LINK https://doi.org/10.1016/j.jechem.2017.07.006 [Google Scholar]
  29. P. Lahijani, Z. A. Zainal, M. Mohammadi, A. R. Mohamed, Renew. Sust. Energy Rev., 2015, 41, 615 LINK https://doi.org/10.1016/j.rser.2014.08.034 [Google Scholar]
  30. F.-Y. Gao, R.-C. Bao, M.-R. Gao, S.-H. Yu, J. Mater. Chem. A, 2020, 8, (31), 15458 LINK https://doi.org/10.1039/D0TA03525D [Google Scholar]
  31. G. Chen, L. Wang, T. Godfroid, R. Snyders, ‘Progress in Plasma-Assisted Catalysis for Carbon Dioxide Reduction’, in “Plasma Chemistry and Gas Conversion”, eds. N. Britun, T. Silva, IntechOpen, London, UK, 2018, pp. 59–69 LINK https://doi.org/10.5772/intechopen.80798 [Google Scholar]
  32. D. Ramey, S.-T. Yang, ‘Production of Butyric acid and Butanol from Biomass’,US Department of Energy, Oak Ridge, TN, USA, 2005 LINK https://doi.org/10.2172/843183 [Google Scholar]
  33. S. Szwaja, J. D. Naber, Fuel, 2010, 89, (7), 1573 LINK https://doi.org/10.1016/j.fuel.2009.08.043 [Google Scholar]
  34. M. Munro, S. Nash, C. J. Chuck, R. W. Jenkins, Fuel, 2013, 103, 593 LINK https://doi.org/10.1016/j.fuel.2012.08.019 [Google Scholar]
  35. B. O. Abo, M. Gao, Y. Wang, C. Wu, Q. Wang, H. Ma, Environ. Sci. Poll. Res., 2019, 26, 20164 LINK https://doi.org/10.1007/s11356-019-05437-y [Google Scholar]
  36. H. Aitchison, R. L. Wingad, D. F. Wass, ACS Catal., 2016, 6, (10), 7125 LINK https://doi.org/10.1021/acscatal.6b01883 [Google Scholar]
  37. S. Bai, Q. Shao, P. Wang, Q. Dai, X. Wang, X. Huang, J. Am. Chem. Soc., 2017, 139, (20), 6827 LINK https://doi.org/10.1021/jacs.7b03101 [Google Scholar]
  38. L. Wang, L. Wang, J. Zhang, X. Liu, H. Wang, W. Zhang, Q. Yang, J. Ma, X. Dong, S. J. Yoo, J.-G. Kim, X. Meng, F.-S. Xiao, Angew. Chem. Int. Ed., 2018, 57, (21), 6104 LINK https://doi.org/10.1002/anie.201800729 [Google Scholar]
  39. H. Xu, D. Rebollar, H. He, L. Chong, Y. Liu, C. Liu, C.-J. Sun, T. Li, J. V. Muntean, R. E. Winans, D.-J. Liu, T. Xu, Nat. Energy, 2020, 5, 623 LINK https://doi.org/10.1038/s41560-020-0666-x [Google Scholar]
  40. B. Zhao, Y. Liu, Z. Zhu, H. Guo, X. Ma, J. CO2 Util., 2018, 24, 34 LINK https://doi.org/10.1016/j.jcou.2017.10.013 [Google Scholar]
  41. L. R. L. Ting, R. García-Muelas, A. J. Martín, F. L. P. Veenstra, S. T.-J. Chen, Y. Peng, E. Y. X. Per, S. Pablo-García, N. López, J. Pérez-Ramírez, B. S. Yeo, Angew. Chem. Int. Ed., 2020, 59, (47), 21072 LINK https://doi.org/10.1002/anie.202008289 [Google Scholar]
  42. G. R. M. Dowson, P. Styring, Front. Energy Res., 2017, 5, 26 LINK https://doi.org/10.3389/fenrg.2017.00026 [Google Scholar]
  43. F. Speiser, P. Braunstein, L. Saussine, Acc. Chem. Res., 2005, 38, (10), 784 LINK https://doi.org/10.1021/ar050040d [Google Scholar]
  44. L. Tan, G. Yang, Y. Yoneyama, Y. Kou, Y. Tan, T. Vitidsant, N. Tsubaki, Appl. Catal. A: Gen., 2015, 505, 141 LINK https://doi.org/10.1016/j.apcata.2015.08.002 [Google Scholar]
  45. M. Y. Kim, S. H. Yoon, B. W. Ryu, C. S. Lee, Fuel, 2008, 87, (12), 2779 LINK https://doi.org/10.1016/j.fuel.2008.01.032 [Google Scholar]
  46. ‘Mack Trucks Tests Alternative Fuel DME’,Volvo Group, Gothenburg, Sweden, 24th January, 2017 LINK www.volvogroup.com/en-en/news/2017/jan/mack-trucks-tests-alternative-fuel-dme.html [Google Scholar]
  47. ‘Ford Leads Project to Develop Near Zero Particulate Emission Diesel Cars that Could Run On Converted CO2’,Ford of Europe, Aachen, Germany, 11th September, 2015 LINK https://media.ford.com/content/fordmedia/feu/en/news/2015/09/11/ford-leads-project-to-develop-near-zero-particulate-emission-die.html [Google Scholar]
  48. J. McLaren, J. Miller, E. O’Shaughnessy, E. Wood, E. Shapiro, ‘Emissions Associated with Electric Vehicle Charging: Impact of Electricity Generation Mix, Charging Infrastructure Availability, and Vehicle Type’,NREL/TP-6A20-64852, National Renewable Energy Laboratory, Golden, CO, USA, April, 2016 LINK https://doi.org/10.2172/1247645 [Google Scholar]
  49. Thangavelu Jayabalan, ‘Flexible DME Production From Biomass: Fledged Project Update’,DME Sustainable Mobility Workshop, Berlin, Germany, 24th May 2019 LINK http://www.fledged.eu/fledged-project-represented-at-the-second-edition-of-the-dme-sustainable-mobility-workshop-in-berlin/ [Google Scholar]
  50. S. Michailos, S. McCord, V. Sick, G. Stokes, P. Styring, Energy Conv. Manage., 2019, 184, 262 LINK https://doi.org/10.1016/j.enconman.2019.01.046 [Google Scholar]
  51. A. Corradini, J. McCormick, Oberon Fuels Inc,, ‘Process and System for Converting Biogas to Liquid Fuels’,US Patent 8809603; 2014 [Google Scholar]
  52. M. Aresta, A. Dibenedetto, Dalton Trans., 2007, (28), 2975 LINK https://doi.org/10.1039/b700658f [Google Scholar]
  53. C.-H. Huang, C.-S. Tan, Aerosol Air Qual. Res., 2014, 14, (2), 480 LINK https://doi.org/10.4209/aaqr.2013.10.0326 [Google Scholar]
  54. J. Schittkowski, H. Ruland, D. Laudenschleger, K. Girod, K. Kähler, S. Kaluza, M. Muhler, R. Schlögl, Chem. Ing. Techn., 2018, 90, (10), 1419 LINK https://doi.org/10.1002/cite.201800017 [Google Scholar]
  55. L. Yao, X. Shen, Y. Pan, Z. Peng, Energy Fuels, 2020, 34, (7), 8635 LINK https://doi.org/10.1021/acs.energyfuels.0c01256 [Google Scholar]
  56. S. Polierer, D. Guse, S. Wild, K. H. Delgado, T. N. Otto, T. A. Zevaco, M. Kind, J. Sauer, F. Studt, S. Pitter, Catalysts, 2020, 10, (8), 816 LINK https://doi.org/10.3390/catal10080816 [Google Scholar]
  57. Q. Sheng, R.-P. Ye, W. Gong, X. Shi, B. Xu, M. Argyle, H. Adidharma, M. Fan, J. Environ. Sci., 2020, 92, 106 LINK https://doi.org/10.1016/j.jes.2020.02.015 [Google Scholar]
  58. A. Modak, P. Bhanja, S. Dutta, B. Chowdhury, A. Bhaumik, Green Chem., 2020, 22, (13), 4002 LINK https://doi.org/10.1039/D0GC01092H [Google Scholar]
  59. N. D. Otalvaro, M. Kaiser, K. H. Delgado, S. Wild, J. Sauer, H. Freund, React. Chem. Eng., 2020, 5, (5), 949 LINK https://doi.org/10.1039/D0RE00041H [Google Scholar]
  60. A. Kornas, M. Śliwa, M. Ruggiero-Mikołajczyk, K. Samson, J. Podobiński, R. Karcz, D. Duraczyńska, D. Rutkowska-Zbik, R. Grabowski, React. Kinet. Mech. Catal., 2020, 130, 179 LINK https://doi.org/10.1007/s11144-020-01778-9 [Google Scholar]
  61. U. Lee, J. Han, M. Wang, J. Ward, E. Hicks, D. Goodwin, R. Boudreaux, P. Hanarp, H. Salsing, P. Desai, E. Varenne, P. Klintbom, W. Willems, S. L. Winkler, H. Maas, R. De Kleine, J. Hansen, T. Shim, E. Furusjö, SAE Int. J. Fuels Lubr., 2016, 9, (3), 546 LINK https://doi.org/10.4271/2016-01-2209 [Google Scholar]
  62. S. Hänggi, P. Elbert, T. Bütler, U. Cabalzar, S. Teske, C. Bach, C. Onder, Energy Rep., 2019, 5, 555 LINK https://doi.org/10.1016/j.egyr.2019.04.007 [Google Scholar]
  63. W. Ahmad, F. L. Chan, A. Hoadley, H. Wang, A. Tanksale, Appl. Catal. B: Environ., 2020, 269, 118765 LINK https://doi.org/10.1016/j.apcatb.2020.118765 [Google Scholar]
  64. C. H. Gierlich, K. Beydoun, J. Klankermayer, R. Palkovits, Chem. Ing. Techn., 2020, 92, (1–2), 116 LINK https://doi.org/10.1002/cite.201900187 [Google Scholar]
  65. J. Wunderlich, L. Müller, G. A. Buchner, A. Marxen, S. Michailos, K. Armstrong, H. Naims, S. McCord, P. Styring, V. Sick, R. Schomäcker, A. W. Zimmermann, Front. Energy Res., 2020, 8, 5 LINK https://doi.org/10.3389/fenrg.2020.00005 [Google Scholar]
  66. V. Sick, K. Armstrong, G. Cooney, L. Cremonese, A. Eggleston, G. Faber, G. Hackett, A. Kätelhön, G. Keoleian, J. Marano, J. Marriott, S McCord, S. A. Miller, M. Mutchek, B. Olfe-Kräutlein, D. Ravikumar, L. K. Roper, J. Schaidle, T. Skone, L. Smith, T. Strunge, P. Styring, L. Tao, S. Völker, A. Zimmermann, Energy Technol., 2019, 8, (11), 1901034 LINK https://doi.org/10.1002/ente.201901034 [Google Scholar]
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