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Volume 70, Issue 2
  • ISSN: 2056-5135
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  • oa Unveiling the Potential of Platinum in Homogeneous Catalysis: A Review of Platinum--Heterocyclic Carbene Chemistry and Platinum-Catalysed Hydrosilylation Reactions: Part I

    Synthesis, properties and applications of platinum--heterocyclic carbene complexes

  • Authors: Benon P. Maliszewski1ORCID icon, Eleonora Casillo1ORCID icon, Thomas Scattolin2ORCID icon, Fady Nahra1,3ORCID icon, Catherine S. J. Cazin1ORCID icon and Steven P. Nolan1ORCID icon
  • 1 Department of Chemistry and Centre for Sustainable Chemistry, Ghent University, Krijgslaan 281–Building S3, 9000 Ghent, Belgium 2 Department of Chemical Sciences, University of Padova, Via Marzolo, 1-35131 Padova, Italy 3 Flemish Institute for Technological Research (VITO), Materials & Chemistry (MATCH) Unit, Boeretang 200, 2400 Mol, Belgium
    *[email protected]; §[email protected]; ǂ[email protected]
  • Source: Johnson Matthey Technology Review, Volume 70, Issue 2, Apr 2026, p. 152 - 172
  • DOI: https://doi.org/10.1595/205651326X17524853738421
    • Received: 27 May 2025
    • Accepted: 11 Jul 2025

Abstract

The utility of molecular organoplatinum complexes in catalytic transformations has long driven major industrial advancements, most notably in the hydrosilylation reaction, a process that is critical to the global, multibillion-dollar silicones industry. One of the most important breakthroughs in this field was the introduction of platinum--heterocyclic carbene (NHC) pre-catalysts. Apart from their significance in hydrosilylation processes, these unique complexes have also contributed to developments in other research areas, including cancer therapy and photophysics. This two-part review highlights the evolving role of platinum in homogeneous catalysis, with an emphasis on NHC complexes, providing both historical context and the latest findings. Part I introduces platinum-NHC complexes, covering their synthetic accessibility, properties and role in homogeneous catalysis, along with other notable applications. Part II (1) will discuss the fundamentals and recent developments in the catalytic hydrosilylation of alkenes and alkynes, centred around platinum-NHC pre-catalysts.

© 2026 Johnson Matthey
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Unveiling the Potential of Platinum in Homogeneous Catalysis: A Review of Platinum-N-Heterocyclic Carbene Chemistry and Platinum-Catalysed Hydrosilylation Reactions: Part I
Johnson Matthey Technology Review 70, 152 (2026); https://doi.org/10.1595/205651326X17524853738421
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/content/journals/10.1595/205651326X17524853738421
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